acetamide
formamide, methyl-
 
Notes:
Acetamide (or acetic acid amide or ethanamide), CH3CONH2, the amide of acetic acid, is a white crystalline solid in pure form. It is produced by dehydrating ammonium acetate:
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      01-02200 ACETAMIDE, Kosher
       
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acetamide (Click)
CAS Number: 60-35-5Picture of molecule
ECHA EINECS - REACH Pre-Reg: 200-473-5
FDA UNII: 8XOE1JSO29
Nikkaji Web: J2.339F
Beilstein Number: 1071207
MDL: MFCD00008023
XlogP3-AA: -0.90 (est)
Molecular Weight: 59.06805000
Formula: C2 H5 N O
BioActivity Summary: listing
NMR Predictor: Predict (works with chrome or firefox)
Category: food contact closures with sealing gaskets for food containers
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
IBM Patents: Obtain
Pubchem Patents: Search
PubMed: Search
NCBI: Search
FEMA Number: 4251
FDA Mainterm: ACETAMIDE
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Physical Properties:
Appearance: white to pale yellow crystalline powder (est)
Assay: 99.00 to 100.00 % 
Food Chemicals Codex Listed: No
Melting Point: 79.00 to  81.00 °C. @ 760.00 mm Hg
Boiling Point: 221.00 to  222.00 °C. @ 760.00 mm Hg
Vapor Pressure: 1.000000 mm/Hg @ 65.00 °C.
Flash Point: > 212.00 °F. TCC ( > 100.00 °C. )
logP (o/w): -1.260
Soluble in:
 alcohol
 water, 1e+006 mg/L @ 25 °C (est)
 water, 2.25E+06 mg/L @ 25 °C (exp)
Similar Items: note
acetamide MEA
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Organoleptic Properties:
Odor Description:
bland
  
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: not used anymore
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Suppliers:
Aceto
Acetamide
Parchem
acetamide
Penta International
ACETAMIDE, Kosher
Sigma-Aldrich: Aldrich
For experimental / research use only.
Acetamide sublimed, 99%
TCI AMERICA
For experimental / research use only.
Acetamide >98.0%(GC)
Viachem
Acetamide
Odor: bland
Use: Acetamide is an organic compound with the formula CH3CONH2. It is the simplest amide derived from acetic acid. Acetamide is used as a co-monomer in the production of polymeric materials such as polyvinyl acetamide, a polymeric product used as an absorbent. It finds some use as a plasticizer and as an industrial solvent.
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Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xn - Harmful.
R 36/37 - Irritating to eyes and respiratory system.
R 40 - Possible risks of irreversable effects.
S 02 - Keep out of the reach of children.
S 23 - Do not breath vapour.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50  7000 mg/kg
Oyo Yakuri. Pharmacometrics. Vol. 4, Pg. 451, 1970.

intravenous-rat LD50  12500 mg/kg
Oyo Yakuri. Pharmacometrics. Vol. 4, Pg. 451, 1970.

intraperitoneal-rat LD50  10300 mg/kg
LUNGS, THORAX, OR RESPIRATION: DYSPNEA BEHAVIORAL: MUSCLE WEAKNESS BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)
Arzneimittel-Forschung. Drug Research. Vol. 20, Pg. 1242, 1970.

intravenous-rabbit LD50  7500 mg/kg
SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
Nippon Yakurigaku Zasshi. Japanese Journal of Pharmacology. Vol. 64(1), Pg. 42S, 1968.

oral-mouse LD50  12900 mg/kg
PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE
Nippon Yakurigaku Zasshi. Japanese Journal of Pharmacology. Vol. 64(1), Pg. 42S, 1968.

intravenous-mouse LD50  10000 mg/kg
SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
Nippon Yakurigaku Zasshi. Japanese Journal of Pharmacology. Vol. 64(1), Pg. 42S, 1968.

intraperitoneal-mouse LD50  1000 mg/kg
JNCI, Journal of the National Cancer Institute. Vol. 62, Pg. 911, 1979.

intravenous-chicken LDLo  33410 mg/kg
Arzneimittel-Forschung. Drug Research. Vol. 20, Pg. 1242, 1970.

intravenous-rat LD50  12500 mg/kg
PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE
Nippon Yakurigaku Zasshi. Japanese Journal of Pharmacology. Vol. 64(1), Pg. 42S, 1968.

oral-rat LD50  7000 mg/kg
Journal of Reproduction and Fertility. Vol. 4, Pg. 219, 1962.

