EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

trimethylolpropane
propanediol, 2-ethyl-2-(hydroxymethyl)-, 1,3-

Supplier Sponsors

Name:2-ethyl-2-(hydroxymethyl)propane-1,3-diol
CAS Number: 77-99-6Picture of molecule3D/inchi
Other(deleted CASRN):101164-61-8
ECHA EINECS - REACH Pre-Reg:201-074-9
FDA UNII: 090GDF4HBD
Nikkaji Web:J35.936J
Beilstein Number:1698309
MDL:MFCD00004694
XlogP3-AA:-0.80 (est)
Molecular Weight:134.17518000
Formula:C6 H14 O3
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:humectants, solvents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
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Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 FDA/DG SANTE Petitions, Reviews, Notices:
FCN 92 Trimethylolpropane View - notice
FCN 312 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol View - notice
FCN 527 1,3-Propanediol, 2-ethyl-2-(hydroxymethyl) View - notice
FCN 551 Trimethylolpropane View - notice
FCN 804 Trimethylolpropane View - notice
FCN 1691 Trimethylolpropane View - notice
FCN 1698 Trimethylolpropane View - notice
FCN 1953 Trimethylolpropane View - notice
DG SANTE Food Contact Materials:1,1,1-trimethylolpropane
FDA Mainterm (IAUFC):77-99-6 ; TRIMETHYLOLPROPANE
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 58.00 °C. @ 760.00 mm Hg
Boiling Point: 289.00 °C. @ 760.00 mm Hg
Flash Point: 298.00 °F. TCC ( 147.70 °C. ) (est)
logP (o/w): -0.975 (est)
Soluble in:
 water, 1.00E+06 mg/L @ 25 °C (exp)
 water, 1e+006 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: humectants
solvents
 
Suppliers:
BOC Sciences
For experimental / research use only.
1,1,1-Tris(hydroxymethyl)propane 99%
Charkit Chemical
TRIMETHYLOLPROPANE
Covalent Chemical
Trimethylol Propane
Penta International
TRIMETHYLOLPROPANE
Sigma-Aldrich: Aldrich
For experimental / research use only.
1,1,1-Tris(hydroxymethyl)propane dist., ≥98.0% (GC)
Silver Fern Chemical
Trimethylolpropane (TMP)
Odor: characteristic
Use: TMP is widely used as a building block in the polymer industry. It is also used as a conditioning agent, manufacture of varnishes, alkyd resins, synthetic drying oils, urethane foams and coatings, silicone lubricant oils, lactone plasticizers, textile finishes, surfactants, and epoxy products.
TCI AMERICA
For experimental / research use only.
Trimethylolpropane >98.0%(GC)
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-mouse LD50 13700 mg/kg
LUNGS, THORAX, OR RESPIRATION: DYSPNEA BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
Hygiene and Sanitation Vol. 32(5), Pg. 288, 1967.

oral-rat LD50 14100 mg/kg
LUNGS, THORAX, OR RESPIRATION: DYSPNEA BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
Hygiene and Sanitation Vol. 32(5), Pg. 288, 1967.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
humectants, solvents
Recommendation for trimethylolpropane usage levels up to:
 not for fragrance use.
 
Recommendation for trimethylolpropane flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
NIOSH International Chemical Safety Cards:search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):77-99-6
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :6510
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:1
2-ethyl-2-(hydroxymethyl)propane-1,3-diol
Chemidplus:0000077996
RTECS:77-99-6
 
References:
 2-ethyl-2-(hydroxymethyl)propane-1,3-diol
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:77-99-6
Pubchem (cid):6510
Pubchem (sid):134972956
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Indirect Additives used in Food Contact Substances:View
CHEMBL:View
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2905.41.0000
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 butan-1-ol, 2,2-bis(hydroxymethyl)-
2-ethyl-2-(hydroxymethyl)-1,3-propanediol
2-ethyl-2-(hydroxymethyl)propane diol
2-ethyl-2-(hydroxymethyl)propane-1,3-diol
2-ethyl-2-hydroxymethyl-1,3-propanediol
2-ethyl-2-hydroxymethyl-propane-1,3-diol
 hexaglycerine
1,1,1-tris(hydroxymethyl) propane
2,2-bis(hydroxymethyl)-1-butanol
1,1,1-tris(hydroxymethyl)propane
 methanol, (propanetriyl)tris-
 propane, 1,1,1-tris(hydroxymethyl)-
1,3-propanediol, 2-ethyl-2-(hydroxymethyl)-
 propanediol, 2-ethyl-2-(hydroxymethyl)-, 1,3-
 propylidynetrimethanol
 tri(hydroxymethyl)propane
1,1,1-tri(hydroxymethyl)propane
 trimethylol propane
1,1,1-trimethylolpropane
 

Articles:

PubMed:Biomimetic piezoelectric quartz crystal sensor with chloramphenicol-imprinted polymer sensing layer.
