| SAFETY DATA SHEET |
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| 1 : PRODUCT AND COMPANY IDENTIFICATION |
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| Product Code / Trade Name : | RW101479 / vanillin |
| Supplier Details : | The Good Scents Company
1977 E. Montana Ave., Oak Creek, WI 53154 |
| Information : | 414-764-2659 |
| Version Date : | 09/03/2020 |
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| 2 : HAZARDS IDENTIFICATION |
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| 2.1 Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
Eye irritation (Category 2A), H319
Acute aquatic toxicity (Category 3), H402
Chronic aquatic toxicity (Category 3), H412
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| 2.2 GHS Label elements, including precautionary statements |
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| Pictogram |  |
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| Signal word | Warning |
| Hazard statement(s) |
H319 - Causes serious eye irritation
H402 - Harmful to aquatic life
H412 - Harmful to aquatic life with long lasting effects
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| Precautionary statement(s) |
P264 - Wash skin thouroughly after handling.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - IF eye irritation persists: Get medical advice/attention.
P501 - Dispose of contents/ container to an approved waste disposal plant.
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| 3 : COMPOSITION / INFORMATION ON INGREDIENTS |
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| Chemical characterization : |
| Hazardous ingredient(s) : |
| 3-methoxy-4-hydroxybenzaldehyde 99.00 to 100.00 % |
| Hazard symbols : Xn R phrases : 22 36
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| mol./wt. : 152.1493600
formula : C8 H8 O3
cas: 121-33-5
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| einecs: 204-465-2 |
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| 4 : FIRST-AID MEASURES |
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| Remove contaminated soaked clothing and wash before reuse. |
| After eye contact : |
| In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes. |
| After skin contact : |
| After contact with skin, wash immediately affected area with soap and plenty of water. |
| After inhalation : |
| If inhaled, remove person to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. |
| After ingestion : |
| If swallowed, rinse mouth with water (only if the person is conscious). Obtain medical advice. |
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| 5 : FIRE-FIGHTING MEASURES |
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| Extinguishing media : |
| Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. |
| Special firefighting procedures : |
| Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. |
| Unusual fire and explosion hazards : |
| Emits toxic fumes under fire conditions. |
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| 6 : ACCIDENTAL RELEASE MEASURES |
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| Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves. Keep people away, evacuate area. |
| To avoid possible contamination of the environment, Do not discharge into any drains, surface waters or groundwaters. |
| Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. |
| Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. Dispose of in accordance with current laws and regulations. |
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| 7 : HANDLING AND STORAGE |
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| Measures should be taken to prevent materials from being splashed into the eyes or on the skin. Wear eyeshields and protective clothing. Smoking should not be permitted in work areas. |
| Provide suitable air extraction ventilation in the work areas. Vapors may form explosive mixtures with air. Keep material away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges. |
| To be stored in tightly sealed and preferably full containers in cool, dry and ventilated area. Protect from heat/overheating and light sources. |
| Keep in glass, suitable plastic, aluminum or laquer-lined containers. |
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| 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION |
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| Occupational exposure limits : |
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OSHA TWA : Not determined |
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ACGIH TWA : Not determined |
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NIOSH TWA : Not determined |
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OSHA PEL : Not determined |
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ACGIH STEL : Not determined |
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NIOSH STEL : Not determined |
| Respiratory protection : |
| Do not breath vapors. Mechanical exhaust required. In confined or poorly ventilated areas, the use of an appropriate respiratory protection may be required. |
| Hand protection : |
| Compatible chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. |
| Eye protection : |
| Chemical safety goggles are recommended. Wash contaminated goggles before reuse. |
| Body protection : |
| Light protective clothing recommended. Wash contaminated clothing before reuse. |
| Hygiene measures : |
| Avoid inhalation and contact with skin and eyes. Good personal hygiene practices should be used. Wash after any contact, before breaks and meals, and at the end of the work period. Safety shower and eye bath recommended. |
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| 9 : PHYSICAL AND CHEMICAL PROPERTIES |
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| Appearance / odor : |
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white to off white crystalline powder / sweet vanilla creamy chocolate |
| Melting point : | 81.00 to 84.00 °C. @ 760.00 mmHg
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| Boiling point : | 285.00 to 286.00°C. @ 760.00 mmHg
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| Flash point ( ° F. ) : | > 200.00 °F. TCC ( > 93.33 °C. )
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| Flammability : | Not determined
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| Autoflammability : | Not determined
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| Explosive properties : | Not determined
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| Oxidizing properties : | Not determined
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| Vapor pressure : | 0.00194 mm/Hg @ 25.00 °C.
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| Vapor density : | 5.3 ( Air = 1 )
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| Volatile by volume : | 100.00 %
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| Evaporation rate : | Not determined
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| Specific gravity : | 1.04800 to 1.05900 @ 25 °C.
