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Category:herbicides / pesticides
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | light brown powder (est) |
| Assay: | 95.00 to 100.00
|
| Food Chemicals Codex Listed: | No |
| Melting Point: | 172.00 °C. @ 760.00 mm Hg
|
| Vapor Pressure: | 7.130000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 32.00 °F. TCC ( 0.00 °C. ) (est)
|
| logP (o/w): | 1.400 |
| Soluble in: |
| | water, 26.6 mg/L @ 20 °C (exp) | | | water, 438.9 mg/L @ 25 °C (est) |
Organoleptic Properties:
| Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-dog LDLo 4000 mg/kg BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
SENSE ORGANS AND SPECIAL SENSES: MYDRIASIS (PUPILLARY DILATION): EYE Toxicology and Applied Pharmacology. Vol. 23, Pg. 606, 1972.
oral-guinea pig LD50 3640 mg/kg BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
SENSE ORGANS AND SPECIAL SENSES: MYDRIASIS (PUPILLARY DILATION): EYE Toxicology and Applied Pharmacology. Vol. 23, Pg. 606, 1972.
intraperitoneal-mouse LD50 790 mg/kg BEHAVIORAL: TREMOR
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
SENSE ORGANS AND SPECIAL SENSES: CHANGE IN OLFACTORY NERVE: OLFACTION Toxicology and Applied Pharmacology. Vol. 23, Pg. 606, 1972.
oral-mouse LD50 3400 mg/kg BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
SENSE ORGANS AND SPECIAL SENSES: CHANGE IN OLFACTORY NERVE: OLFACTION
BEHAVIORAL: TREMOR Toxicology and Applied Pharmacology. Vol. 23, Pg. 606, 1972.
oral-rabbit LD50 2270 mg/kg BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
SENSE ORGANS AND SPECIAL SENSES: MYDRIASIS (PUPILLARY DILATION): EYE Toxicology and Applied Pharmacology. Vol. 23, Pg. 606, 1972.
intraperitoneal-rat LD50 1140 mg/kg SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE
SENSE ORGANS AND SPECIAL SENSES: CHANGE IN OLFACTORY NERVE: OLFACTION
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Toxicology and Applied Pharmacology. Vol. 23, Pg. 606, 1972.
oral-rat LD50 6640 mg/kg SENSE ORGANS AND SPECIAL SENSES: CHANGE IN OLFACTORY NERVE: OLFACTION
SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Toxicology and Applied Pharmacology. Vol. 23, Pg. 606, 1972.
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| Dermal Toxicity: |
skin-guinea pig LD50 > 10000 mg/kg Japan Pesticide Information. Vol. (5), Pg. 38, 1970.
skin-mouse LD50 > 10000 mg/kg Japan Pesticide Information. Vol. (5), Pg. 38, 1970.
skin-quail LD50 > 5000 mg/kg Pesticide Manual. Vol. 9, Pg. 820, 1991.
skin-rabbit LD50 > 10000 mg/kg Japan Pesticide Information. Vol. (5), Pg. 38, 1970.
skin-rat LD50 > 10000 mg/kg Japan Pesticide Information. Vol. (5), Pg. 38, 1970.
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| Inhalation Toxicity: |
inhalation-rat LC50 1700 mg/m3/4H Farm Chemicals Handbook. Vol. -, Pg. C302, 1991.
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Safety in Use Information:
| Category: | | herbicides / pesticides |
| Recommendation for thiophanate-methyl usage levels up to: | | | not for fragrance use.
|
| |
| Recommendation for thiophanate-methyl flavor usage levels up to: |
| | not for flavor use.