Dermal Toxicity:
subcutaneous-rat LD50 10000 mg/kg
AUTONOMIC NERVOUS SYSTEM: "SMOOTH MUSCLE RELAXANT (MECHANISM UNDEFINED, SPASMOLYTIC)" PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE) CARDIAC: CHANGE IN RATE
Oyo Yakuri. Pharmacometrics. Vol. 4, Pg. 451, 1970.

subcutaneous-mouse LD50 8300 mg/kg
AUTONOMIC NERVOUS SYSTEM: "SMOOTH MUSCLE RELAXANT (MECHANISM UNDEFINED, SPASMOLYTIC)" CARDIAC: CHANGE IN RATE PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE)
Oyo Yakuri. Pharmacometrics. Vol. 4, Pg. 451, 1970.

Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: food contact closures with sealing gaskets for food containers
Recommendation for acetamide usage levels up to:
 not for fragrance use.
 
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 22
Click here to view publication 22
 average usual ppmaverage maximum ppm
baked goods: 1.000005.00000
beverages(nonalcoholic): --
beverages(alcoholic): --
breakfast cereal: 0.200001.00000
cheese: 0.400002.00000
chewing gum: --
condiments / relishes: 0.100000.50000
confectionery froastings: 1.000005.00000
egg products: --
fats / oils: 0.100000.50000
fish products: 0.200001.00000
frozen dairy: 0.400002.00000
fruit ices: 0.400002.00000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: 0.200001.00000
milk products: 0.400002.00000
nut products: --
other grains: 0.200001.00000
poultry: 0.200001.00000
processed fruits: 0.400002.00000
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: 0.100000.50000
snack foods: 1.000005.00000
soft candy: --
soups: 0.100000.50000
sugar substitutes: --
sweet sauces: --
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Safety References:
European Food Safety Authority (EFSA) reference(s):
Flavouring Group Evaluation 86, (FGE.86)[1] - Consideration of aliphatic and aromatic amines and amides evaluated by JECFA (65th meeting) - Scientific Opinion of the Panel on Food Additives - Flavourings, Processing Aids and Materials in Contact with Food
View page or View pdf
EPI System: View
NIOSH International Chemical Safety Cards: search
NLM Hazardous Substances Data Bank: Search
Chemical Carcinogenesis Research Information System: Search
AIDS Citations: Search
Cancer Citations: Search
Toxicology Citations: Search
Carcinogenic Potency Database: Search
EPA GENetic TOXicology: Search
Env. Mutagen Info. Center: Search
NLM Developmental and Reproductive Toxicity: Search
EPA Substance Registry Services (TSCA): 60-35-5
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 178
National Institute of Allergy and Infectious Diseases: Data
SCCNFP: opinion
WISER: UN 3077
WGK Germany: 1
 acetamide
Chemidplus: 0000060355
EPA/NOAA CAMEO: hazardous materials
RTECS: 60-35-5
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References:
 acetamide
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 60-35-5
Pubchem (cid): 178
Pubchem (sid): 134972933
Pherobase: View
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS): View
CHEBI: View
CHEMBL: View
UM BBD: Search
KEGG (GenomeNet): C06244
HMDB (The Human Metabolome Database): HMDB31645
FooDB: FDB008298
YMDB (Yeast Metabolome Database): YMDB01563
Export Tariff Code: 2924.10.1050
FDA Listing of Food Additive Status: View
Haz-Map: View
ChemSpider: View
Wikipedia: View
RSC Learn Chemistry: View
Read: Under the conditions of intended use - New developments in the FEMA GRAS program and the safety assessment of flavor ingredients
Read: A GRAS assessment program for flavor ingredients
Read: Sensory testing for flavorings with modifying properties. Food Technology
Read: Criteria for the safety evaluation of flavoring substances
Read: A procedure for the safety evaluation of natural flavor complexes used as ingredients in food: essential oils
Read: FEMA Expert Panel: 30 Years of safety evaluation for the flavor industry
Read: Consumption ratio and food predominance of flavoring materials
Formulations/Preparations:
in 1963 available in usa as technical grade (99% minimum acetamide & 0.3% maximum free acid) & as chemically pure, odorless grade (99.5-99.9% acetamide & trace of free acid). grades: technical; cp chemically pure: a grade designation signifying a minimum of impurities, but not 100% purity (odorless); intermediate; reagent.
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Potential Blenders and core components note
 
