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Category:flavoring agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless clear liquid (est) |
| Assay: | 98.00 to 100.00
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| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.85100 to 0.85600 @ 25.00 °C.
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| Pounds per Gallon - (est).: | 7.081 to 7.123
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| Refractive Index: | 1.41200 to 1.41400 @ 20.00 °C.
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| Melting Point: | -129.00 °C. @ 760.00 mm Hg
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| Boiling Point: | 97.00 to 98.00 °C. @ 760.00 mm Hg
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| Vapor Pressure: | 26.100000 mmHg @ 25.00 °C. |
| Vapor Density: | 2.0 ( Air = 1 ) |
| Flash Point: | 72.00 °F. TCC ( 22.22 °C. )
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| logP (o/w): | 0.170 |
| Soluble in: |
| | alcohol | | | water, 1.00E+06 mg/L @ 20 °C (exp) |
| Similar Items:note |
| 2-propen-1-one |
Organoleptic Properties:
| Odor Type: alliaceous |
| pungent mustard |
| Odor Description:at 0.10 % in dipropylene glycol. pungent mustard |
| Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | T N - Toxic, Dangerous for the environment. |
R 10 - Flammable.
R 23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
R 50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S 02 - Keep out of the reach of children.
S 20/21 - When using do not eat, drink or smoke.
S 23 - Do not breath vapour.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 28 - After contact with skin, wash immediately with plenty of water.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-rat LD50 64 mg/kg
Journal of Industrial Hygiene and Toxicology. Vol. 30, Pg. 63, 1948.
intraperitoneal-rat LD50 37 mg/kg
Toxicology and Applied Pharmacology. Vol. 83, Pg. 108, 1986.
oral-rabbit LD50 52 mg/kg
National Technical Information Service. Vol. OTS0571508
oral-mouse LD50 96 mg/kg
BEHAVIORAL: ATAXIA
LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA
AMA Archives of Industrial Health. Vol. 18, Pg. 303, 1958.
intravenous-mouse LD50 78 mg/kg
Archives Internationales de Pharmacodynamie et de Therapie. Vol. 135, Pg. 330, 1962.
intraperitoneal-mouse LD50 60 mg/kg
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL: ATAXIA
BEHAVIORAL: EXCITEMENT
AMA Archives of Industrial Health. Vol. 18, Pg. 303, 1958.
parenteral-frog LDLo 51 mg/kg
GASTROINTESTINAL: NAUSEA OR VOMITING
BEHAVIORAL: EXCITEMENT
Archives Internationales de Pharmacodynamie et de Therapie. Vol. 50, Pg. 296, 1935.
oral-mammal (species unspecified) LD50 70 mg/kg
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 32(10), Pg. 25, 1988.
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| Dermal Toxicity: |
skin-rabbit LD50 45 mg/kg
Journal of Industrial Hygiene and Toxicology. Vol. 30, Pg. 63, 1948.
subcutaneous-rabbit LDLo 100 mg/kg
"Zur Pharmakologie Ungesattigter Alkohole, Dissertation," Bock, H., Pharmakologischen Institu der Universitat Breslau, Poland, 1930Vol. -, Pg. -, 1930.
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| Inhalation Toxicity: |
inhalation-mouse LC50 500 mg/m3/2H
"Zur Pharmakologie Ungesattigter Alkohole, Dissertation," Bock, H., Pharmakologischen Institu der Universitat Breslau, Poland, 1930Vol. -, Pg. -, 1930.
inhalation-mammal (species unspecified) LC50 1000 mg/m3
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 32(10), Pg. 25, 1988.
inhalation-mouse LC50 500 mg/m3/2H
"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 17, 1982.
inhalation-rabbit LCLo 1000 ppm/3.5H
SENSE ORGANS AND SPECIAL SENSES: IRITIS: EYE
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
BLOOD: HEMORRHAGE
JAMA, Journal of the American Medical Association. Vol. 98, Pg. 2269, 1932.
inhalation-rat LC50 76 ppm/8H
LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA
AMA Archives of Industrial Health. Vol. 18, Pg. 303, 1958.
