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Category:herbicides / pesticides
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Assay: | 95.00 to 100.00
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| Food Chemicals Codex Listed: | No |
| Melting Point: | 176.00 °C. @ 760.00 mm Hg
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| Vapor Pressure: | 1.280000 mmHg @ 25.00 °C. (est) |
| logP (o/w): | 1.560 |
| Soluble in: |
| | water, 230 mg/L @ 25 °C (exp) |
Organoleptic Properties:
| Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-duck LD50 > 2510 mg/kg
Pesticide Manual. Vol. 9, Pg. 814, 1991.
oral-mouse LD50 > 5000 mg/kg
Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 18, Pg. S219, 1993.
oral-rat LD50 > 5000 mg/kg
Farm Chemicals Handbook. Vol. -, Pg. C239, 1991.
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| Dermal Toxicity: |
skin-rabbit LD50 > 2000 mg/kg
Farm Chemicals Handbook. Vol. -, Pg. C239, 1991.
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| Inhalation Toxicity: |
inhalation-rat LC50 > 7900 mg/m3/4H
Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 18, Pg. S219, 1993.
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Safety in Use Information:
| Category: | | herbicides / pesticides |
| Recommendation for thifensulfuron-methyl usage levels up to: | | | not for fragrance use.
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| Recommendation for thifensulfuron-methyl flavor usage levels up to: |
| | not for flavor use.
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Safety References:
European Food Safety Authority (EFSA) reference(s):
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Conclusion on the peer review of the pesticide risk assessment of the active substance thifensulfuron-methyl
View page or View pdf
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Outcome of the consultation with Member States, the applicant and EFSA on the pesticide risk assessment for thifensulfuron-methyl in light of confirmatory data
View page or View pdf
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| EPI System: View |
| EPA-Iris:IRIS |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :73674 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:2 |
| methyl 3-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]thiophene-2-carboxylate |
| Chemidplus:0079277273 |
| RTECS:XM8463000 for cas# 79277-27-3 |
References:
| | methyl 3-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]thiophene-2-carboxylate |
| NIST Chemistry WebBook: | Search Inchi |
| Pubchem (cid): | 73674 |
| Pubchem (sid): | 135031132 |
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| CHEBI: | View |
| CHEMBL: | View |
| KEGG (GenomeNet): | C10957 |
| HMDB (The Human Metabolome Database): | Search |
| Export Tariff Code: | 2935.90.9500 |
| ChemSpider: | View |
| Wikipedia: | View |
Formulations/Preparations:
•selected products: harmony; pinnacle; ...prospect; refine. mixtures: canvas (+metsulfuron-methyl, +tribenuron-methyl); ...basis (+rimsulfuron); calibre (+tribenuron-methyl); concert (+chlorimuron-ethyl); grid (+rimsulfuron); harmony express (+carfentrazone-ethyl); harmony extra (+tribenuron-methyl); harmony m (+metsulfuron-methyl); lexus millenium (+flupyrsulfuron-methyl-sodium); millenium (+flupyrsulfuron-methyl-sodium); reliance (+chlorimuron-ethyl); scoop (+metsulfuron-methyl); synchronyl sts (+chlorimuron-ethyl).
•discontinued products: crackshot. mixtures: dp 928 (+metsulfuron-methyl); duk 110 (+tribenuron-methyl).
•formulations: dry flowable.
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Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | EPA pesticide chemical code 128845 | | | harmony 75DF | | | harmony GT | | | harmony GT-XP | | | methyl 3-(4-methoxy-6-methyl-1,3,5-triazin-2-ylcarbamoylsulfamoyl)-2-thenoate | | | methyl 3-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]thiophene-2-carboxylate | | | pinnacle 25DF | | | refine DF | | | thifensulfuron methyl | | | thifensulfuron methyl ester | | | thifensulfuron-methyl [ISO:BSI] | | 2- | thiophenecarboxylic acid, 3-(((((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)carbonyl)amino)sulfonyl)-, methyl ester |
Articles:
| PubMed:Application of liquid chromatography/electrospray ionization tandem mass spectrometry for the elucidation of hydroxyl radical oxidation of metsulfuron methyl and related sulfonylurea pesticide products: evidence for the triazine skeleton scission. |
| PubMed:Biodegradation of thifensulfuron-methyl by Ochrobactrum sp. in liquid medium and soil. |
| PubMed:Use of ammonium formate in QuEChERS for high-throughput analysis of pesticides in food by fast, low-pressure gas chromatography and liquid chromatography tandem mass spectrometry. |
| PubMed:Rapid and sensitive on-line solid phase extraction-ultra high performance liquid chromatography-electrospray-tandem mass spectrometry analysis of pesticides in surface waters. |
| PubMed:Use of gold nanoparticle-coated sorbent materials for the selective preconcentration of sulfonylurea herbicides in water samples and determination by capillary liquid chromatography. |
| PubMed:Accumulation and half-lives of 13 pesticides in muscle tissue of freshwater fishes through food exposure. |