PubMed:Untethered photonic sensor for wall pressure measurement.
PubMed:Dental composite components induce DNA-damage and altered nuclear morphology in gingiva fibroblasts.
PubMed:Chemoenzymatic Synthesis of Amphiphilic Core-Shell TMP-(PCL-b-PGMA2)3 Star-Block Copolymer.
PubMed:Molecularly imprinted polymer beads for clean-up and preconcentration of β-lactamase-resistant penicillins in milk.
PubMed:Robust naphthyl methacrylate monolithic column for high performance liquid chromatography of a wide range of solutes.
PubMed:In vitro evaluation of thermal frontally polymerized thiol-ene composites as bone augments.
PubMed:Influence of the filler on thermal properties of porous VP-TRIM copolymers.
PubMed:Preparation and Characterization of Polyhedral Oligomeric Silsesquioxane-Containing, Titania-Thiol-Ene Composite Photocatalytic Coatings, Emphasizing the Hydrophobic-Hydrophilic Transition.
PubMed:Preparation of melamine molecularly imprinted polymer by computer-aided design.
PubMed:Experimental mixture design as a tool for the synthesis of antimicrobial selective molecularly imprinted monodisperse microbeads.
PubMed:Core-shell magnetic molecularly imprinted polymers as sorbent for sulfonylurea herbicide residues.
PubMed:Palm oil derived trimethylolpropane triesters synthetic lubricants and usage in industrial metalworking fluid.
PubMed:Single step natural poly(tannic acid) particle preparation as multitalented biomaterial.
PubMed:Thiol-epoxy click polymerization for preparation of polymeric monoliths with well-defined 3D framework for capillary liquid chromatography.
PubMed:Facile construction of macroporous hybrid monoliths via thiol-methacrylate Michael addition click reaction for capillary liquid chromatography.
PubMed:Cholesterol-based polymeric monolithic columns for capillary liquid chromatography.
PubMed:Novel acyloxy derivatives of branched mono- and polyol esters of sal fat: multiviscosity grade lubricant base stocks.
PubMed:Fabrication of highly cross-linked reversed-phase monolithic columns via living radical polymerization.
PubMed:Separation of Rebaudiana A from Steviol glycoside using a polymeric adsorbent with multi-hydrogen bonding in a non-aqueous system.
PubMed:Environmentally friendly method for the determination of acrylamide and trimethylolpropane in paper packaging materials by liquid chromatography with tandem mass spectrometry.
PubMed:In situ polymerization of monolith based on poly(Triallyl Isocyanurate-co-trimethylolpropane triacrylate) and its application in high-performance liquid chromatography.
PubMed:Monolithic molecularly imprinted polymeric capillary columns for isolation of aflatoxins.
PubMed:Structural and Interfacial Properties of Hyperbranched-Linear Polymer Surfactant.
PubMed:In vitro and in vivo characterization of pentaerythritol triacrylate-co-trimethylolpropane nanocomposite scaffolds as potential bone augments and grafts.
PubMed:Facile preparation of octadecyl monoliths with incorporated carbon nanotubes and neutral monoliths with coated carbon nanotubes stationary phases for HPLC of small and large molecules by hydrophobic and π-π interactions.
PubMed:Molecularly imprinted polymer nanocarriers for sustained release of erythromycin.
PubMed:Preparation of Monolithic Capillary Chromatographic Columns Using Supercritical Fluid as a Porogen Solvent.
PubMed:Selective and simultaneous determination of trace bisphenol A and tebuconazole in vegetable and juice samples by membrane-based molecularly imprinted solid-phase extraction and HPLC.
PubMed:Development of sustained antimicrobial-release systems using poly(2-hydroxyethyl methacrylate)/trimethylolpropane trimethacrylate hydrogels.
PubMed:On the influence of crosslinker on template complexation in molecularly imprinted polymers: a computational study of prepolymerization mixture events with correlations to template-polymer recognition behavior and NMR spectroscopic studies.
PubMed:One-step interfacial thiol-ene photopolymerization for metal nanoparticle-decorated microcapsules (MNP@MCs).
PubMed:A new method of evaluation of fracture patterns following microtensile bond strength testing using polarized light microscopy.
PubMed:[Preparation of nicosulfuron molecularly imprinted microspheres and research of adsorption characteristics].
PubMed:Beauty of lotus is more than skin deep: highly buoyant superhydrophobic films.
