| SAFETY DATA SHEET |
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| 1 : PRODUCT AND COMPANY IDENTIFICATION |
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| Product Code / Trade Name : | RW101455 / methyl salicylate |
| Supplier Details : | The Good Scents Company
1977 E. Montana Ave., Oak Creek, WI 53154 |
| Information : | 414-764-2659 |
| Version Date : | 06/06/2017 |
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| 2 : HAZARDS IDENTIFICATION |
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| 2.1 Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
Acute toxicity, Oral (Category 4), H302
Acute aquatic toxicity (Category 3), H402
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| 2.2 GHS Label elements, including precautionary statements |
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| Pictogram |  |
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| Signal word | Warning |
| Hazard statement(s) |
H302 - Harmful if swallowed
H402 - Harmful to aquatic life
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| Precautionary statement(s) |
P264 - Wash skin thouroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P273 - Avoid release to the environment.
P301 + P312 - IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P330 - Rinse mouth.
P501 - Dispose of contents/ container to an approved waste disposal plant.
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| 3 : COMPOSITION / INFORMATION ON INGREDIENTS |
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| Chemical characterization : |
| Hazardous ingredient(s) : |
| methyl 2-hydroxybenzoate 99.00 to 100.00 % |
| Hazard symbols : Xn R phrases : 22 36/38
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| mol./wt. : 152.1493600
formula : C8 H8 O3
cas: 119-36-8
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| einecs: 204-317-7 |
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| 4 : FIRST-AID MEASURES |
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| Remove contaminated soaked clothing and wash before reuse. |
| After eye contact : |
| In case of contact with eyes, rinse immediately with plenty of water for at least 10 minutes. Assure adequate flushing by separating the eyelids with fingers and seek medical advice. |
| After skin contact : |
| After contact with skin, wash immediately affected area with soap and plenty of water. |
| After inhalation : |
| If inhaled, remove person to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. |
| After ingestion : |
| If swallowed, rinse mouth with water (only if the person is conscious). Obtain medical advice. |
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| 5 : FIRE-FIGHTING MEASURES |
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| Extinguishing media : |
| Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. |
| Special firefighting procedures : |
| Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. |
| Unusual fire and explosion hazards : |
| Emits toxic fumes under fire conditions. |
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| 6 : ACCIDENTAL RELEASE MEASURES |
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| Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves. Keep people away, evacuate area. |
| To avoid possible contamination of the environment, Do not discharge into any drains, surface waters or groundwaters. |
| Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. |
| Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. Dispose of in accordance with current laws and regulations. |
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| 7 : HANDLING AND STORAGE |
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| Measures should be taken to prevent materials from being splashed into the eyes or on the skin. Wear eyeshields and protective clothing. Smoking should not be permitted in work areas. |
| Provide suitable air extraction ventilation in the work areas. Vapors may form explosive mixtures with air. Keep material away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges. |
| To be stored in tightly sealed and preferably full containers in cool, dry and ventilated area. Protect from heat/overheating and light sources. |
| Keep in glass, suitable plastic, aluminum or laquer-lined containers. |
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| 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION |
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| Occupational exposure limits : |
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OSHA TWA : Not determined |
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ACGIH TWA : Not determined |
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NIOSH TWA : Not determined |
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OSHA PEL : Not determined |
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ACGIH STEL : Not determined |
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NIOSH STEL : Not determined |
| Respiratory protection : |
| Do not breath vapors. Mechanical exhaust required. In confined or poorly ventilated areas, the use of an appropriate respiratory protection may be required. |
| Hand protection : |
| Compatible chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. |
| Eye protection : |
| Chemical safety goggles are recommended. Wash contaminated goggles before reuse. |
| Body protection : |
| Light protective clothing recommended. Wash contaminated clothing before reuse. |
| Hygiene measures : |
| Avoid inhalation and contact with skin and eyes. Good personal hygiene practices should be used. Wash after any contact, before breaks and meals, and at the end of the work period. Safety shower and eye bath recommended. |
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| 9 : PHYSICAL AND CHEMICAL PROPERTIES |
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| Appearance / odor : |
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colorless to pink clear liquid / wintergreen mint |
| Melting point : | -8.00 to -7.00 °C. @ 760.00 mmHg
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| Boiling point : | 222.00 to 224.00°C. @ 760.00 mmHg
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| Flash point ( ° F. ) : | 205.00 °F. TCC ( 96.11 °C. )
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| Flammability : | Not determined
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| Autoflammability : | 847.00
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| Explosive properties : | Not determined
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| Oxidizing properties : | Not determined
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| Vapor pressure : | 0.03430 mm/Hg @ 25.00 °C.