|
Safety References:
European Food Safety Authority (EFSA) reference(s):
|
Reasoned opinion on the review of the existing maximum residue levels (MRLs) for thiophanate-methyl and carbendazim according to Article 12 of Regulation (EC) No 396/2005 View page or View pdf
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Peer review of the pesticide risk assessment of the active substance thiophanate-methyl View page or View pdf
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Reasoned opinion on the toxicological properties and maximum residue levels (MRLs) for the benzimidazole substances carbendazim and thiophanate-methyl View page or View pdf
|
| EPI System: View |
| EPA-Iris:IRIS |
| Chemical Carcinogenesis Research Information System:Search |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA GENetic TOXicology:Search |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :3032791 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:2 |
| methyl N-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate |
| Chemidplus:0023564058 |
| EPA/NOAA CAMEO:hazardous materials |
| RTECS:BA3675000 for cas# 23564-05-8 |
References:
| | methyl N-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 23564-05-8 |
| Pubchem (cid): | 3032791 |
| Pubchem (sid): | 134994909 |
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| CHEBI: | View |
| CHEMBL: | View |
| KEGG (GenomeNet): | C14432 |
| HMDB (The Human Metabolome Database): | Search |
| ChemSpider: | View |
| Wikipedia: | View |
Formulations/Preparations: •usepaopp pesticide code 102001; trade names: topsin, cercobin m, banrot, component of (with 084701), fungo, td-1771, nf-44, enovit methyl.
•thiophanate-methyl formulations include dust, granular, wettable powder, water-dispersible granular, and flowable concentrate, ranging from 1.5% to 90% active ingredient.
•wettable powder, paste, flowable, granule, dust, ulv.
•tops mz potato dee-piece treatment fungicide; active ingredients 6.00% mancozeb and 2.50% thiophanate-methyl
•evolve potato seed piece treatment fungicide; active ingredients 6.00% mancozeb, 2.50% thiophanate-methyl, and 1.00% cymoxanil
•tops-mz-gaucho potato seed-piece treament; active ingredients 6.00% mancozeb, 2.50% thiophanate-methyl, and 1.25% imidacloprid
•tops 30 flowable fungicide; active ingredient 30.00% thiophanate-methyl
•four way peanut seed treatment fungicide; 49.00% captan, 13.60% thiophanate-methyl, 0.80% metalaxyl, and 2.00% trifloxystrobin
•2636 fungicide; active ingredients 19.65% thiophanate-methyl and 19.65% iprodione
•sysstar wdg; active ingredients 28.58% thiophanate-methyl and 51.42% flutolanil
•systemic fungicide; active ingredient 2.30% thiophanate-methyl
•proturf fertilizer plus dsb fungicide; active ingredient 1.75% thiophanate-methyl
•proturf fluid fungicide; 19.65% thiophanate-methyl and 19.65% iprodione
•3336 wp turf and ornamental fungicide; active ingredient 50.00% thiophanate-methyl
•3336 f; active ingredient 41.25% thiophanate-methyl
•3336 g; active ingredient 2.08% thiophanate-methyl
•spectro 90 wdg; active ingredients 72.00% chlorothalonil and 18.00% thiophanate-methyl
•3336 plus systemic fungicide; active ingredient 19.40% thiophanate-methyl
•premium systemic fungicide; active ingredient 44.62% thiophanate-methyl
•3336 (r) 70eg; active ingredient 70.00% thiophanate-methyl
•thiophanate-methyl 45% f fungicide; active ingredient 46.20% thiophanate-methyl
•thiophanate-methyl 50% wsb fungicide; active ingredient 50.00% thiophanate-methyl
•andersons golf products fungicide ix; active ingredients 3.26% chloroneb and 1.63% thiophanate-methyl
•andersons golf products fungo flo; active ingredient 45.00% thiophanate-methyl
•andersons golf products fertilizer plus fungicide viii; active ingredients 2.05% thiophanate-methyl and 1.02% iprodione