PubMed:Enhancing trimethylolpropane esters synthesis through lipase immobilized on surface hydrophobic modified support and appropriate substrate feeding methods.
PubMed:The first photochemical in situ production of Ti-based nanoparticles: a SH2 strategy using bis(cyclopentadienyl)titanium dichloride (Cp2TiCl2).
PubMed:Stacked quantum dot embedded silica film on a phosphor plate for superior performance of white light-emitting diodes.
PubMed:Preparation and characterization of poly(triallyl isocyanurate-co-trimethylolpropane triacrylate) monolith and its applications in the separation of small molecules by liquid chromatography.
PubMed:Species and gender differences in the carcinogenic activity of trimethylolpropane triacrylate in rats and mice.
PubMed:Photocured thiol-ene based optical fluorescence sensor for determination of gold(III).
PubMed:Osmocapsules for direct measurement of osmotic strength.
PubMed:Preparation of a novel porous poly (trimethylol propane triacrylate-co-ethylene dimethacrylate) monolithic column for highly efficient HPLC separations of small molecules.
PubMed:High-performance liquid chromatography separation of small molecules on a porous poly (trimethylol propane triacrylate-co-N-isopropylacrylamide-co-ethylene dimethacrylate) monolithic column.
PubMed:Photopolymerizable phosphate acrylates as comonomers in dental adhesives with or without triclosan monomer units.
PubMed:Extraction of quercetin from Herba Lysimachiae by molecularly imprinted-matrix solid phase dispersion.
PubMed:Kinetic modeling of lipase-catalyzed esterification reaction between oleic acid and trimethylolpropane: a simplified model for multi-substrate multi-product ping-pong mechanisms.
PubMed:Molecularly imprinted polymer microspheres containing photoswitchable spiropyran-based binding sites.
PubMed:Factors affecting the TMPTA radical polymerization photoinitiated by phenyltrialkylborates paired with tri-cationic hemicyanine dye. Kinetic studies.
PubMed:Photoembossing of surface relief structures in polymer films for biomedical applications.
PubMed:Poly(ester amine) synthesized from trimethylolpropane triacrylate and spermine as an efficient siRNA carrier.
PubMed:Progress in the development of enzyme-based nerve agent bioscavengers.
PubMed:Preparation of doxycycline-imprinted magnetic microspheres by inverse-emulsion suspension polymerization for magnetic dispersion extraction of tetracyclines from milk samples.
PubMed:Hole-shell microparticles from controllably evolved double emulsions.
PubMed:Thiol-acrylate nanocomposite foams for critical size bone defect repair: A novel biomaterial.
PubMed:Polymer monolithic capillary microextraction combined on-line with inductively coupled plasma MS for the determination of trace rare earth elements in biological samples.
PubMed:A facile approach for preparation of molecularly imprinted polymers layer on the surface of carbon nanotubes.
PubMed:Responsive hybrid microcapsules by the one-step interfacial thiol-ene photopolymerization.
PubMed:Ring-opening metathesis polymerization-derived, lectin-functionalized monolithic supports for affinity separation of glycoproteins.
PubMed:Toxicology and carcinogenesis studies of trimethylolpropane triacrylate (technical grade) (CASRN 15625-89-5) in F344/N rats and B6C3F1/N mice (dermal studies).
PubMed:Two decades of occupational (meth)acrylate patch test results and focus on isobornyl acrylate.
PubMed:Preparation of an amperometric sensor for norfloxacin based on molecularly imprinted grafting photopolymerization.
PubMed:Imprintable, bendable, and shape-conformable polymer electrolytes for versatile-shaped lithium-ion batteries.
PubMed:Construction of a novel macroporous imprinted biosensor based on quartz crystal microbalance for ribonuclease A detection.
PubMed:Optimization of a two-step process comprising lipase catalysis and thermal cyclization improves the efficiency of synthesis of six-membered cyclic carbonate from trimethylolpropane and dimethylcarbonate.
PubMed:High Throughput Micropatterning of Optical Oxygen Sensor for Single Cell Analysis.
PubMed:Optimization of human serum albumin monoliths for chiral separations and high-performance affinity chromatography.
PubMed:Preparation and characterization of grafted imprinted monolith for capillary electrochromatography.
PubMed:Non-chromatographic mercury speciation and determination in wine by new core-shell ion-imprinted sorbents.
PubMed:Synthesis and evaluation of uniformly sized nalidixic acid-imprinted nanospheres based on precipitation polymerization method for analytical and biomedical applications.
PubMed:Modernizing the MTT assay with microfluidic technology and image cytometry.
PubMed:Multiparametric assessment of Cd²+ cytotoxicity using MTT-based microfluidic image cytometry.