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Safety in Use Information:
| Category: | | flavoring agents |
| Recommendation for allyl alcohol usage levels up to: | | | not for fragrance use.
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Safety References:
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| 3- | hydroxy-1-propene | | 3- | hydroxypropene | | | prop-2-en-1-ol | | 2- | propen-1-ol | | 2- | propen-1-yl alcohol | | 1- | propen-3-ol | | 2- | propenol | | 2- | propenyl alcohol | | | vinyl carbinol | | | vinylcarbinol |
Articles:
| PubMed:Enhancement of allyl alcohol hepatotoxicity by endotoxin requires extrahepatic factors |
| PubMed:Short-term toxicity of allyl alcohol in rats |
| PubMed:NTP Technical Report on the comparative toxicity studies of allyl acetate (CAS No. 591-87-7), allyl alcohol (CAS No. 107-18-6) and acrolein (CAS No. 107-02-8) administered by gavage to F344/N rats and B6C3 |
| PubMed:Neutrophils contribute to endotoxin enhancement of allyl alcohol hepatotoxicity |
| PubMed:A General Asymmetric Synthesis of (R)-Matsutakeol and Flavored Analogs |
| PubMed:Synergistic antiyeast activity of garlic oil and allyl alcohol derived from alliin in garlic |
| PubMed:Does External Exposure of Glycidol-Related Chemicals Influence the Forming of the Hemoglobin Adduct, N-(2,3-dihydroxypropyl)valine, as a Biomarker of Internal Exposure to Glycidol? |
| PubMed:Allyl isothiocyanate is mutagenic in Salmonella typhimurium |
| PubMed:Tissue repair plays pivotal role in final outcome of liver injury following chloroform and allyl alcohol binary mixture |
| PubMed:In-situ modification, regeneration, and application of keratin biopolymer for arsenic removal |
| PubMed:Synthesis of allyl esters of fatty acids and their ovicidal effect on Cydia pomonella (L.) |
| PubMed:Survival and proliferation of alginate encapsulated Trichoderma spp. in Egyptian soil in comparison with allyl alcohol soil fumigation |
| PubMed:Improving isopropanol tolerance and production of Clostridium beijerinckii DSM 6423 by random mutagenesis and genome shuffling |
| PubMed:ENDOR characterization of an iron-alkene complex provides insight into a corresponding organometallic intermediate of nitrogenase |
| PubMed:Liver regeneration: a critical toxicodynamic response in predictive toxicology |
| PubMed:Applications of direct analysis in real time mass spectrometry (DART-MS) in Allium chemistry. 2-propenesulfenic and 2-propenesulfinic acids, diallyl trisulfane S-oxide, and other reactive sulfur compounds |
| PubMed:Genomic indicators in the blood predict drug-induced liver injury |
| PubMed:Production of Acetaldehyde by Zymomonas mobilis |
| PubMed:Allyl alcohol as a nutrient for micro-organisms |
| PubMed:Allium chemistry: synthesis, natural occurrence, biological activity, and chemistry of Se-alk(en)ylselenocysteines and their gamma-glutamyl derivatives and oxidation products |
| PubMed:Coupling reactions of catechins with natural aldehydes and allyl alcohols and radical scavenging activities of the triglyceride-soluble products |
| PubMed:[Screening of a low alcohol dehydrogenase activity mutant of rhizopus oryzae and the regulation of Zn2+ and Mg2+] |
| PubMed:Limited infection without evidence of replication by porcine endogenous retrovirus in guinea pigs |
| PubMed:Identification of allyl esters in garlic cheese |
| PubMed:Enantioselective epoxidation with chiral MN(III)(salen) catalysts: kinetic resolution of aryl-substituted allylic alcohols |
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Present in garlic (Allium sativum)
Allyl alcohol is an organic compound with the structural formula CH2=CHCH2OH. Like many alcohols, it is a water soluble, colourless liquid, but it is more toxic than typical small alcohols. Allyl alcohol is used as a raw material for the production of glycerol, but is used as a precursor to many specialized compounds. Allyl alcohol is the smallest representative of the allylic alcohols. (Wikipedia)
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3D/inchi