| SAFETY DATA SHEET |
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| 1 : PRODUCT AND COMPANY IDENTIFICATION |
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| Product Code / Trade Name : | RW101419 / ethyl acetoacetate |
| Supplier Details : | The Good Scents Company
1977 E. Montana Ave., Oak Creek, WI 53154 |
| Information : | 414-764-2659 |
| Version Date : | 09/03/2020 |
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| 2 : HAZARDS IDENTIFICATION |
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| 2.1 Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
Flammable liquids (Category 3), H226
Eye irritation (Category 2A), H319
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
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| 2.2 GHS Label elements, including precautionary statements |
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| Pictogram |   |
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| Signal word | Warning |
| Hazard statement(s) |
H226 - Flammable liquid and vapour
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
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| Precautionary statement(s) |
P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash skin thouroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P337 + P313 - IF eye irritation persists: Get medical advice/attention.
P370 + P378 - In case of fire: Use appropriate media for extinction.
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 - Store in a well-ventilated place. Keep cool.
P501 - Dispose of contents/container in accordance with local/regional/national/international regulations.
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| 3 : COMPOSITION / INFORMATION ON INGREDIENTS |
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| Chemical characterization : |
| Hazardous ingredient(s) : |
| ethyl 3-oxobutanoate 99.00 to 100.00 % |
| Hazard symbols : Xi R phrases : 36/37/38
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| mol./wt. : 130.1433000
formula : C6 H10 O3
cas: 141-97-9
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| einecs: 205-516-1 |
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| 4 : FIRST-AID MEASURES |
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| Remove contaminated soaked clothing and wash before reuse. |
| After eye contact : |
| In case of contact with eyes, rinse immediately with plenty of water for at least 10 minutes and seek medical advice. |
| After skin contact : |
| After contact with skin, wash immediately affected area with soap and plenty of water. |
| After inhalation : |
| If inhaled, remove person to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. |
| After ingestion : |
| If swallowed, rinse mouth with water (only if the person is conscious). Obtain medical advice. |
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| 5 : FIRE-FIGHTING MEASURES |
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| Extinguishing media : |
| Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. |
| Special firefighting procedures : |
| Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. |
| Unusual fire and explosion hazards : |
| Emits toxic fumes under fire conditions. |
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| 6 : ACCIDENTAL RELEASE MEASURES |
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| Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves. Keep people away, evacuate area. |
| To avoid possible contamination of the environment, Do not discharge into any drains, surface waters or groundwaters. |
| Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. |
| Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. Dispose of in accordance with current laws and regulations. |
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| 7 : HANDLING AND STORAGE |
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| Measures should be taken to prevent materials from being splashed into the eyes or on the skin. Wear eyeshields and protective clothing. Smoking should not be permitted in work areas. |
| Provide suitable air extraction ventilation in the work areas. Vapors may form explosive mixtures with air. Keep material away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges. |
| To be stored in tightly sealed and preferably full containers in cool, dry and ventilated area. Protect from heat/overheating and light sources. |
| Keep in glass, suitable plastic, aluminum or laquer-lined containers. |
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| 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION |
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| Occupational exposure limits : |
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OSHA TWA : Not determined |
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ACGIH TWA : Not determined |
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NIOSH TWA : Not determined |
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OSHA PEL : Not determined |
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ACGIH STEL : Not determined |
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NIOSH STEL : Not determined |
| Respiratory protection : |
| Do not breath vapors. Mechanical exhaust required. In confined or poorly ventilated areas, the use of an appropriate respiratory protection may be required. |
| Hand protection : |
| Compatible chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. |
| Eye protection : |
| Chemical safety goggles are recommended. Wash contaminated goggles before reuse. |
| Body protection : |
| Light protective clothing recommended. Wash contaminated clothing before reuse. |
| Hygiene measures : |
| Avoid inhalation and contact with skin and eyes. Good personal hygiene practices should be used. Wash after any contact, before breaks and meals, and at the end of the work period. Safety shower and eye bath recommended. |
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| 9 : PHYSICAL AND CHEMICAL PROPERTIES |
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| Appearance / odor : |
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colorless to yellow clear liquid / fresh fruity green apple fatty |
| Melting point : | -45.40 to -44.00 °C. @ 760.00 mmHg
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| Boiling point : | 180.00 to 181.00°C. @ 760.00 mmHg
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| Flash point ( ° F. ) : | 184.00 °F. TCC ( 84.44 °C. )
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| Explosion limits in air : |
Upper :9.50 | Lower :1.40
| | Flammability : | Not determined
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| Autoflammability : | 580.00
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| Explosive properties : | Not determined
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| Oxidizing properties : | Not determined
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| Vapor pressure : | 0.89000 mm/Hg @ 25.00 °C.