PubMed:Ring-opening metathesis polymerization-derived large-volume monolithic supports for reversed-phase and anion-exchange chromatography of biomolecules.
PubMed:Rational design of molecularly imprinted polymer: the choice of cross-linker.
PubMed:Controlled synthesis of bulk polymer nanocomposites with tunable second order nonlinear optical properties.
PubMed:Modification and characterization of biodegradable methylcellulose films with trimethylolpropane trimethacrylate (TMPTMA) by γ radiation: effect of nanocrystalline cellulose.
PubMed:[Microchip-based reversed-phase liquid chromatography-tandem mass spectrometry platform for protein analysis].
PubMed:Photo-crosslinkable cyanoacrylate bioadhesive: shrinkage kinetics, dynamic mechanical properties, and biocompatibility of adhesives containing TMPTMA and POSS nanostructures as crosslinking agents.
PubMed:Properties of indirect composites reinforced with monomer-impregnated glass fiber.
PubMed:Microshear bond strength and interfacial morphology of etch-and-rinse and self-etch adhesive systems to superficial and deep dentin.
PubMed:Molecularly imprinted polymer grafted to porous polyethylene frits: a new selective solid-phase extraction format.
PubMed:Enhanced two-photon excited fluorescence in three-dimensionally crosslinked bovine serum albumin microstructures.
PubMed:Isocyanate-functional adhesives for biomedical applications. Biocompatibility and feasibility study for vascular closure applications.
PubMed:Synthesis of a difunctional orthogonal coupler for the preparation of carbohydrate-functionalized sP(EO-stat-PO) hydrogels.
PubMed:Mixed ligand monolithic columns for reversed-phase capillary electrochromatography via hydrophobic and π interactions.
PubMed:Synthesis of trimethylolpropane esters of oleic acid by Lipoprime 50T.
PubMed:Synthesis of X(Y)-(EO)(n)-OCH₃ type heterobifunctional and X(Y)-(EO)(n)-Z type heterotrifunctional poly(ethylene glycol)s.
PubMed:[Spectroscopy study of binding mechanisms and molecular recognition of class-specific molecularly imprinted polymer beads].
PubMed:Layered double hydroxide as nanofiller in the development of polyurethane nanocomposites.
PubMed:QSRR analysis of β-lactam antibiotics on a penicillin G targeted MIP stationary phase.
PubMed:Naphthyl methacrylate-phenylene diacrylate-based monolithic column for reversed-phase capillary electrochromatography via hydrophobic and π interactions.
PubMed:A novel, neutral hydroxylated octadecyl acrylate monolith with fast electroosmotic flow velocity and its application to the separation of various solutes including peptides and proteins in the absence of electrostatic interactions.
PubMed:Surface-tension-induced synthesis of complex particles using confined polymeric fluids.
PubMed:High performance magnetically controllable microturbines.
PubMed:Capillary electrophoresis characterization of molecularly imprinted polymer particles in fast binding with 17β-estradiol.
PubMed:Class-specific molecularly imprinted polymers for the selective extraction and determination of sulfonylurea herbicides in maize samples by high-performance liquid chromatography-tandem mass spectrometry.
PubMed:Flow-through immunosensors using antibody-immobilized polymer monoliths.
PubMed:Feedback regulated drug delivery vehicles: carbon dioxide responsive cationic hydrogels for antidote release.
PubMed:pCEC coupling with ESI-MS for the analysis of beta(2)-agonists and narcotics using a poly-(1-hexadecene-co-TMPTMA) monolithic column.
PubMed:[Preparation of bovine serum albumin immobilized adsorbent for specific adsorption of bilirubin].
PubMed:Nitroxide polymer networks formed by Michael addition: on site-cured electrode-active organic coating.
PubMed:Development of a molecularly imprinted polymer for selective extraction of bisphenol A in water samples.
PubMed:Preparation of polyamine-functionalized copper specific adsorbents for selective adsorption of copper.
PubMed:Synthesis of a novel camphorquinone derivative having acylphosphine oxide group, characterization by UV-VIS spectroscopy and evaluation of photopolymerization performance.
PubMed:Modeling of reaction kinetics for transesterification of palm-based methyl esters with trimethylolpropane.
PubMed:Ring-opening metathesis polymerization based pore-size-selective functionalization of glycidyl methacrylate based monolithic media: access to size-stable nanoparticles for ligand-free metal catalysis.
PubMed:Molecularly imprinted polymer/cryogel composites for solid-phase extraction of bisphenol A from river water and wine.
PubMed:Preparation and evaluation of a contact lens vehicle for puerarin delivery.
PubMed:Altering amine basicities in biodegradable branched polycationic polymers for nonviral gene delivery.
