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Category:natural substances and extractives
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Assay: | 95.00 to 100.00
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| Food Chemicals Codex Listed: | No |
| Boiling Point: | 209.90 °C. @ 760.00 mm Hg (est)
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| Flash Point: | 173.00 °F. TCC ( 78.50 °C. ) (est)
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| logP (o/w): | 2.920 (est) |
| Soluble in: |
| | water, 287.6 mg/L @ 25 °C (est) |
Organoleptic Properties:
| Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
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Not determined
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| Dermal Toxicity: |
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Not determined
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| Inhalation Toxicity: |
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Not determined
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Safety in Use Information:
| Category: | | natural substances and extractives |
| Recommendation for fragranol usage levels up to: | | | not for fragrance use.
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| Recommendation for fragranol flavor usage levels up to: |
| | not for flavor use.
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Safety References:
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | cyclobutaneethanol, 1-methyl-2-(1-methylethenyl)-, (1R,2R)- | | | cyclobutaneethanol, 2-isopropenyl-1-methyl-, cis-(+)- | | | grandisol | | 2-[(1R,2R)-2-iso | propenyl-1-methylcyclobutyl]ethanol |
Articles:
| PubMed:Toxic essential oils: anxiolytic, antinociceptive and antimicrobial properties of the yarrow Achillea umbellata Sibth. et Sm. (Asteraceae) volatiles. |
| PubMed:Identification of male-produced aggregation pheromone of the curculionid beetle Sternechus subsignatus. |
| PubMed:Transannular Claisen rearrangement reactions for the synthesis of vinylcyclobutanes: formal synthesis of (±)-grandisol. |
| PubMed:A versatile synthetic approach to grandisol monoterpene pheromone. |
| PubMed:Synthesis of grandisol, the sexual attracting insect pheromone. |
| PubMed:(1R,2S,6R)-2-Hydroxymethyl-2,6-dimethyl-3-oxabicyclo[4.2.0]octane, a new volatile released by males of the papaya borer Pseudopiazurus obesus (Col.: Curculionidae). |
| PubMed:An efficient synthesis of (+/-)-grandisol featuring 1,5-enyne metathesis. |
| PubMed:Comparative study of the essential oils and extracts of Achillea fragrantissima (Forssk.) Sch. Bip. and Achillea santolina L. (Asteraceae) from Egypt. |
| PubMed:C2-Symmetric enantiopure ethanotethered bis(alpha,beta-butenolides) as templates for asymmetric synthesis. Application to the synthesis of (+)-grandisol. |
| PubMed:Preparative chiral liquid chromatography for enantiomeric separation of pheromones. |
| PubMed:Strategies of a bark beetle, Pityogenes bidentatus, in an olfactory landscape. |
| PubMed:An asymmetric synthesis of (+)-grandisol, a constituent of the aggregation pheromone of the cotton boll weevil, via a kinetic resolution. |
| PubMed:Highly efficient, enantioselective synthesis of (+)-grandisol from a C2-symmetric bis(alpha,beta-butenolide). |
| PubMed:Semiochemicals from bark beetles: New results, remarks, and reflections. |
| PubMed:Enantiomeric composition of grandisol and grandisal produced byPissodes strobi andP. nemorensis and their electroantennogram response to pure enantiomers. |
| PubMed:Receptor chirality and behavioral specificity of the boll weevil,Anthonomus grandis Boh. (Coleoptera: Curculionidae), for its pheromone, (+)-grandisol. |
| PubMed:Extreme sensitivity of grandisal to acids. |
| PubMed:Interspecific activity of semiochemicals among sibling species ofPissodes (Coleoptera: Curculionidae). |
| PubMed:Aggregation pheromone of the deodar weevll,Pissodes nemorensis (Coleoptera: Curculionidae): Isolation and activity of grandisol and grandisal. |
| PubMed:Aggregation pheromone components of two species ofPissodes weevils (Coleoptera: Curculionidae) Isolation, identification, and field activity. |
| PubMed:Studies on terpenes. 4. Synthesis of optically active grandisol, the boll weevil pheromone. |
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3D/inchi