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| PH of Product : | Not determined
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| Solubility in water : | Slightly Soluble |
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| 10 : STABILITY AND REACTIVITY |
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| Stability : |
Stable
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| Conditions to avoid : |
Heat, excessive heat, open flames and other sources of ignition. |
| Incompatibility : |
Moisture, light, heat, strong oxidizing agents, strong reducing agents, strong bases. |
| Hazardous decomposition products : |
Carbon monoxide, carbon dioxide. Hazardous polymerization will not occur. |
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| 11 : TOXICOLOGICAL INFORMATION |
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| Acute effects : |
Causes serious eye irritation
Harmful to aquatic life
Harmful to aquatic life with long lasting effects
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| Oral Toxicity(LD50) : |
gavage-rat [sex: M,F] 1580 mg/kg (Taylor et al., 1964)
intraperitoneal-rat 1160 mg/kg Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 243, Pg. 609, 1956.
gavage-rabbit 2600 mg/kg (Deichmann & Kitzmiller, 1940)
gavage-mouse [sex: M] 1000 mg/kg (Inouye et al., 1988)
intraperitoneal-mouse 475 mg/kg
gavage-guinea pig [sex: M,F] 1400 mg/kg (Jenner et al., 1964)
gavage-rat [sex: M,F] 1580 mg/kg (Jenner et al., 1964)
gavage-rat [sex: M,F] 3978 mg/kg (Lheritier, 1992)
gavage-rat [sex: M,F] 3925 mg/kg (Lheritier, 1992)
gavage-rat [sex: M] 3830 mg/kg (Monsanto Co., 1955b)
oral-rat [sex: M,F] 3300 mg/kg (Monsanto Co., 1976)
oral-rat 4370 mg/kg (Makaruk, 1980)
intravenous-dog 1320 mg/kg Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 236, Pg. 2549, 1953.
oral-guinea pig 1400 mg/kg Food and Cosmetics Toxicology. Vol. 2, Pg. 327, 1964.
intraperitoneal-mouse 475 mg/kg FAO Nutrition Meetings Report Series. Vol. 44A, Pg. 78, 1967.
oral-mouse 3925 mg/kg National Technical Information Service. Vol. OTS0536271
oral-rabbit 3000 mg/kg Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 29, Pg. 425, 1940.
oral-rat 1580 mg/kg Food and Cosmetics Toxicology. Vol. 2, Pg. 327, 1964.
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| Dermal Toxicity(LD50) : |
skin-rabbit > 5010 mg/kg National Technical Information Service. Vol. OTS0533712
subcutaneous-rat 1500 mg/kg Revue Medicale de la Suisse Romande. Vol. 16, Pg. 449, 1896.
skin-rat > 2000 mg/kg National Technical Information Service. Vol. OTS0536272
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| Skin Irritation : |
Not determined
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| Eye Irritation : |
Not determined
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| Inhalation data(LC50) : |
inhalation-mouse > 41700 ug/kg/2 Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 45(6), Pg. 78, 1980.
inhalation-rat > 41700 ug/kg/4 Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 45(6), Pg. 78, 1980.
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| Mutagenicity data : |
Not determined
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| Phototoxicity data : |
Not determined
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| Human experience : |
Not determined
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| Carcinogenicity : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
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| Reproductive toxin : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
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| On the TSCA Inventory? : |
Yes |
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| 12 : ECOLOGICAL INFORMATION |
| Biodegradability |
| Readily biodegradable : |
Not determined
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| Inherently biodegradable : |
Not determined
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| Ecotoxicity |
| Fish : |
LC50 MG/L/96H Pimephales prome
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| Algae : |
Not determined
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| Daphnia : |
Not determined
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| Bacteria : |
Not determined
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| Further information : |
Prevent contamination of soil, ground and surface waters. Do not discharge product unmonitored into the environment. |
| Mixture reportable to : |
FIFRA-Inerts |
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| 13 : DISPOSAL CONSIDERATIONS |
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Dispose of in accordance with all federal, state and local environmental regulations.
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| 14 : TRANSPORT INFORMATION |
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| US DOT Hazard Class : |
n/a keep away from children
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| UN Number : |
Not found
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| UN Pkg. Group : |
Not determined
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| UN item : |
Not determined
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| ERG Number : |
Not determined
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| Land transport (ADR/RID) |
| Class : |
Not determined
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| Transportfactor : |
Not determined
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| Marine transport (IMDG) |
| IMDG-class : |
Not determined
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| Page No. : |
Not determined
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| MFAG : |
Not determined
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| EmS-No. : |
Not determined
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| Air transport (IATA) |
| IATA-class : |
Not determined
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| Passenger : |
Not determined
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| Cargo : |
Not determined
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| 15 : REGULATORY INFORMATION |
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| Reviews, standards, and regulations : |
| None found |
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| 16 : OTHER INFORMATION |
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| Fema No. : | 3107 |
| Hazardous materials identification system : |
| Fire : 1 |
Health : 2 |
Reactivity : 0 |
Personal protection : C
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| Disclaimer |
| The information contained on the Material Data Sheet has been compiled from data considered accurate. ; This data is believed to be reliable, however, it must be pointed out that values for certain properties are known ; to vary from source to source. The Good Scents Company USA Expressly disclaims any warranty expressed or implied ; as well as any liability for any injury or loss arising from the use of this information or the materials described. ; This data is not to be construed as absolutely complete since additional data may be desirable when particular ; conditions or circumstances exist. It is the responsibility of the user to determine the best precautions ; necessary for the safe handling and use of this product for your application. This data relates only to the ; specific material designated and not to be used in combination with any other material. Many federal and state ; regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material. ; It is the purchaser's responsiblity to familiarize themselves with all applicable regulations. |