•andersons golf products fluid fungicide; active ingredients 19.65% thiophanate-methyl and 19.65% iprodione
•thiofan 8 methyl 4.5 fungicide; active ingredient 46.20% thiophanate-methyl
•thio-m 50 wsb fungicide; active ingredient 50.00% thiophanate-methyl
•lpi thio-m 70 wsb; active ingredient 70.00% thiophanate-methyl
•lpi thio-m ag 4.5f; active ingredient 46.20% thiophanate-methyl
•et-003; active ingredient 98.00% thiophanate-methyl
•consyst wdg; active ingredients 50.00% chlorothalonil and 16.66% thiophanate-methyl
•systec 1998 fl; active ingredient 46.20% thiophanate-methyl
•systec 1998 wdg; active ingredient 85.00% thiophanate-methyl
•t-methyl g-pro granular; active ingredient 2.08% thiophanate-methyl
•banrot broad spectrum fungicide 40% wettable powder; active ingredients 15.00% etridiazole and 25.00% thiophanate-methyl
•banrot 8 g fungicide; active ingredients 3.00% etridiazole and 5.00% thiophanate-methyl
•fungo 50 wsb wettable powder turf & ornamental systemic fungicide; active ingredient 50.00% thiophanate-methyl
•duosan wsb wettable powder turf and ornamental fungicide; active ingredients 64.00% mancozeb and 15.60% thiophanate-methyl
•duosan broad spectrum contact turf fungicide; active ingredients 64.00% mancozeb and 15.60% thiophanate-methyl
•domain fl; active ingredient 46.20% thiophanate-methyl
•ohp 4.5 l fungicide; active ingredient 46.20% thiophanate-methyl
•ohp 50 wp fungicide; active ingredient 50.00% thiophante-methyl
•thiophanate methyl 4.5 f; active ingredient 46.20% thiophanate-methyl
•thiophanate methyl 85 wdg; active ingredient 85.00% thiophanate-methyl
•thiophanate methyl 70w; active ingredient 70.00% thiophanate-methyl
•thiophanate methyl 4.5l; active ingredient 46.20% thiophanate-methyl
•thiophanate methyl 50w; active ingredient 50.00% thiophanate-methyl
•thiophanate methyl 70w wsb; active ingredient 70.00% thiophanate-methyl
•thiophanate methyl 98% tech; active ingredient 98.30% thiophanate-methyl
•iprodione thiophanate methyl combo; active ingredients 19.65% thiophanate-methyl and 19.65% iprodione
•thiophanate methyl 85eg; active ingredient 85.00% thiophanate-methyl
•thiophanate methyl 4.5f ag; active ingredient 46.20% thiophanate-methyl
•transom 50 wsb; active ingredient 50.00% thiophanate-methyl
•transom 4.5 f; active ingredient 46.20% thiophanate-methyl
•topsin m technical; active ingredient 97.00% thiophanate-methyl
•fanate 70wsb; active ingredient 70.00% thiophanate-methyl
•topsin m 70wp; active ingredient 70.00% thiophanate-methyl
•topsin m 5d fungicide; active ingredient 5.00% thiophanate-methyl
•topsin 4.5 fl; active ingredient 45.00% thiophanate-methyl
•topsin m 5g fungicide; active ingredient 5.00% thiophanate-methyl
•topsin m 85 wdg; active ingredient 85.00% thiophanate-methyl
•topsin m wsb; active ingredient 70.00% thiophanate-methyl
•topsin m 70wdg; active ingredient 70.00% thiophanate-methyl
•tebuconazoletopsin premix; active ingredients 37.50% thiophanate-methyl and 7.50% 1h-1,2,4-triazole-1-ethanol, .alpha.-(2-(4-chlorophenyl)ethyl)-.alpha.-(1,1-dimethylethyl)-, (+-)
•t-methyl e-pro 4.5 f fungicide; active ingredient 46.20% thiophanate-methyl
•t-methyl e-pro 50 wsb fungicide; active ingredients 50.00% thiophanate-methyl
•tm ip e-pro fungicide; active ingredients 19.65% thiophanate-methyl and 19.65% iprodione
•t-methyl e-pro granular fungicide; active ingredient 2.08% thiophanate-methyl
•tm + ctn e-pro 66.6 wdg fungicide; active ingredients 50.00% chlorothalonil and 16.66% thiophanate-methyl
•tm + ctn e-pro 90 wdg fungicide; active ingredients 72.00% chlorothalonil and 18.00% thiophanate-methyl
•t-methyl e-ag 4.5 f fungicide; active ingredient 46.20% thiophanate-methyl
•t-methyl e-ag 70 wsb fungicide; active ingredient 70.00% thiophanate-methyl