PubMed:Preparation of a crosslinked bioimprinted lipase for enrichment of polyunsaturated fatty acids from fish processing waste.
PubMed:Preparation and evaluation of the highly cross-linked poly(1-hexadecane-co-trimethylolpropane trimethacrylate) monolithic column for capillary electrochromatography.
PubMed:Investigation of thiol-ene and thiol-ene-methacrylate based resins as dental restorative materials.
PubMed:Macroradical initiated polymerisation of acrylic and methacrylic monomers.
PubMed:Molecularly imprinted solid-phase extraction of fumonisin B analogues in bell pepper, rice and corn flakes.
PubMed:Cyclodextrin-containing hydrogels for contact lenses as a platform for drug incorporation and release.
PubMed:Migration of bacteria through a monolith.
PubMed:Electrochemical formation of stable p-i-n junction in conjugated polymer thin films.
PubMed:Asthma induced by a thermal printer.
PubMed:Magnetic molecularly imprinted polymer for aspirin recognition and controlled release.
PubMed:Dynamic mechanical analysis and esterase degradation of dentin adhesives containing a branched methacrylate.
PubMed:Isolation and detection of steroids from human urine by molecularly imprinted solid-phase extraction and liquid chromatography.
PubMed:Tuning curvature in flow lithography: a new class of concave/convex particles.
PubMed:Effect of filler type and polishing on the discoloration of composite resin artificial teeth.
PubMed:Ion-imprinted polymethacrylic microbeads as new sorbent for preconcentration and speciation of mercury.
PubMed:Occupational conjunctivitis as the sole manifestation of airborne contact allergy to trimethylolpropane triacrylate contained in a UV-cured paint.
PubMed:Neutral polar methacrylate-based monoliths for normal phase nano-LC and CEC of polar species including N-glycans.
PubMed:A facile route to bulk high-Z polymer composites for gamma ray scintillation.
PubMed:Preparation and evaluation of non-bonded hyperbranched polymer-coated columns for capillary electrophoresis.
PubMed:Electron beam triggered, free radical polymerization-derived monolithic capillary columns for high-performance liquid chromatography.
PubMed:Toxicology studies of trimethylolpropane triacrylate (technical grade) (CAS No. 15625-89-5) in F344/N rats, B6C3F1 mice, and genetically modified (FVB Tg.AC hemizygous) mice (dermal studies).
PubMed:Analysis of recognition of fructose by imprinted polymers.
PubMed:Anti-Her-2 monoclonal antibody conjugated polymer fluorescent nanoparticles probe for ovarian cancer imaging.
PubMed:Neutral octadecyl monolith for reversed phase capillary electrochromatography of a wide range of solutes.
PubMed:Dissociation constants for GABA(A) receptor antagonists determined with neuronal networks on microelectrode arrays.
PubMed:Hydrogels for potential colon drug release by thiol-ene conjugate addition of a new inulin derivative.
PubMed:An improved method for de novo sequencing of arginine-containing, Nalpha-tris(2,4,6-trimethoxyphenyl)phosphonium-acetylated peptides.
PubMed:Development of new bone cement utilizing low toxicity monomers.
PubMed:Effect of the template and functional monomer on the textural properties of molecularly imprinted polymers.
PubMed:Surface functionalization of ZrO2 nanocrystallites for the integration into acrylate nanocomposite films.
PubMed:Preparation of molecularly imprinted solid phase extraction using bensulfuron-methyl imprinted polymer and clean-up for the sulfonylurea-herbicides in soybean.
PubMed:Optofluidic encapsulation of crystalline colloidal arrays into spherical membrane.
PubMed:Preparation and Properties of Novel Dentin Adhesives with Esterase Resistance.
PubMed:Photocurable pickering emulsion for colloidal particles with structural complexity.
PubMed:New biomedical devices with selective peptide recognition properties. Part 1: Characterization and cytotoxicity of molecularly imprinted polymers.
PubMed:Preparation, characterization, and heat resistance studies of a holographic photopolymer based on SU-8 epoxy resin.
PubMed:Water solubilization of DDGS via derivatization with phosphite esters.
PubMed:Comparative study on the separation behavior of monolithic columns prepared via ring-opening metathesis polymerization and via electron beam irradiation triggered free radical polymerization for proteins.
PubMed:Selective removal of copper and lead ions by diethylenetriamine-functionalized adsorbent: behaviors and mechanisms.
PubMed:Facile approach to the fabrication of a micropattern possessing nanoscale substructure.
PubMed:Separation behavior of electron-beam curing derived, acrylate-based monoliths.
PubMed:In situ synthesis of molecularly imprinted polymers on glass microspheres in a column.