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| Vapor density : | 5.26 ( Air = 1 )
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| Volatile by volume : | 100.00 %
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| Evaporation rate : | Not determined
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| Specific gravity : | 1.18000 to 1.18500 @ 25 °C.
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| PH of Product : | Not determined
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| Solubility in water : | Very Slightly Soluble |
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| 10 : STABILITY AND REACTIVITY |
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| Stability : |
Stable
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| Conditions to avoid : |
Heat, excessive heat, open flames and other sources of ignition. |
| Incompatibility : |
Strong oxidizing agents, strong reducing agents. |
| Hazardous decomposition products : |
Hazardous combustion or decomposition products: carbon monoxide, carbon dioxide. Hazardous polymerization will not occur. |
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| 11 : TOXICOLOGICAL INFORMATION |
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| Acute effects : |
Harmful if swallowed
Harmful to aquatic life
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| Oral Toxicity(LD50) : |
gavage-mouse [sex: M] 1390 mg/kg (Ohsumi et al., 1984)
gavage-rat 1250 mg/kg (Giroux et al., 1954b)
oral-rat [sex: M,F] M:3049.00 F:2642 mg/kg (Givaudan Corporation, 1982)
gavage-rat [sex: M,F] 887 mg/kg (Jenner et al., 1964)
oral-rat 1220 mg/kg (Nivikov et al., 1994)
oral-mouse [sex: M] 1110 mg/kg (Davison et al., 1961)
gavage-guinea pig [sex: M,F] 1060 mg/kg (Jenner et al., 1964)
gavage-mouse [sex: M,F] 1440 mg/kg (NTP, 1984a)
oral-woman 355 mg/kg American Journal of the Medical Sciences. Vol. 193, Pg. 772, 1937.
oral-rat 887 mg/kg Food and Cosmetics Toxicology. Vol. 2, Pg. 327, 1964.
oral-rabbit 1300 mg/kg Food and Cosmetics Toxicology. Vol. 16, Pg. 821, 1978.
oral-mouse 1110 mg/kg Journal of Pharmacology and Experimental Therapeutics. Vol. 132, Pg. 207, 1961.
unreported-man 522 mg/kg "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970.
oral-man 1329 mg/kg Clinical Toxicology. Vol. 6, Pg. 189, 1973.
oral-man 101 mg/kg American Journal of the Medical Sciences. Vol. 193, Pg. 772, 1937.
oral-human 506 mg/kg "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals", 11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989Vol. 11, Pg. 961, 1989.
oral-guinea pig 700 mg/kg "Industrial Hygiene and Toxicology," 2nd ed., Patty, F.A., ed., New York, John Wiley & Sons, Inc., 1958-63Vol. 2, Pg. 1897, 1963.
oral-dog 2100 mg/kg Food and Cosmetics Toxicology. Vol. 16, Pg. 821, 1978.
oral-child 700 mg/kg Archives of Disease in Childhood. Vol. 28, Pg. 475, 1953.
oral-child 228 mg/kg American Journal of Diseases of Children. Vol. 69, Pg. 37, 1945.
