| SAFETY DATA SHEET |
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| 1 : PRODUCT AND COMPANY IDENTIFICATION |
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| Product Code / Trade Name : | RW101442 / dextro- limonene |
| Supplier Details : | The Good Scents Company
1977 E. Montana Ave., Oak Creek, WI 53154 |
| Information : | 414-764-2659 |
| Version Date : | 06/06/2017 |
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| 2 : HAZARDS IDENTIFICATION |
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| 2.1 Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
Flammable liquids (Category 3), H226
Aspiration hazard (Category 1), H304
Skin irritation (Category 2), H315
Skin sensitisation (Category 1), H317
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410
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| 2.2 GHS Label elements, including precautionary statements |
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| Pictogram |     |
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| Signal word | Danger |
| Hazard statement(s) |
H226 - Flammable liquid and vapour
H304 - May be fatal if swallowed and enters airways
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H400 - Very toxic to aquatic life
H410 - Very toxic to aquatic life with long lasting effects
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| Precautionary statement(s) |
P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash skin thouroughly after handling.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P331 - Do NOT induce vomiting.
P333 + P313 - IF SKIN irritation or rash occurs: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P391 - Collect spillage. Hazardous to the aquatic environment
P403 + P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/ container to an approved waste disposal plant.
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| 3 : COMPOSITION / INFORMATION ON INGREDIENTS |
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| Chemical characterization : |
| Hazardous ingredient(s) : |
| 1-methyl-4-isopropenyl-1-cyclohexene 96.00 to 100.00 % |
| Hazard symbols : Xi N R phrases : 10 38 43 50/53 65
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| mol./wt. : 136.2375200
formula : C10 H16
cas: 5989-27-5; 58555-74-1
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| einecs: 227-813-5 |
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| 4 : FIRST-AID MEASURES |
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| Remove contaminated soaked clothing and wash before reuse. |
| After eye contact : |
| In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes. |
| After skin contact : |
| After contact with skin, wash immediately affected area with soap and plenty of water. |
| After inhalation : |
| If inhaled, remove person to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. |
| After ingestion : |
| If swallowed, rinse mouth with water (only if the person is conscious). Obtain medical advice. |
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| 5 : FIRE-FIGHTING MEASURES |
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| Extinguishing media : |
| Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. |
| Special firefighting procedures : |
| Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. |
| Unusual fire and explosion hazards : |
| Emits toxic fumes under fire conditions. |
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| 6 : ACCIDENTAL RELEASE MEASURES |
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| Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves. Keep people away, evacuate area. |
| To avoid possible contamination of the environment, Do not discharge into any drains, surface waters or groundwaters. |
| Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. |
| Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. Dispose of in accordance with current laws and regulations. |
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| 7 : HANDLING AND STORAGE |
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| Measures should be taken to prevent materials from being splashed into the eyes or on the skin. Wear eyeshields and protective clothing. Smoking should not be permitted in work areas. |
| Provide suitable air extraction ventilation in the work areas. Vapors may form explosive mixtures with air. Keep material away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges. |
| To be stored in tightly sealed and preferably full containers in cool, dry and ventilated area. Protect from heat/overheating and light sources. |
| Keep in glass, suitable plastic, aluminum or laquer-lined containers. |
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| 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION |
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| Occupational exposure limits : |
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OSHA TWA : Not determined |
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ACGIH TWA : 20.00 ppm |
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NIOSH TWA : Not determined |
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OSHA PEL : Not determined |
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ACGIH STEL : Not determined |
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NIOSH STEL : Not determined |
| Respiratory protection : |
| Do not breath vapors. Mechanical exhaust required. In confined or poorly ventilated areas, the use of an appropriate respiratory protection may be required. |
| Hand protection : |
| Compatible chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. |
| Eye protection : |
| Chemical safety goggles are recommended. Wash contaminated goggles before reuse. |
| Body protection : |
| Light protective clothing recommended. Wash contaminated clothing before reuse. |
| Hygiene measures : |
| Avoid inhalation and contact with skin and eyes. Good personal hygiene practices should be used. Wash after any contact, before breaks and meals, and at the end of the work period. Safety shower and eye bath recommended. |
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| 9 : PHYSICAL AND CHEMICAL PROPERTIES |
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| Appearance / odor : |
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colorless to pale yellow clear liquid / citrus orange fresh sweet |
| Melting point : | -96.00 °C. @ 760.00 mmHg
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| Boiling point : | 175.00 to 177.00°C. @ 760.00 mmHg
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| Flash point ( ° F. ) : | 117.00 °F. TCC ( 47.22 °C. )
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| Explosion limits in air : |
Upper :6.10 | Lower :0.70
| | Flammability : | Not determined
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| Autoflammability : | 238
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| Explosive properties : | Not determined
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| Oxidizing properties : | Not determined
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| Vapor pressure : | 0.19800 mm/Hg @ 25.00 °C.
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| Vapor density : | 4.7 ( Air = 1 )
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| Volatile by volume : | 100.00 %
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| Evaporation rate : | Not determined
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| Specific gravity : | 0.83800 to 0.84300 @ 25 °C.
