EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

ethyl methacrylate
2-propenoic acid, 2-methyl-, ethyl ester

Supplier Sponsors

Name:ethyl 2-methylprop-2-enoate
CAS Number: 97-63-2Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:202-597-5
FDA UNII: 80F70CLT4O
Nikkaji Web:J3.576I
Beilstein Number:0471201
MDL:MFCD00009161
XlogP3:1.90 (est)
Molecular Weight:114.14410000
Formula:C6 H10 O2
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:information only not used for fragrances or flavors
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
DG SANTE Food Flavourings:09.375 ethyl methacrylate
DG SANTE Food Contact Materials:ethyl methacrylate
FDA Mainterm (IAUFC):97-63-2 ; ETHYL METHACRYLATE
 
Physical Properties:
Appearance:colorless clear liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.91000 to 0.91600 @ 25.00 °C.
Pounds per Gallon - (est).: 7.572 to 7.622
Refractive Index:1.41000 to 1.41600 @ 20.00 °C.
Boiling Point: 116.00 to 117.00 °C. @ 760.00 mm Hg
Vapor Pressure:15.218000 mmHg @ 25.00 °C. (est)
Vapor Density:4.0 ( Air = 1 )
Flash Point: 60.00 °F. TCC ( 15.56 °C. )
logP (o/w): 1.940
Soluble in:
 alcohol
 water, 2321 mg/L @ 25 °C (est)
 water, 5400 mg/L @ 25 °C (exp)
Insoluble in:
 water
 
Organoleptic Properties:
Odor Type: acrylate
acrylate
Odor Description:at 0.10 % in dipropylene glycol. acrylate
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: viscosity controlling agents
 
Suppliers:
EMD Millipore
For experimental / research use only.
Ethyl Methacrylate
Penta International
ETHYL METHACRYLATE
Santa Cruz Biotechnology
For experimental / research use only.
Ethyl methacrylate
Shiva Chemicals and Pharmaceuticals
Ethyl Methacrylate
Sigma-Aldrich: Aldrich
For experimental / research use only.
Ethyl methacrylate 99%
contains 15-20 ppm monomethyl ether hydroquinone as inhibitor
TCI AMERICA
For experimental / research use only.
Ethyl Methacrylate (stabilized with HQ)
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 11 - Highly flammable.
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
R 43 - May cause sensitisation by skin contact.
S 02 - Keep out of the reach of children.
S 16 - Keep away from sources of ignition - No Smoking.
S 23 - Do not breath vapour.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 33 - Take precautionary measures against static discharge.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
intraperitoneal-mouse LD50 1369 mg/kg
Journal of Pharmaceutical Sciences. Vol. 62, Pg. 778, 1973.

oral-mouse LD50 7836 mg/kg
Toxicology Letters. Vol. 11, Pg. 125, 1982.

oral-rabbit LD50 3630 mg/kg
LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION BEHAVIORAL: COMA BEHAVIORAL: MUSCLE WEAKNESS
Journal of Industrial Hygiene and Toxicology. Vol. 23, Pg. 343, 1941.

intraperitoneal-rat LD50 1223 mg/kg
Journal of Dental Research. Vol. 51, Pg. 1632, 1972.

oral-rat LD50 14800 mg/kg
LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION BEHAVIORAL: COMA BEHAVIORAL: MUSCLE WEAKNESS
Journal of Industrial Hygiene and Toxicology. Vol. 23, Pg. 343, 1941.

intravenous-dog LDLo 137 uL/kg
Journal of Pharmaceutical Sciences. Vol. 63, Pg. 376, 1974.

Dermal Toxicity:
skin-rabbit > 10 ml/kg
Journal of Industrial Hygiene and Toxicology. Vol. 23, Pg. 343, 1941.

subcutaneous-rat LDLo 25000 mg/kg
BEHAVIORAL: MUSCLE WEAKNESS BEHAVIORAL: COMA LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
Journal of Industrial Hygiene and Toxicology. Vol. 23, Pg. 343, 1941.

Inhalation Toxicity:
inhalation-rat LC50 8300 ppm/4H
SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE LUNGS, THORAX, OR RESPIRATION: DYSPNEA SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION
Journal of Toxicology and Environmental Health. Vol. 16, Pg. 811, 1985.