•t-bird 85 wdg; active ingredient 85.00% thiophanate-methyl
•t-bird 4.5l; active ingredient 46.20% thiophanate-methyl
•peregrine; active ingredients 50.00% chlorothalonil and 16.66% thiophanate-methyl
•dovetail; active ingredients 19.65% thiophanate-methyl and 19.65% iprodione
•tee-off 4.5f; active ingredient 46.20% thiophanate-methyl
•tee-1 up wdg fungicide; active ingredients 50.00% chlorothalonil and 16.66% thiophanate-methyl
•nations ag ii thiophanate-methyl technical; active ingredient 99.00% thiophanate-methyl
•greenleaf lawn fungus control; active ingredient 2.30% thiophanate-methyl
•thiophanate-methyl 85% wdg; active ingredient 85.00% thiophanate-methyl
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Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | allophanic acid, 4,4'-o-phenylenebis(3-thio-, dimethyl ester | | | caligran | | | carbamic acid, (1,2-phenylenebis(iminocarbonothioyl))bis-, dimethyl ester | | | carbamic acid, (1,2-phenylenebis(iminocarbonothioyl)bis-, dimethyl ester | | | cercobin M | | | cercobin methyl | | 1,2- | di-(3-methoxycarbonyl-2-thioureido)benzene | | | dimethyl ((1,2-phenylene)bis-(iminocarbonothioyl))bis(carbamate) | | | dimethyl ((1,2-phenylene)bis(iminocarbonothioyl))bis(carbamate) | | | dimethyl 4,4'-o-phenylenebis(3-thioallophanate) | | | ditek | | | enovit M | | | enovit methyl | | | fungo | | | fungo 50 | | o-bis(3- | methoxycarbonyl-2-thioureido)benzene | | 1,2-bis(3-( | methoxycarbonyl)-2-thioureido)benzene | | 1,2-bis( | methoxycarbonylthioureido)benzene | | | methyl N-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate | | | methyl thiophanate | | | methyl topsin | | | methylthiofanate | | | methylthiophanate | | | metoben | | | mildothane | | | neotopsin | | | PELT 14 | | | PELT-44 | | | sipcaplant | | | sipcasan | | | sipcavit | | | thiophanate M | | | thiophanate methyl | | | tiofanate metile | | | topsin M | | | topsin Methyl | | | topsin NF 44 | | | topsin NF-44 | | | topsin WP methyl | | | topsin-M |
Articles:
| PubMed:Isolation and Characterization of the Colletotrichum acutatum ABC Transporter CaABC1. |
| PubMed:Sensitivity of Podosphaera xanthii populations to anti-powdery-mildew fungicides in Spain. |
| PubMed:A variety of pesticides trigger in vitro α-synuclein accumulation, a key event in Parkinson's disease. |
| PubMed:Independent Emergence of Resistance to Seven Chemical Classes of Fungicides in Botrytis cinerea. |
| PubMed:Methyl-thiophanate increases reactive oxygen species production and induces genotoxicity in rat peripheral blood. |
| PubMed:Multiresidue determination of 256 pesticides in lavandin essential oil by LC/ESI/sSRM: advantages and drawbacks of a sampling method involving evaporation under nitrogen. |
| PubMed:Simultaneous determination of thiophanate-methyl and its metabolite carbendazim in tea using isotope dilution ultra performance liquid chromatography-tandem mass spectrometry. |
| PubMed:Influence of different planting seasons of six leaf vegetables on residues of five pesticides. |
| PubMed:Simultaneous quantification of alleles E198A and H6Y in the β-tubulin gene conferring benzimidazole resistance in Monilinia fructicola using a duplex real-time (TaqMan) PCR. |
| PubMed:MSPD sample preparation approach for reversed-phase liquid chromatographic analysis of pesticide residues in stem of coconut palm. |
| PubMed:Salting-out assisted liquid-liquid extraction with the aid of experimental design for determination of benzimidazole fungicides in high salinity samples by high-performance liquid chromatography. |
| PubMed:Spinach or amaranth may represent highest residue of thiophanate-methyl with open field application on six leaf vegetables. |
| PubMed:Effect of preharvest anti-fungal compounds on Aspergillus steynii and A. carbonarius under fluctuating and extreme environmental conditions. |
