| SAFETY DATA SHEET |
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| 1 : PRODUCT AND COMPANY IDENTIFICATION |
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| Product Code / Trade Name : | RW101477 / para- tolualdehyde |
| Supplier Details : | The Good Scents Company
1977 E. Montana Ave., Oak Creek, WI 53154 |
| Information : | 414-764-2659 |
| Version Date : | 09/03/2020 |
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| 2 : HAZARDS IDENTIFICATION |
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| 2.1 Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
Flammable liquids (Category 4), H227
Acute toxicity, Oral (Category 4), H302
Skin irritation (Category 2), H315
Eye irritation (Category 2A), H319
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
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| 2.2 GHS Label elements, including precautionary statements |
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| Pictogram |  |
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| Signal word | Warning |
| Hazard statement(s) |
H227 - Combustible liquid
H302 - Harmful if swallowed
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
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| Precautionary statement(s) |
P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash skin thouroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P312 - IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302 + P352 - IF ON SKIN: wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P330 - Rinse mouth.
P332 + P313 - IF SKIN irritation occurs: Get medical advice/attention.
P337 + P313 - IF eye irritation persists: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/ container to an approved waste disposal plant.
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| 3 : COMPOSITION / INFORMATION ON INGREDIENTS |
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| Chemical characterization : |
| Hazardous ingredient(s) : |
| 4-methyl benzaldehyde 97.00 to 100.00 % |
| Hazard symbols : Xn R phrases : 22 36/37/38
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| mol./wt. : 120.1509600
formula : C8 H8 O
cas: 104-87-0
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| einecs: 203-246-9 |
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| 4 : FIRST-AID MEASURES |
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| Remove contaminated soaked clothing immediately and dispose of safely. |
| After eye contact : |
| In case of contact with eyes, rinse immediately with plenty of water for at least 10 minutes. Assure adequate flushing by separating the eyelids with fingers and seek medical advice. |
| After skin contact : |
| In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. call a physician. |
| After inhalation : |
| If inhaled, remove person to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. |
| After ingestion : |
| If swallowed, rinse mouth with water (only if the person is conscious). Seek medical advice immediately. |
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| 5 : FIRE-FIGHTING MEASURES |
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| Extinguishing media : |
| Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. |
| Special firefighting procedures : |
| Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. |
| Unusual fire and explosion hazards : |
| Emits toxic fumes under fire conditions. |
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| 6 : ACCIDENTAL RELEASE MEASURES |
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| Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves. Keep people away, evacuate area. |
| To avoid possible contamination of the environment, Do not discharge into any drains, surface waters or groundwaters. |
| Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. |
| Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. Dispose of in accordance with current laws and regulations. |
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| 7 : HANDLING AND STORAGE |
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| Measures should be taken to prevent materials from being splashed into the eyes or on the skin. Wear eyeshields and protective clothing. Smoking should not be permitted in work areas. |
| Provide suitable air extraction ventilation in the work areas. Vapors may form explosive mixtures with air. Keep material away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges. |
| To be stored in tightly sealed and preferably full containers in cool, dry and ventilated area. Protect from heat/overheating and light sources. |
| Keep only in original container. |
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| 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION |
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| Occupational exposure limits : |
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OSHA TWA : Not determined |
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ACGIH TWA : Not determined |
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NIOSH TWA : Not determined |
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OSHA PEL : Not determined |
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ACGIH STEL : Not determined |
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NIOSH STEL : Not determined |
| Respiratory protection : |
| Do not breath vapors. Mechanical exhaust required. In confined or poorly ventilated areas, the use of an appropriate respiratory protection may be required. |
| Hand protection : |
| Compatible chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. |
| Eye protection : |
| Chemical safety goggles are recommended. Wash contaminated goggles before reuse. |
| Body protection : |
| Light protective clothing recommended. Wash contaminated clothing before reuse. |
| Hygiene measures : |
| Avoid inhalation and contact with skin and eyes. Good personal hygiene practices should be used. Wash after any contact, before breaks and meals, and at the end of the work period. Safety shower and eye bath recommended. |
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| 9 : PHYSICAL AND CHEMICAL PROPERTIES |
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| Appearance / odor : |
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pale yellow clear oily liquid / fruity cherry deep phenolic |
| Melting point : | -6.00 °C. @ 760.00 mmHg
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| Boiling point : | 204.00 to 205.00°C. @ 760.00 mmHg
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| Flash point ( ° F. ) : | 176.00 °F. TCC ( 80.00 °C. )
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| Flammability : | Not determined
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| Autoflammability : | Not determined
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| Explosive properties : | Not determined
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| Oxidizing properties : | Not determined
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| Vapor pressure : | 0.26300 mm/Hg @ 25.00 °C.