None Found
 
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Potential Uses:
 cereal 
 cheese 
 dairy 
 fish 
 fruitFR
 meat 
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Occurrence (nature, food, other): note
 not found in nature
 beet root
Search Trop  Picture
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Synonyms:
 acetic acid amide
 ethanamide
 formamide, methyl-
 methane carboxamide
 methanimidic acid, methyl-
 methylcarbylamine
monomethylformamide
 methylimidoformic acid
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Articles:
PubMed: Pellet cryopreservation for chicken semen: effects of sperm working concentration, cryoprotectant concentration, and equilibration time during in vitro processing.
PubMed: The postprandial plasma rye fingerprint includes benzoxazinoid-derived phenylacetamide sulfates.
PubMed: Inhibition of β-N-acetylglucosaminidase by acetamide affects sperm motility and fertilization success of rainbow trout (Oncorhynchus mykiss) and Siberian sturgeon (Acipenser baerii).
PubMed: The TRPA1 agonist, methyl syringate suppresses food intake and gastric emptying.
PubMed: Ammoxidation of lignocellulosic materials: formation of nonheterocyclic nitrogenous compounds from monosaccharides.
PubMed: Can the unauthorised use of ceftiofur be detected in poultry?
PubMed: Synthesis and anticonvulsant and antidepressant activity of 2-(5-bromo-2,3-dioxoindolin)-N-substituted phenylacetamide derivatives.
PubMed: Comparative analysis of flagellin glycans among pathovars of phytopathogenic Pseudomonas syringae.
PubMed: Hydroxylated phenylacetamides derived from bioactive benzoxazinoids are bioavailable in humans after habitual consumption of whole grain sourdough rye bread.
PubMed: Molecular and behavioral pharmacology of two novel orally-active 5HT2 modulators: potential utility as antipsychotic medications.
PubMed: SEPALLATA1/2-suppressed mature apples have low ethylene, high auxin and reduced transcription of ripening-related genes.
PubMed: Biodegradation of butachlor by Rhodococcus sp. strain B1 and purification of its hydrolase (ChlH) responsible for N-dealkylation of chloroacetamide herbicides.
PubMed: Inclusion of 1-naphthylacetic acid and 2-(1-naphthyl)acetamide into three typical multiresidue methods for LC/MS/MS analysis of tomatoes and zucchini.
PubMed: New nitrogen-containing bromophenols from the marine red alga Rhodomela confervoides and their radical scavenging activity.
PubMed: Isolation, identification and characterization of human intestinal bacteria with the ability to utilize chloramphenicol as the sole source of carbon and energy.
PubMed: Radiation dosimetry and biodistribution of the TSPO ligand 11C-DPA-713 in humans.
PubMed: Forced degradation study of thiocolchicoside: characterization of its degradation products.
PubMed: Assessment of liquid chromatography-tandem mass spectrometry approaches for the analysis of ceftiofur metabolites in poultry muscle.
PubMed: Activity of meadowfoam (Limnanthes alba) seed meal glucolimnanthin degradation products against soilborne pathogens.
PubMed: Discriminating multiple impacts of biogas residues amendment in selectively decontaminating chloroacetanilide herbicides.
PubMed: Biodegradation of chloroacetamide herbicides by Paracoccus sp. FLY-8 in vitro.
PubMed: Fate and efficacy of metolachlor granular and emulsifiable concentrate formulations in a conservation tillage system.
PubMed: T-type calcium channel antagonism decreases motivation for nicotine and blocks nicotine- and cue-induced reinstatement for a response previously reinforced with nicotine.
PubMed: A concise synthesis of 1,4-dihydro-[1,4]diazepine-5,7-dione, a novel 7-TM receptor ligand core structure with melanocortin receptor agonist activity.
PubMed: Antagonist selective modulation of adenosine A1 and A3 receptor pharmacology by the food dye Brilliant Black BN: evidence for allosteric interactions.
PubMed: Identification of Pseudomonas aeruginosa in water-bottling plants on the basis of procedures included in ISO 16266:2006.
PubMed: Reduction in metolachlor and degradate concentrations in shallow groundwater through cover crop use.
PubMed: Reactivity of 1-deoxy-D-erythro-hexo-2,3-diulose: a key intermediate in the maillard chemistry of hexoses.