| PubMed:Unlikely remedy: fungicide clears infection from pathogenic fungus in larval southern leopard frogs (Lithobates sphenocephalus). |
| PubMed:Rational coformer or solvent selection for pharmaceutical cocrystallization or desolvation. |
| PubMed:[Determination of thiophanate-methyl and carbendazim in cucumber and soil by QuEChERS-high performance liquid chromatography-triple quadrupole tandem mass spectrometry]. |
| PubMed:[Rapid determination of 6 pesticide residues in tomato paste by ultra performance liquid chromatography-tandem mass spectrometry]. |
| PubMed:Characterization of Paecilomycescinnamomeus from the camellia whitefly, Aleurocanthus camelliae (Hemiptera: Aleyrodidae), infesting tea in Japan. |
| PubMed:Evaluation of fungicides for the management of Botryosphaeria dieback diseases of grapevines. |
| PubMed:Investigating phenotypic variability in Colletotrichum lindemuthianum populations. |
| PubMed:The impact of pesticides on the pathogen Batrachochytrium dendrobatidis independent of potential hosts. |
| PubMed:The genetic profile and molecular diagnosis of thiophanate-methyl resistant strains of Fusarium asiaticum in Japan. |
| PubMed:Testicular toxicity of methyl thiophanate in the Italian wall lizard (Podarcis sicula): morphological and molecular evaluation. |
| PubMed:Determination of sixteen pesticides in peppers using high-performance liquid chromatography/mass spectrometry. |
| PubMed:Determination of carbendazim, thiophanate, thiophanate-methyl and benomyl residues in agricultural products by liquid chromatography-tandem mass spectrometry. |
| PubMed:Optical spectroscopy studies of the interaction between thiophanate methyl and human serum albumin for biosensor applications. |
| PubMed:Genotoxic effects of the fungicide thiophanate-methyl on Podarcis sicula assessed by micronucleus test, comet assay and chromosome analysis. |
| PubMed:Biodegradation kinetics of the benzimidazole fungicide thiophanate-methyl by bacteria isolated from loamy sand soil. |
| PubMed:Potential for bioremediation of agro-industrial effluents with high loads of pesticides by selected fungi. |
| PubMed:[Pathogen identification of Pinellia ternata tuber disease and selection of fungicide]. |
| PubMed:Dissipation study of thiophanate methyl residue in/on grapes (Vitis vinifera L.) in India. |
| PubMed:Genotoxic fungicide methyl thiophanate as an oxidative stressor inducing 8-oxo-7,8-dihydro-2' -deoxyguanosine adducts in DNA and mutagenesis. |
| PubMed:Synthesis and biological activity of some novel trifluoromethyl-substituted 1,2,4-triazole and bis(1,2,4-triazole) Mannich bases containing piperazine rings. |
| PubMed:Methyl thiophanate as a DNA minor groove binder produces MT-Cu(II)-DNA ternary complex preferably with AT rich region for initiation of DNA damage. |
| PubMed:Fungicide methyl thiophanate binding at sub-domain IIA of human serum albumin triggers conformational change and protein damage. |
| PubMed:Pesticide extraction from table grapes and plums using ionic liquid based dispersive liquid-liquid microextraction. |
| PubMed:Description of Cryptosporiopsis kienholzii and species profiles of Neofabraea in major pome fruit growing districts in the Pacific Northwest USA. |
| PubMed:Ionic liquid based dispersive liquid-liquid microextraction for the extraction of pesticides from bananas. |
| PubMed:Flower-inhabiting Frankliniella Thrips (Thysanoptera: Thripidae), pesticides, and Fusarium hardlock in cotton. |
| PubMed:Determination of multi-class pesticides in wines by solid-phase extraction and liquid chromatography-tandem mass spectrometry. |
| PubMed:Assessment of methyl thiophanate-Cu (II) induced DNA damage in human lymphocytes. |