PubMed:Dispersion behavior of zirconia nanocrystals and their surface functionalization with vinyl group-containing ligands.
PubMed:Nanofabricated particles for engineered drug therapies: a preliminary biodistribution study of PRINT nanoparticles.
PubMed:Synthesis and characterization of branched polymers from lipase-catalyzed trimethylolpropane copolymerizations.
PubMed:Development of fructosyl valine binding polymers by covalent imprinting.
PubMed:Solid phase selective separation and preconcentration of Cu(II) by Cu(II)-imprinted polymethacrylic microbeads.
PubMed:Molecularly imprinted polymer films for reflectometric interference spectroscopic sensors.
PubMed:Structural aspects of surfactant selection for the design of vegetable oil semi-synthetic metalworking fluids.
PubMed:Fabrication and characterization of rigid magnetic monodisperse microspheres for protein adsorption.
PubMed:Selective molecularly imprinted polymer obtained from a combinatorial library for the extraction of bisphenol A.
PubMed:Co- and terpolyesters based on isosorbide and succinic acid for coating applications: synthesis and characterization.
PubMed:Quantification of organic eluates from polymerized resin-based dental restorative materials by use of GC/MS.
PubMed:Vulnerability of long-term neurotoxicity of chlorpyrifos: effect on schedule-induced polydipsia and a delay discounting task.
PubMed:Nanoparticle-based continuous full filling capillary electrochromatography/electrospray ionization-mass spectrometry for separation of neutral compounds.
PubMed:Stilbene-like molecules as fluorescent probes applied for monitoring of polymerization process.
PubMed:Development and evaluation of spherical molecularly imprinted polymer beads.
PubMed:Control of cardiomyocyte orientation on a microscaffold fabricated by photopolymerization with laser beam interference.
PubMed:Final report of the safety assessment of methacrylate ester monomers used in nail enhancement products.
PubMed:Integration of zinc oxide nanoparticles into transparent poly(butanediolmonoacrylate) via photopolymerisation.
PubMed:Molecular engineering of fluorescent penicillins for molecularly imprinted polymer assays.
PubMed:Synthesis and characterization of peptide grafted porous polymer microstructures.
PubMed:Concomitant contact allergy to the resins, reactive diluents and hardener of a bisphenol A/F-based epoxy resin in subway construction workers.
PubMed:Selective extraction of organophosphorus nerve agent degradation products by molecularly imprinted solid-phase extraction.
PubMed:Interactions of bupivacaine with a molecularly imprinted polymer in a monolithic format studied by NMR.
PubMed:Molecularly imprinted polymers grafted to flow through poly(trimethylolpropane trimethacrylate) monoliths for capillary-based solid-phase extraction.
PubMed:1,1,1-Tris(hydroxymethyl)propane in manganese carboxylate chemistry: synthesis, structure and magnetic properties of a mixed-valence [MnIII4MnII4] cluster featuring the novel [MnIII4MnII4(mu3-OR)6(mu2-OR)8]6+ core.
PubMed:[Composite template membranes as synthetic receptor systems 1. Preparation, specificity and template effect].
PubMed:Evaluation of hyperbranched poly(amino ester)s of amine constitutions similar to polyethylenimine for DNA delivery.
PubMed:Using paramagnetic particles as repulsive templates for the preparation of membranes of controlled porosity.
PubMed:Topical application of representative multifunctional acrylates produced proliferative and inflammatory lesions in F344/N rats and B6C3F1 mice, and squamous cell neoplasms in Tg.AC mice.
PubMed:Thiol-ene oligomers as dental restorative materials.
PubMed:Light-directed movement of polymer microstructures.
PubMed:Control of particle assisted wetting by an external magnetic field.
PubMed:Effects of filler composition on flexibility of microfilled resin composite.
PubMed:[The preparation of chemical-bonded hyperbranched polymer coated column for capillary electrophoresis and their application to separation of basic proteins].
PubMed:Developmental toxicity evaluation of trimethylolpropane caprylate caprate in Sprague-Dawley rats.
PubMed:Photo-polymerized microarchitectural constructs prepared by microstereolithography (muSL) using liquid acrylate-end-capped trimethylene carbonate-based prepolymers.
PubMed:Affinity depletion of albumin from human cerebrospinal fluid using Cibacron-blue-3G-A-derivatized photopatterned copolymer in a microfluidic device.
PubMed:Introducing lactide-based biodegradable tissue adhesives.
PubMed:Methacrylates in dental restorative materials.
PubMed:Tailoring lactide/caprolactone co-oligomers as tissue adhesives.
PubMed:Determination of albumin concentration by MIP-QCM sensor.