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| Dermal Toxicity(LD50) : |
subcutaneous-dog 2250 mg/kg Food and Cosmetics Toxicology. Vol. 16, Pg. 821, 1978.
subcutaneous-guinea pig 1500 mg/kg FAO Nutrition Meetings Report Series. Vol. 44A, Pg. 63, 1967.
subcutaneous-rabbit 4250 mg/kg Food and Cosmetics Toxicology. Vol. 16, Pg. 821, 1978.
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| Skin Irritation : |
skin-rabbit 500 mg/24hours moderate FCTXAV 16,821,1978
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| Eye Irritation : |
eye-rabbit 500 mg/24hours mild 85JCAE -,668,1986
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| Inhalation data(LC50) : |
Not determined
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| Mutagenicity data : |
Not determined
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| Phototoxicity data : |
Not determined
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| Human experience : |
8 % solution: no irritation or sensitization.
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| Carcinogenicity : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
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| Reproductive toxin : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
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| On the TSCA Inventory? : |
Yes |
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| 12 : ECOLOGICAL INFORMATION |
| Biodegradability |
| Readily biodegradable : |
Yes to OECD criteria
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| Inherently biodegradable : |
Not determined
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| Ecotoxicity |
| Fish : |
LC0 42.00 MG/L/96H Brachydanio reri
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| Algae : |
Not determined
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| Daphnia : |
EC50 50.00 MG/L/24H Daphnia
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| Bacteria : |
EC50 250.00 MG/L Activated sludge OECD 209 / ISO 8192
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| Further information : |
Prevent contamination of soil, ground and surface waters. Do not discharge product unmonitored into the environment. |
| Mixture reportable to : |
FIFRA-Inerts |
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| 13 : DISPOSAL CONSIDERATIONS |
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Dispose of in accordance with all federal, state and local environmental regulations.
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| 14 : TRANSPORT INFORMATION |
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| US DOT Hazard Class : |
LIQUID, N.O.S. (METHYL SALICYLATE)
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| UN Number : |
3082
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| UN Pkg. Group : |
III
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| UN item : |
Not determined
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| ERG Number : |
Not determined
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| Land transport (ADR/RID) |
| Class : |
Not determined
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| Transportfactor : |
Not determined
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| Marine transport (IMDG) |
| IMDG-class : |
9
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| Page No. : |
9028
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| MFAG : |
Not determined
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| EmS-No. : |
Not determined
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| Air transport (IATA) |
| IATA-class : |
Not determined
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| Passenger : |
not regulate
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| Cargo : |
not regulate
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| 15 : REGULATORY INFORMATION |
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| Reviews, standards, and regulations : |
| EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC 54,7740,1989
NOHS 1974: HZD 48320; NIS 138; TNF 15668; NOS 80; TNE 105490
NOES 1983: HZD 48320; NIS 193; TNF 30724; NOS 134; TNE 454822; TFE 134722
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JANUARY 2001
German Regulations on Flammable Liquids - VbF: class AIII.
Water pollution class (WGK = Classification in accordance with the German
Water Resources Act): WGK 1 - slightly hazardous to water. (self classification) |
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| 16 : OTHER INFORMATION |
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| Fema No. : | 2745 |
| Hazardous materials identification system : |
| Fire : 1 |
Health : 1 |
Reactivity : 0 |
Personal protection : C
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| Disclaimer |
| The information contained on the Material Data Sheet has been compiled from data considered accurate. ; This data is believed to be reliable, however, it must be pointed out that values for certain properties are known ; to vary from source to source. The Good Scents Company USA Expressly disclaims any warranty expressed or implied ; as well as any liability for any injury or loss arising from the use of this information or the materials described. ; This data is not to be construed as absolutely complete since additional data may be desirable when particular ; conditions or circumstances exist. It is the responsibility of the user to determine the best precautions ; necessary for the safe handling and use of this product for your application. This data relates only to the ; specific material designated and not to be used in combination with any other material. Many federal and state ; regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material. ; It is the purchaser's responsiblity to familiarize themselves with all applicable regulations. |