| PubMed:In vitro toxicity of selected fungicides from the groups of benzimidazoles and demethylation inhibitors to Cladobotryum dendroides and Agaricus bisporus. |
| PubMed:In vitro study on the interaction between thiophanate methyl and human serum albumin. |
| PubMed:Rapid development of fungicide resistance by Sclerotinia homoeocarpa on turfgrass. |
| PubMed:Genetic Analysis of Isolates of Botrytis cinerea Sensitive and Resistant to Benzimidazole and Dicarboximide Fungicides. |
| PubMed:Combinations of Fungicides with Phylloplane Yeasts for Improved Control of Botrytis cinerea on Geranium Seedlings. |
| PubMed:Adaptation to fungicides in Monilinia fructicola isolates with different fungicide resistance phenotypes. |
| PubMed:Screening preharvest/postharvest strategies to prevent fruit rot decay. |
| PubMed:[Study on usage of pesticides in various countries]. |
| PubMed:Morphological and functional changes in the thyroid gland of methyl thiophanate-injected lizards, Podarcis sicula. |
| PubMed:Molecular characterization of benzimidazole-resistant isolates of Cladosporium fulvum. |
| PubMed:Quantification of allele E198A in beta-tubulin conferring benzimidazole resistance in Monilinia fructicola using real-time PCR. |
| PubMed:Application of genetic algorithm for selection of variables for the BLLS method applied to determination of pesticides and metabolites in wine. |
| PubMed:The effects of the fungicide methyl thiophanate on adrenal gland morphophysiology of the lizard, Podarcis sicula. |
| PubMed:Determination of thiophanate methyl and carbendazim residues in vegetable samples using microwave-assisted extraction. |
| PubMed:[Susceptibility of Trichogramma pretiosum Riley (Hymenoptera: Trichogrammatidae) adults to fungicides used to control apple diseases]. |
| PubMed:PPARalpha mediates the effects of the pesticide methyl thiophanate on liver of the lizard Podarcis sicula. |
| PubMed:Impact of the stem borer, Dectes texanus, on yield of the cultivated sunflower, Helianthus annuus. |
| PubMed:Survival of adult Tiphia vernalis (Hymenoptera: Tiphiidae) after insecticide, fungicide, and herbicide exposure in laboratory bioassays. |
| PubMed:The newt Triturus carnifex as a model for monitoring the ecotoxic impact of the fungicide thiophanate methyl: adverse effects on the adrenal gland. |
| PubMed:[Determination of thiophanate-methyl residue in peppers by solid phase extraction-HPLC]. |
| PubMed:Characterization and PCR-based detection of benzimidazole-resistant isolates of Monilinia laxa in California. |
| PubMed:Effects of thiophanate-methyl and glyphosate on asexual and sexual reproduction in the rotifer Brachionus calyciflorus Pallas. |
| PubMed:A simple and rapid spectrophotometric method for determination of thiophanate-methyl in commercial formulations and its residues in foodstuffs. |
| PubMed:Activity of some chemicals in the control of Botrytis cinerea on roses. |
| PubMed:Re-identification and characterization of pathogens causing ugurassa (Flacourtia inermis) fruit anthracnose. |
| PubMed:Effect of thiophanate-methyl on the reproduction and survival of the freshwater rotifer Brachionus calyciflorus Pallas. |
| PubMed:Identification and characterization of benzimidazole resistance in Monilinia fructicola from stone fruit orchards in California. |
| PubMed:Histological and histomorphometric alterations in thyroid and adrenals of CD rat pups exposed in utero to methyl thiophanate. |
| PubMed:Complexation of several fungicides with beta-cyclodextrin: determination of the association constants and isolation of the solid complexes. |
| PubMed:Risk assessment of pesticide runoff from turf. |
| PubMed:[Effects of Atractylodes macrocephala seeds coated with SCF on field diseases]. |