 
Safety in Use Information:
Category:
information only not used for fragrances or flavors
Recommendation for ethyl methacrylate usage levels up to:
 not for fragrance use.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.12 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI): 3900 (μg/person/day)
Threshold of Concern:540 (μg/person/day)
Structure Class: II
 
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
 average usage mg/kgmaximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0): 7.0000035.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0): 5.0000025.00000
Edible ices, including sherbet and sorbet (03.0): 10.0000050.00000
Processed fruit (04.1): 7.0000035.00000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): --
Confectionery (05.0): 10.0000050.00000
Chewing gum (05.3): --
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 5.0000025.00000
Bakery wares (07.0): 10.0000050.00000
Meat and meat products, including poultry and game (08.0): 2.0000010.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 2.0000010.00000
Eggs and egg products (10.0): --
Sweeteners, including honey (11.0): --
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 5.0000025.00000
Foodstuffs intended for particular nutritional uses (13.0): 10.0000050.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): 5.0000025.00000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 10.0000050.00000
Ready-to-eat savouries (15.0): 20.00000100.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): 5.0000025.00000
 
Safety References:
European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) on a request from the Commission related to Flavouring Group Evaluation 5: Esters of 23 branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and 24 branched- and straight-chain unsaturated carboxylic acids from chemical groups 1, 2, and 5
View page or View pdf

Flavouring Group Evaluation 5, Revision 1 (FGE.05Rev1):Esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids from chemical groups 1, 2, and 5 (Commission Regulation (EC) No 1565/2000 of 18 July 2000) [1] - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)
View page or View pdf

Flavouring Group Evaluation 62 (FGE.62) Consideration of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05 (2005) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06 (2004) (Commission Regulation (EC) No 1565/2000 of 18 July 2000)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 71: Consideration of aliphatic, linear, alpha,beta-unsaturated carboxylic acids and related esters
View page or View pdf

Flavouring Group Evaluation 72 (FGE.72): Consideration of aliphatic, branched-chain saturated and unsaturated alcohols, aldehydes, acids, and related esters evaluated by the JECFA (61st meeting) structurally related to branched- and straight-chain unsaturated carboxylic acids. Esters of these and straight-chain aliphatic saturated alcohols evaluated by EFSA in FGE.05Rev2 (2010)
View page or View pdf

Flavouring Group Evaluation 5, Revision 2 (FGE.05Rev2): Branched- and straight-chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols from chemical groups 1, 2, 3 and 5
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 5, Revision 3 (FGE.05Rev3): Branched- and straight-chain unsaturated aldehydes, dienals, unsaturated and saturated carboxylic acids and related esters with saturated and unsaturated aliphatic alcohols and a phenylacetic acid related ester from chemical groups 1, 2, 3, 5 and 15
View page or View pdf

EPI System: View
NIOSH International Chemical Safety Cards:search
Chemical Carcinogenesis Research Information System:Search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):97-63-2
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :7343
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 2277
WGK Germany:1
ethyl 2-methylprop-2-enoate
Chemidplus:0000097632
EPA/NOAA CAMEO:hazardous materials
RTECS:97-63-2
 
References:
 ethyl 2-methylprop-2-enoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:97-63-2
Pubchem (cid):7343
Pubchem (sid):134970640
Pherobase:View
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Indirect Additives used in Food Contact Substances:View
CHEMBL:View
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2916.14.2010
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
Wikipedia:View
Formulations/Preparations:
•grade: technical (inhibited). •typical inhibitor, 15 ppm monomethyl ether of hydroquinone •commercial products contain hydroquinone methyl ester or similar polymerization inhibitors. •rhoplex ac-33 (rohm and haas)
 
Potential Blenders and core components note
None Found
 
Potential Uses:
 viscosity controlling agents
 
Occurrence (nature, food, other):note
 quince
 starfruit
 
Synonyms:
 ethyl 2-methacrylate
 ethyl 2-methyl acrylate
 ethyl 2-methyl-2-propenoate
 ethyl 2-methylacrylate
 ethyl 2-methylprop-2-enoate
 ethyl 2-methylpropenoate
 ethyl alpha-methyl acrylate
 ethyl alpha-methylacrylate
 ethyl methacrylate [UN2277] [Flammable liquid]
 ethyl methylacrylate
 methacrylic acid ethyl ester
 methacrylic acid, ethyl ester
2-methyl acrylic acid ethyl ester
2-methyl-2-propenoic acid ester
2-methyl-2-propenoic acid ethyl ester
2-methyl-2-propenoic acid, ethyl ester
2-methylacrylic acid ethyl ester
2-methylacrylic acid, ethyl ester
2-propenoic acid, 2-methyl-, ethyl ester
 
 
Notes:
None found
Please share your Comments.
Email Address:
Top of Page Home
Copyright © 1980-2021 The Good Scents Company (tgsc) ™ Disclaimer Privacy Policy