| PubMed:Growth inhibition and recovery of Lemna gibba after pulse exposure to sulfonylurea herbicides. |
| PubMed:Pesticide pressure and fish farming in barrage pond in Northeastern France. Part II: residues of 13 pesticides in water, sediments, edible fish and their relationships. |
| PubMed:Ionic liquids supported on magnetic nanoparticles as a sorbent preconcentration material for sulfonylurea herbicides prior to their determination by capillary liquid chromatography. |
| PubMed:Toxic effects of four sulphonylureas herbicides on soil microbial biomass. |
| PubMed:SulE, a sulfonylurea herbicide de-esterification esterase from Hansschlegelia zhihuaiae S113. |
| PubMed:Rapid determination of sixteen sulfonylurea herbicides in surface water by solid phase extraction cleanup and ultra-high-pressure liquid chromatography coupled with tandem mass spectrometry. |
| PubMed:Multiresidue method for the determination of 13 pesticides in three environmental matrices: water, sediments and fish muscle. |
| PubMed:Multiresidue method to quantify pesticides in fish muscle by QuEChERS-based extraction and LC-MS/MS. |
| PubMed:Study of biochemical pathway and enzyme involved in metsulfuron-methyl degradation by Ancylobacter sp. XJ-412-1 isolated from soil. |
| PubMed:Development and validation of a solid-phase extraction method coupled to high-performance liquid chromatography with ultraviolet-diode array detection for the determination of sulfonylurea herbicide residues in bovine milk samples. |
| PubMed:Chemiluminescence sensor for sulfonylurea herbicide using molecular imprinted microspheres as recognition element. |
| PubMed:Class-specific molecularly imprinted polymers for the selective extraction and determination of sulfonylurea herbicides in maize samples by high-performance liquid chromatography-tandem mass spectrometry. |
| PubMed:Trace level determination of selected sulfonylurea herbicides in wetland sediment by liquid chromatography electrospray tandem mass spectrometry. |
| PubMed:N-methylimidazolium ionic liquid-functionalized silica as a sorbent for selective solid-phase extraction of 12 sulfonylurea herbicides in environmental water and soil samples. |
| PubMed:Leaching of three sulfonylurea herbicides during sprinkler irrigation. |
| PubMed:Mass spectrometry of the photolysis of sulfonylurea herbicides in Prairie waters. |
| PubMed:The study of the interactions between heavy metals with sulfonylurea herbicides using ACE. |
| PubMed:Impact of basic soil parameters on pesticide disappearance investigated by multivariate partial least square regression and statistics. |
| PubMed:HPLC-UV and HPLC-MSn multiresidue determination of amidosulfuron, azimsulfuron, nicosulfuron, rimsulfuron, thifensulfuron methyl, tribenuron methyl and azoxystrobin in surface waters. |
| PubMed:Possibilities of chemical weed control in Lupinus albus and Lupinus luteus-screening of herbicides. |
| PubMed:Chemical cotton stalk destruction for maintenance of host-free periods for the control of overwintering boll weevil in tropical and subtropical climates. |
| PubMed:Persistence of the sulfonylurea herbicides thifensulfuron-methyl, ethametsulfuron-methyl, and metsulfuron-methyl in farm dugouts (ponds). |
| PubMed:[Simultaneous determination of ten sulfonylurea herbicide residues in soybeans by high performance liquid chromatography]. |
| PubMed:Physiological and biochemical characterization of quinclorac resistance in a false cleavers (Galium spurium L.) biotype. |
| PubMed:Effects of insecticides and defoliants applied alone and in combination for control of overwintering boll weevil (Anthonomus grandis; Coleoptera: Curculionidae)--laboratory and field studies. |
| PubMed:Toxicovigilance: new biochemical tool used in sulfonylurea herbicides toxicology studies. |
| PubMed:Selective trace analysis of sulfonylurea herbicides in water and soil samples based on solid-phase extraction using a molecularly imprinted polymer. |
| PubMed:Mineralisation studies of 14C-labelled metsulfuron-methyl, tribenuron-methyl, chlorsulfuron and thifensulfuron-methyl in one Danish soil and groundwater sediment profile. |
| PubMed:Screening Method for Nine Sulfonylurea Herbicides in Soil and Water by Liquid Chromatography with Ultraviolet Detection. |
| PubMed:Coupling of size-exclusion chromatography to liquid chromatography/mass spectrometry for determination of trace levels of thifensulfuron-methyl and tribenuron-methyl in cottonseed and cotton gin trash. |
| PubMed:Determination of sulfonylurea degradation products in soil by liquid chromatography-ultraviolet detection followed by confirmatory liquid chromatography-tandem mass spectrometry. |
| PubMed:A kinetic study of the methanolysis of the sulfonylureas bensulfuron methyl and sulfometuron methyl using capillary electrophoresis. |
| PubMed:Multiresidue determination of sulfonylurea herbicides by capillary electrophoresis for hydrolysis studies in water and sediments. |
| PubMed:Acceptance Criteria for Ultratrace HPLC-Tandem Mass Spectrometry: Quantitative and Qualitative Determination of Sulfonylurea Herbicides in Soil. |
| PubMed:Capillary electrophoretic behavior of seven sulfonylureas. |
| PubMed:Determination of sulfonylurea herbicides in grains by capillary electrophoresis. |
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3D/inchi