PubMed:A chemiluminescence flow immunosensor based on a porous monolithic metacrylate and polyethylene composite disc modified with protein G.
PubMed:Photocurable biodegradable liquid copolymers: synthesis of acrylate-end-capped trimethylene carbonate-based prepolymers, photocuring, and hydrolysis.
PubMed:Treatment of spontaneous and chemically induced EEG paroxysms in the Fischer-344 rat with traditional antiepileptic drugs or AED+CGP 35348 polytherapy.
PubMed:Period-doubling behavior in frontal polymerization of multifunctional acrylates.
PubMed:Preparation of polyol esters based on vegetable and animal fats.
PubMed:Spectra from 2.5-15 microm of tissue phantom materials, optical clearing agents and ex vivo human skin: implications for depth profiling of human skin.
PubMed:[Molecularly imprinted polymeric microspheres prepared by seed swelling and suspension polymerization].
PubMed:Synthesis and screening of a molecularly imprinted polymer library targeted for penicillin G.
PubMed:Allergic contact dermatitis from trimethylolpropane triacrylate and pentaerythritol triacrylate.
PubMed:Application of stored waveform ion modulation 2D-FTICR MS/MS to the analysis of complex mixtures.
PubMed:Nanoparticles as pseudostationary phase in capillary electrochromatography/ESI-MS.
PubMed:Gene modulation in total brain induced by exposure to the bicyclic phosphorus ester trimethylolpropane phosphate (TMPP).
PubMed:Capillary LC-MS2 at the attomole level for monitoring and discovering endogenous peptides in microdialysis samples collected in vivo.
PubMed:Identification of differential gene expression profiles in rat cortical cells exposed to the neuroactive agents trimethylolpropane phosphate and bicuculline.
PubMed:Characterization of acute neurotoxic effects of trimethylolpropane phosphate via neuronal network biosensors.
PubMed:The use of GABA(A) receptors expressed in neural precursor cells for cell-based assays.
PubMed:Reduction of motor seizures in rats induced by the ethyl bicyclophosphate trimethylolpropane phosphate (TMPP).
PubMed:Behavioral sensitization following exposure to low doses of trimethylolpropane phosphate.
PubMed:An in vitro wear study of posterior denture tooth materials on human enamel.
PubMed:Semipreparative capillary electrochromatography.
PubMed:Trimethylolpropane phosphate induces epileptiform discharges in the CA1 region of the rat hippocampus.
PubMed:Strength of relined denture base polymers subjected to long-term water immersion.
PubMed:Influence of mobile phase composition and cross-linking density on the enantiomeric recognition properties of molecularly imprinted polymers.
PubMed:Inhibition of spontaneous GABAergic transmission by trimethylolpropane phosphate.
PubMed:Fetal and neonatal exposure to trimethylolpropane phosphate alters rat social behavior and emotional responsivity.
PubMed:Imprinted polymers as tools for the recovery of secondary metabolites produced by fermentation
PubMed:Highly cross-linked networks for dental applications obtained by photocuring of tris[2-(acryloyloxy)ethyl]isocyanurate, 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate, and pentaerythritol triacrylate.
PubMed:Beaded reactive polymers. 3. Effect of triacrylates as crosslinkers on the physical properties of glycidyl methacrylate copolymers and immobilization of penicillin G acylase.
PubMed:Biodegradable products by lipase biocatalysis.
PubMed:Magnetic molecularly imprinted polymer beads for drug radioligand binding assay.
PubMed:Repeated exposure to trimethylolpropane phosphate induces central nervous system sensitization and facilitates electrical kindling.
PubMed:Tissue distribution, metabolism, and clearance of the convulsant trimethylolpropane phosphate in rats.
PubMed:Airborne occupational allergic contact dermatitis due to trimethylolpropane triacrylate (TMPTA) used in the manufacture of printed circuit boards.
PubMed:Acute effects of a bicyclophosphate neuroconvulsant on monoamine neurotransmitter and metabolite levels in the rat brain.
PubMed:Long-term changes in rat social behavior following treatment with trimethylolpropane.
PubMed:Effect of resin monomer composition on toothbrush wear resistance.
PubMed:Photodynamically generated bovine serum albumin radicals: evidence for damage transfer and oxidation at cysteine and tryptophan residues.
PubMed:Trimethylolpropane phosphate (TMPP) perfusion into the nucleus accumbens of the rat: electroencephalographic, behavioral and neurochemical correlates.
PubMed:10 years of patch testing with the (meth)acrylate series.
PubMed:Preparation of an effective light-cured bonding agent for orthodontic application.
PubMed:An overview of the development, validation, and application of neurobehavioral and neuromolecular toxicity assessment batteries: potential applications to combustion toxicology.