PubMed: 2-[(2,3-dihydro-1H-indol-1-yl)methyl]melatonin analogues: a novel class of MT2-selective melatonin receptor antagonists.
PubMed: Runoff and leaching of metolachlor from Mississippi River alluvial soil during seasons of average and below-average rainfall.
PubMed: 2-Chloro-N,N-diphenyl-acetamide.
PubMed: Characterization of metabolites of fungicidal cymoxanil in a sensitive strain of Botrytis cinerea.
PubMed: A dose-ranging study of the pharmacokinetics and pharmacodynamics of the selective apoptotic antineoplastic drug (SAAND), OSI-461, in patients with advanced cancer, in the fasted and fed state.
PubMed: The conversion of chicken manure to bio-oil by fast pyrolysis. III. Analyses of chicken manure, bio-oils and char by Py-FIMS and Py-FDMS.
PubMed: Suitability of two laboratory testing methods to evaluate the side effects of pesticides on Typhlodromus pyri Scheuten (Acari: Phytoseiidae).
PubMed: Synthesis and antimicrobial activity of some derivatives of (7-hydroxy-2-oxo-2H-chromen-4-yl)-acetic acid hydrazide.
PubMed: Detection of Pseudomonas aeruginosa in water samples using a novel synthetic medium and impedimetric technology.
PubMed: Cytotoxicity of chloroacetanilide herbicide alachlor in HepG2 cells independent of CYP3A4 and CYP3A7.
PubMed: Effects of atypical anxiolytic N-phenyl-2-[1-[3-(2-pyridinylethynyl)benzoyl]-4-piperidine]acetamide (JNJ-5234801) on alcohol intake in alcohol-preferring P rats.
PubMed: Identification of metabolites produced from N-phenylpiperazine by Mycobacterium spp.
PubMed: One-pot synthesis of macrocycles by a tandem three-component reaction and intramolecular [3+2] cycloaddition.
PubMed: Felinine stability in the presence of selected urine compounds.
PubMed: Degradation of chloroacetanilide herbicides by anodic fenton treatment.
PubMed: QSAR models for Daphnia magna toxicity prediction of benzoxazinone allelochemicals and their transformation products.
PubMed: Joint action of benzoxazinone derivatives and phenolic acids.
PubMed: Degradation of alachlor in natural and sludge-amended soils, studied by gas and liquid chromatography coupled to mass spectrometry (GC-MS and HPLC-MS).
PubMed: Synthesis of new benzoxazinone derivatives as neuropeptide Y5 antagonists for the treatment of obesity.
PubMed: Effect of processing on Celecoxib and its solvates.
PubMed: [Modafinil and fatigue in multiple sclerosis].
PubMed: Application of micellar electrokinetic capillary chromatography to the analysis of uncharged pesticides of environmental impact.
PubMed: Kinetic evidence related to substrate-assisted catalysis of family 18 chitinases.
PubMed: Kinetics and mechanism of the nucleophilic displacement reactions of chloroacetanilide herbicides: investigation of alpha-substituent effects.
PubMed: Kinetics and mechanism of cymoxanil degradation in buffer solutions.
PubMed: Reaction mechanism of chitobiose phosphorylase from Vibrio proteolyticus: identification of family 36 glycosyltransferase in Vibrio.
PubMed: Indole derivatives produced by the fungus Colletotrichum acutatum causing lime anthracnose and postbloom fruit drop of citrus.
PubMed: Multilaboratory trial for determination of ceftiofur residues in bovine and swine kidney and muscle, and bovine milk.
PubMed: Determination of triazine and chloroacetanilide herbicides in soils by microwave-assisted extraction (MAE) coupled to gas chromatographic analysis with either GC-NPD or GC-MS.
PubMed: Analysis and detection of the herbicides dimethenamid and flufenacet and their sulfonic and oxanilic acid degradates in natural water.
PubMed: Runoff and drainage losses of atrazine, metribuzin, and metolachlor in three water management systems.
PubMed: NMR and MS analysis of decomposition compounds produced from N-acetyl-L-glutamine at low pH.
PubMed: Comparison of enzyme-linked immunosorbent assay and gas chromatography procedures for the detection of cyanazine and metolachlor in surface water samples.
PubMed: Tillage, intercrop, and controlled drainage-subirrigation influence atrazine, metribuzin, and metolachlor loss.
PubMed: Development of a gas chromatographic method for fungicide cymoxanil analysis in dried hops.