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| PH of Product : | Not determined
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| Solubility in water : | Insoluble |
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| 10 : STABILITY AND REACTIVITY |
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| Stability : |
Stable
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| Conditions to avoid : |
Heat, excessive heat, open flames and other sources of ignition. |
| Incompatibility : |
Strong oxidizing agents, strong reducing agents. |
| Hazardous decomposition products : |
Carbon monoxide, carbon dioxide. Hazardous polymerization will not occur. |
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| 11 : TOXICOLOGICAL INFORMATION |
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| Acute effects : |
Flammable liquid and vapour
May be fatal if swallowed and enters airways
Causes skin irritation
May cause an allergic skin reaction
Very toxic to aquatic life
Very toxic to aquatic life with long lasting effects
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| Oral Toxicity(LD50) : |
oral-rat [sex: M] > 5000 mg/kg (Moreno, 1972m)
oral-rat [sex: M,F] M:4400 F:5100 mg/kg (Tsuji et al., 1975a)
oral-mouse [sex: M,F] M:5600 F:6600 mg/kg (Tsuji et al., 1975a)
intraperitoneal-mouse 600 mg/kg Oyo Yakuri. Pharmacometrics. Vol. 8, Pg. 1439, 1974.
oral-mouse 5600 mg/kg Oyo Yakuri. Pharmacometrics. Vol. 9, Pg. 387, 1975.
intraperitoneal-rat 3600 mg/kg Oyo Yakuri. Pharmacometrics. Vol. 9, Pg. 387, 1975.
intravenous-rat 110 mg/kg Oyo Yakuri. Pharmacometrics. Vol. 9, Pg. 387, 1975.
oral-rat 4400 mg/kg Oyo Yakuri. Pharmacometrics. Vol. 9, Pg. 387, 1975.
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| Dermal Toxicity(LD50) : |
skin-rabbit > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 13, Pg. 825, 1975.
subcutaneous-mouse 3170 mg/kg Sapporo Igaku Zasshi. Sapporo Medical Journal. Vol. 3, Pg. 73, 1952.
skin-mammal (species unspecified) > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 12, Pg. 703, 1974.
subcutaneous-rat 30200 mg/kg Oyo Yakuri. Pharmacometrics. Vol. 9, Pg. 387, 1975.
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| Skin Irritation : |
Not determined
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| Eye Irritation : |
Not determined
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| Inhalation data(LC50) : |
Not determined
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| Mutagenicity data : |
Not determined
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| Phototoxicity data : |
Not determined
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| Human experience : |
4 % solution: no irritation or sensitization.
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| Carcinogenicity : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
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| Reproductive toxin : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
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| On the TSCA Inventory? : |
Yes |
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| 12 : ECOLOGICAL INFORMATION |
| Biodegradability |
| Readily biodegradable : |
Not determined
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| Inherently biodegradable : |
Not determined
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| Ecotoxicity |
| Fish : |
Not determined
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| Algae : |
Not determined
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| Daphnia : |
EC50 MG/L/48H Daphnia magna
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| Bacteria : |
Not determined
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| Further information : |
Prevent contamination of soil, ground and surface waters. Do not discharge product unmonitored into the environment. |
| Mixture reportable to : |
FIFRA-Inerts |
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| 13 : DISPOSAL CONSIDERATIONS |
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Dispose of in accordance with all federal, state and local environmental regulations.
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| 14 : TRANSPORT INFORMATION |
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| US DOT Hazard Class : |
TERPENE HYDROCARBON, N.O.S. (TERPENES)
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| UN Number : |
2319
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| UN Pkg. Group : |
III
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| UN item : |
Not determined
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| ERG Number : |
128
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| Land transport (ADR/RID) |
| Class : |
3
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| Transportfactor : |
1
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| Marine transport (IMDG) |
| IMDG-class : |
3.3
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| Page No. : |
3383
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| MFAG : |
Not determined
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| EmS-No. : |
Not determined
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| Air transport (IATA) |
| IATA-class : |
3
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| Passenger : |
Not determined
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| Cargo : |
Not determined
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| 15 : REGULATORY INFORMATION |
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| Reviews, standards, and regulations : |
| IARC CANCER REVIEW:ANIMAL LIMITED EVIDENCE IMEMDT 56,135,1993
IARC CANCER REVIEW:ANIMAL SUFFICIENT EVIDENCE IMEMDT 73,307,1999
IARC CANCER REVIEW:HUMAN NO AVAILABLE DATA IMEMDT 56,135,1993
IARC CANCER REVIEW:HUMAN INADEQUATE EVIDENCE IMEMDT 73,307,1999
IARC CANCER REVIEW:GROUP 3 IMEMDT 73,307,1999
NOES 1983: HZD X9088; NIS 87; TNF 8310; NOS 65; TNE 138309; TFE 35634
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES
ON EPA IRIS DATABASE
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JANUARY 2001
NIOSH ANALYTICAL METHOD, 1996: VOLATILE ORGANIC COMPOUND, 2549
NTP CARCINOGENESIS STUDIES (GAVAGE);CLEAR EVIDENCE:RAT
NTPTR* NTP-TR-347,1990
NTP CARCINOGENESIS STUDIES (GAVAGE);NO EVIDENCE:MOUSE
NTPTR* NTP-TR-347,1990 |
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| 16 : OTHER INFORMATION |
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| Fema No. : | 2633 |
| Hazardous materials identification system : |
| Fire : 2 |
Health : 2 |
Reactivity : 0 |
Personal protection : B
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| Disclaimer |
| The information contained on the Material Data Sheet has been compiled from data considered accurate. ; This data is believed to be reliable, however, it must be pointed out that values for certain properties are known ; to vary from source to source. The Good Scents Company USA Expressly disclaims any warranty expressed or implied ; as well as any liability for any injury or loss arising from the use of this information or the materials described. ; This data is not to be construed as absolutely complete since additional data may be desirable when particular ; conditions or circumstances exist. It is the responsibility of the user to determine the best precautions ; necessary for the safe handling and use of this product for your application. This data relates only to the ; specific material designated and not to be used in combination with any other material. Many federal and state ; regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material. ; It is the purchaser's responsiblity to familiarize themselves with all applicable regulations. |