| PubMed:On-line automated sample preparation for liquid chromatography using parallel supported liquid membrane extraction and microporous membrane liquid-liquid extraction. |
| PubMed:Effect of insecticides and fungicides on the interaction between members of the mite families Phytoseiidae and Stigmaeidae on citrus. |
| PubMed:[Effect of pesticides on field-controlling root rot of Vicia faba]. |
| PubMed:Differential sensitivity of two green algae, Scenedesmus obliqnus and Chlorella pyrenoidosa, to 12 pesticides. |
| PubMed:[Renal dysfunction in chemical plant workers producing dust pesticides]. |
| PubMed:Liquid chromatographic-mass spectrometric determination of post-harvest fungicides in citrus fruits. |
| PubMed:Determination of thiophanate-methyl and its metabolites at trace level in spiked natural water using the supported liquid membrane extraction and the microporous membrane liquid-liquid extraction techniques combined on-line with high-performance liquid chromatography. |
| PubMed:Determination of imidacloprid and benzimidazole residues in fruits and vegetables by liquid chromatography-mass spectrometry after ethyl acetate multiresidue extraction. |
| PubMed:Flow cytometric analysis of genetic damage, effect on cell cycle progression, and apoptosis by thiophanate-methyl in human lymphocytes. |
| PubMed:Molecular non-genetic biomarkers of effect related to methyl thiophanate cocarcinogenesis: organ- and sex-specific cytochrome P450 induction in the rat. |
| PubMed:Analysis of carbendazim, benomyl, thiophanate methyl and 2,4-dichlorophenoxyacetic acid in fruits and vegetables after supercritical fluid extraction. |
| PubMed:In vivo studies on possible adverse effects on reproduction of the fungicide methyl thiophanate. |
| PubMed:Effects of Some Pesticides on the Growth of ARF18 and Its Pathogenicity to Heterodera glycines. |
| PubMed:Cytotoxic and cell transforming activities of the fungicide methyl thiophanate on BALB/c 3T3 cells in vitro. |
| PubMed:Cytogenetic effects of benzimidazoles in mouse bone marrow. |
| PubMed:Pesticides in the cultivation of carnations in greenhouses: Part I--Exposure and concomitant health risk. |
| PubMed:Postharvest-applied agrochemicals and their residues in fresh fruits and vegetables. |
| PubMed:Ion-pairing liquid chromatographic determination of benzimidazole fungicides in foods. |
| PubMed:An oxidimetric method for the determination of thiophanatemethyl in commercial formulations. |
| PubMed:Determination of thiophanate methyl as carbendazin by high-pressure liquid chromatography: application to onions and cabbage. |
| PubMed:Cytogenetic hazards from agricultural chemicals. 4. Sequential screening in the barley progeny test for cytogenetic activity of some systemic fungicides and a metabolite. |
| PubMed:[Use of fungi as a biological test for determination of fungicide residues in plant material. II. Determination of benomyl, dichlofluanide, folpet, captane, carbendazyme, methyl thiophanate and thiram in fruit, vegetables and champignons]. |
| PubMed:[Use of fungi as a biological test for the determination of residues of various fungicides in plant material. I. Determination of benomyl, methyl thiophanate, carbendazyme and thiabendazol in lemons, oranges, grapefruit and bananas]. |
| PubMed:The toxicity of benomyl, thiophanate-methyl, and BCM to four freshwater organisms. |
| PubMed:Effect of benomyl and thiophanate-methyl on metabolic activities of Rhizoctonia solani Kühn. |
| PubMed:Persistence and metabolism of thiophanate-methyl in soil. |
| PubMed:Mutagenic, cytogenetic and teratogenic studies on thiophanate-methyl. |
| PubMed:Some pharmacologic properties of a new fungicide thiophanate-methyl. |
| PubMed:Acute toxicity on dimethyl 4,4'-o-phenylene bis(3-thioallophanate), thiophanate-methyl fungicide. |
|