PubMed: Prediction of interindividual variation in drug plasma levels in vivo from individual enzyme kinetic data and physiologically based pharmacokinetic modeling.
PubMed: Structural influences in relative sorptivity of chloroacetanilide herbicides on soil.
PubMed: Pressurized fluid extraction for quantitative recovery of chloroacetanilide and nitrogen heterocyclic herbicides in soil.
PubMed: Photodegradation of metolachlor: isolation, identification, and quantification of monochloroacetic acid.
PubMed: Methylene group modifications of the N-(Isothiazol-5-yl)phenylacetamides. Synthesis and insecticidal activity.
PubMed: Identification of the major urinary and fecal metabolites of 3,5-dinitrobenzamide in chickens and rats.
PubMed: A novel, selective synthetic acetamide containing culture medium for isolating Pseudomonas aeruginosa from milk.
PubMed: Metabolism of metolachlor by the fungus Cunninghamella elegans.
PubMed: Effects of anticonvulsants in a novel operant learning paradigm in rats: comparison of remacemide hydrochloride and FPL 15896AR to other anticonvulsant agents.
PubMed: Determination of ephedrine, pseudoephedrine, and norephedrine in mixtures (bulk and dosage forms) by proton nuclear magnetic resonance spectroscopy.
PubMed: Friedländer synthesis of the food carcinogen 2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine.
PubMed: Purification and characterization of an amidase from an acrylamide-degrading Rhodococcus sp.
PubMed: Oncogenicity studies of the cognition-enhancing agent nefiracetam in mice and rats.
PubMed: Drug dependence study of the new cognition-enhancing agent nefiracetam in rats.
PubMed: Reproductive toxicity studies of the new cognition-enhancing agent nefiracetam in rats and rabbits.
PubMed: Thirteen-week oral toxicity study of the new cognition-enhancing agent nefiracetam in dogs.
PubMed: Evaluation of neuroprotection and behavioral recovery by the kappa-opioid, PD117302 following transient forebrain ischemia.
PubMed: Enhancement of the prophagic but not of the antidipsogenic effect of U-50, 488H after chronic amphetamine.
PubMed: An analytical study of antibacterial residues in meat: the simultaneous determination of 23 antibiotics and 13 drugs using gas chromatography.
PubMed: Single- and multiple-dose pharmacokinetics of nefiracetam, a new nootropic agent, in healthy volunteers.
PubMed: Metabolism of acrylonitrile by Klebsiella pneumoniae.
PubMed: Rapid and uniform electromagnetic heating of aqueous cryoprotectant solutions from cryogenic temperatures.
PubMed: A synthetic, selective culture medium for Pseudomonas aeruginosa.
PubMed: Inhibition of spontaneous growth and induced differentiation of murine erythroleukaemia cells by paraquat and atrazine.
PubMed: Orally administered kappa but not mu opiate agonists enhance gastric emptying of a solid canned food meal in dogs.
PubMed: Discriminative stimulus properties of physostigmine in rats.
PubMed: The kappa agonists PD117302 and U50488 produce a biphasic effect on 24 hour food intake in the rat.
PubMed: Simultaneous gas chromatographic determination of carboxylic acids in soft drinks and jams.
PubMed: Pharmacokinetics of acetohydroxamic acid in patients with staghorn renal calculi.
PubMed: Metabolism of AC 206,784 herbicide [2-chloro-N-(2,3-dimethylphenyl)-N-(1-methylethyl)acetamide] in soybean plants.
PubMed: Residues of the plant growth regulator mefluidide [N-[2,4]dimethy-5-[[(trifluoromethyl)sulfonyl]amino]phenyl]acetamide] in the milk and tissues of lactating dairy cows: a 28-day feeding study.
PubMed: Fate of the plant growth regulator mefluidide [N-[2,4-dimethyl-5-[[(trifluoromethyl)sulfonyl]amino]phenyl]acetamide] in a cow and sheep.
PubMed: 2-Cyano-N-[(ethylamino)carbonyl]-2-(methoxyimino)acetamide, a new fungicide.
PubMed: Gas-liquid chromatographic/mass spectrometric screening method for T-2 toxin in milk.
PubMed: Excretion and metabolism of 3,4,5-tribromo-N,N,alpha-trimethyl-1H-pyrazole-1-acetamide in the rat.
PubMed: Gas-liquid chromatographic determination of vinyl chloride in vinyl chloride polymers, food-simulating solvents, and other samples.
PubMed: Gas-liquid chromatographic determination of diethylstilbestrol in molasses-based liquid feed supplements.
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