PubMed:Chiral recognition in adrenergic receptor binding mimics prepared by molecular imprinting.
PubMed:The effects of cross-linking agents on the water sorption and solubility characteristics of denture base resin.
PubMed:Photopolymerized multifunctional (meth)acrylates as model polymers for dental applications.
PubMed:Effect of light-exposure duration on the amount of leachable monomers from light-activated reline material.
PubMed:Neurotoxin formation from pilot-scale incineration of synthetic ester turbine lubricants with a triaryl phosphate additive.
PubMed:Electrochemical methods for detection of nitric oxide.
PubMed:Review: Selective ligand-exchange adsorbents prepared by template polymerization.
PubMed:Occupational allergic contact dermatitis and contact urticaria caused by polyfunctional aziridine hardener.
PubMed:A new copolymerized composite resin system: a multiphased evaluation.
PubMed:The effects of cross-linking agents on some properties of HEMA-based resins.
PubMed:Densely crosslinked polymer networks of poly(ethylene glycol) in trimethylolpropane triacrylate for cell-adhesion-resistant surfaces.
PubMed:Polymer networks with grafted cell adhesion peptides for highly biospecific cell adhesive substrates.
PubMed:Laboratory evaluation of experimental restorative systems containing 4-META.
PubMed:An in vitro evaluation of a copolymerizable type of microfilled composite resin.
PubMed:Evaluation of shipboard formation of a neurotoxicant (trimethylolpropane phosphate) from thermal decomposition of synthetic aircraft engine lubricant.
PubMed:Biodegradation of a synthetic lubricant by Micrococcus roseus.
PubMed:Permeation of multifunctional acrylates through selected protective glove materials.
PubMed:Potential neurotoxin formation in thermally degraded synthetic ester turbine lubricants.
PubMed:In vitro and in vivo behaviour of narciclasine released from matrices based on poly (2-hydroxyethyl methacrylate).
PubMed:Preparation of thermo-responsive membranes. II.
PubMed:Genotoxicity of multifunctional acrylates in the Salmonella/mammalian-microsome assay and mouse lymphoma TK+/-assay.
PubMed:Lack of genotoxicity of cross-linked acrylate polymers in four short-term genotoxicity assays.
PubMed:Comparison of mutagenicity results for nine compounds evaluated at the hgprt locus in the standard and suspension CHO assays.
PubMed:Immobilization of fatty acid synthetase from Mycobacterium smegmatis by radiation-induced polymerization.
PubMed:[A light-cured acrylic adhesive for fixing resin retention devices to the wax pattern].
PubMed:Differential mutant quantitation at the mouse lymphoma tk and CHO hgprt loci.
PubMed:Analysis of the genotoxicity of nine acrylate/methacrylate compounds in L5178Y mouse lymphoma cells.
PubMed:[The effect of composition on the mechanical properties of composite resin].
PubMed:[Fundamental study on photocured resin for crown and bridge].
PubMed:Radiation-induced polymerization for the immobilization of penicillin acylase.
PubMed:Immunogenicity of acrylate chemicals as assessed by antibody induction.
PubMed:Cytochemical study of the fluorescence reaction of chromatin by the porphyrin derivative meso-tetra (4-N-methylpyridyl) porphine.
PubMed:Allergic contact dermatitis from UV-curing acrylate in the manufacture of optical fibres.
PubMed:Dermatitis from aziridine hardener in printing ink.
PubMed:Contact allergy to aziridine paint hardener.
PubMed:Dermatitis from trimethylolpropane triacrylate.
PubMed:The sensitizing capacity of multifunctional acrylates in the guinea pig.
PubMed:Allergic contact dermatitis due to urethane acrylate in ultraviolet cured inks.
PubMed:Contact allergy to trimethylolpropane triacrylate (TMPTA) in an aziridine plastic hardener.
PubMed:The evaluation of new dental resins prepared with polyfunctional methacrylate monomers.
PubMed:Trimethylolpropane triacrylate.
PubMed:Trimethylolpropane trimethacrylate.
PubMed:Allergic contact dermatitis from acrylates in ultraviolet curing inks.
PubMed:[Preparation of hard crown and bridge resin without PMMA powder (III) (author's transl)].
PubMed:Allergenicity of trimethylol propane triacrylate in ultraviolet curing inks in the guinea pig.
PubMed:[Effect of cross-linking agents on mechanical properties of a fluid resin (author's transl)].
PubMed:A proposed treatment for trimethylolpropane phosphite poisoning.
PubMed:[Data on substantiation of the maximum permissible concentration of trimethylolpropane (Etriol) in the air of industrial sites].
 
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