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| Vapor density : | 4.2 ( Air = 1 )
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| Volatile by volume : | 100.00 %
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| Evaporation rate : | Not determined
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| Specific gravity : | 1.01200 to 1.01800 @ 25 °C.
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| PH of Product : | Not determined
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| Solubility in water : | Insoluble |
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| 10 : STABILITY AND REACTIVITY |
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| Stability : |
Stable
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| Conditions to avoid : |
Heat, excessive heat, open flames and other sources of ignition. |
| Incompatibility : |
Moisture, light, heat, strong oxidizing agents, strong reducing agents, strong bases. |
| Hazardous decomposition products : |
Hazardous combustion or decomposition products: carbon monoxide, carbon dioxide. Hazardous polymerization will not occur. |
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| 11 : TOXICOLOGICAL INFORMATION |
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| Acute effects : |
Combustible liquid
Harmful if swallowed
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation
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| Oral Toxicity(LD50) : |
oral-rat 1600 mg/kg National Technical Information Service. Vol. OTS0533443
intraperitoneal-rat 800 mg/kg National Technical Information Service. Vol. OTS0533443
oral-mouse 3200 mg/kg National Technical Information Service. Vol. OTS0533443
intraperitoneal-mouse 400 mg/kg National Technical Information Service. Vol. OTS0533443
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| Dermal Toxicity(LD50) : |
skin-rat 2500 mg/kg National Technical Information Service. Vol. OTS0533443
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| Skin Irritation : |
skin-rabbit 500 mg/24hours moderate National Technical Information Service. Vol. OTS0533443
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| Eye Irritation : |
Not determined
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| Inhalation data(LC50) : |
inhalation-rat > 2200 mg/m3 National Technical Information Service. Vol. OTS0533443
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| Mutagenicity data : |
Not determined
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| Phototoxicity data : |
Not determined
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| Human experience : |
Not determined
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| Carcinogenicity : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
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| Reproductive toxin : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
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| On the TSCA Inventory? : |
Yes |
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| 12 : ECOLOGICAL INFORMATION |
| Biodegradability |
| Readily biodegradable : |
Not determined
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| Inherently biodegradable : |
Not determined
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| Ecotoxicity |
| Fish : |
Not determined
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| Algae : |
Not determined
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| Daphnia : |
Not determined
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| Bacteria : |
Not determined
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| Further information : |
Prevent contamination of soil, ground and surface waters. Do not discharge product unmonitored into the environment. |
| Mixture reportable to : |
FIFRA-Inerts |
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| 13 : DISPOSAL CONSIDERATIONS |
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Dispose of in accordance with all federal, state and local environmental regulations.
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| 14 : TRANSPORT INFORMATION |
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| US DOT Hazard Class : |
n/a keep away from children
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| UN Number : |
Not found
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| UN Pkg. Group : |
Not determined
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| UN item : |
Not determined
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| ERG Number : |
Not determined
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| Land transport (ADR/RID) |
| Class : |
Not determined
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| Transportfactor : |
Not determined
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| Marine transport (IMDG) |
| IMDG-class : |
Not determined
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| Page No. : |
Not determined
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| MFAG : |
Not determined
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| EmS-No. : |
Not determined
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| Air transport (IATA) |
| IATA-class : |
Not determined
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| Passenger : |
Not determined
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| Cargo : |
Not determined
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| 15 : REGULATORY INFORMATION |
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| Reviews, standards, and regulations : |
| None found |
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| 16 : OTHER INFORMATION |
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| Fema No. : | 3068 |
| Hazardous materials identification system : |
| Fire : 2 |
Health : 2 |
Reactivity : 0 |
Personal protection : C
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| Disclaimer |
| The information contained on the Material Data Sheet has been compiled from data considered accurate. ; This data is believed to be reliable, however, it must be pointed out that values for certain properties are known ; to vary from source to source. The Good Scents Company USA Expressly disclaims any warranty expressed or implied ; as well as any liability for any injury or loss arising from the use of this information or the materials described. ; This data is not to be construed as absolutely complete since additional data may be desirable when particular ; conditions or circumstances exist. It is the responsibility of the user to determine the best precautions ; necessary for the safe handling and use of this product for your application. This data relates only to the ; specific material designated and not to be used in combination with any other material. Many federal and state ; regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material. ; It is the purchaser's responsiblity to familiarize themselves with all applicable regulations. |