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| Vapor density : | 4.48 ( Air = 1 )
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| Volatile by volume : | 100.00 %
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| Evaporation rate : | 0.1 ( Butyl acetate = 1 )
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| Specific gravity : | 1.02200 to 1.02710 @ 25 °C.
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| PH of Product : | 3.80
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| Solubility in water : | Slightly Soluble |
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| 10 : STABILITY AND REACTIVITY |
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| Stability : |
Stable
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| Conditions to avoid : |
Heat, excessive heat, open flames and other sources of ignition. |
| Incompatibility : |
Strong oxidizing agents, strong reducing agents. |
| Hazardous decomposition products : |
Hazardous combustion or decomposition products: carbon monoxide, carbon dioxide. Hazardous polymerization will not occur. |
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| 11 : TOXICOLOGICAL INFORMATION |
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| Acute effects : |
Flammable liquid and vapour
Causes serious eye irritation
May cause respiratory irritation
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| Oral Toxicity(LD50) : |
oral-rat 3980 mg/kg (Smyth et al., 1949)
oral-mouse 5105 mg/kg Journal of Pharmaceutical Sciences. Vol. 60, Pg. 1810, 1971.
oral-rat 3980 mg/kg Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 60, 1949.
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| Dermal Toxicity(LD50) : |
skin-rabbit > 5000 mg/kg
skin-rabbit > 20 mL/kg Union Carbide Data Sheet. Vol. 3/12/1969
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| Skin Irritation : |
skin-rabbit 510 mg open mild UCDS** 3/12/1969
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| Eye Irritation : |
eye-rabbit 100 mg/24hours moderate 85JCAE -,729,1986
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| Inhalation data(LC50) : |
Not determined
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| Mutagenicity data : |
Not determined
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| Phototoxicity data : |
Not determined
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| Human experience : |
8 % solution: non-sensitising.
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| Carcinogenicity : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
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| Reproductive toxin : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
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| On the TSCA Inventory? : |
Yes |
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| 12 : ECOLOGICAL INFORMATION |
| Biodegradability |
| Readily biodegradable : |
Yes to OECD criteria
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| Inherently biodegradable : |
Not determined
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| Ecotoxicity |
| Fish : |
LC0 412.00 MG/L/48H Leuciscus idus DIN 38412,15
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| Algae : |
EC50 > 500.00 MG/L Scenedesmus subspica OECD 201 / ISO 8692
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| Daphnia : |
EC50 790.00 MG/L Daphnia
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| Bacteria : |
EC0 3000.00 MG/L Bacteria Gaehrroehrchentest
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| Further information : |
Prevent contamination of soil, ground and surface waters. Do not discharge product unmonitored into the environment. |
| Mixture reportable to : |
CAA 111, FIFRA-Inerts |
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| 13 : DISPOSAL CONSIDERATIONS |
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Dispose of in accordance with all federal, state and local environmental regulations.
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| 14 : TRANSPORT INFORMATION |
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| US DOT Hazard Class : |
n/a keep away from children
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| UN Number : |
Not found
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| UN Pkg. Group : |
Not determined
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| UN item : |
Not determined
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| ERG Number : |
Not determined
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| Land transport (ADR/RID) |
| Class : |
Not determined
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| Transportfactor : |
Not determined
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| Marine transport (IMDG) |
| IMDG-class : |
Not determined
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| Page No. : |
Not determined
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| MFAG : |
Not determined
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| EmS-No. : |
Not determined
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| Air transport (IATA) |
| IATA-class : |
Not determined
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| Passenger : |
Not determined
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| Cargo : |
Not determined
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| 15 : REGULATORY INFORMATION |
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| Reviews, standards, and regulations : |
| None found |
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| 16 : OTHER INFORMATION |
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| Fema No. : | 2415 |
| Hazardous materials identification system : |
| Fire : 2 |
Health : 2 |
Reactivity : 0 |
Personal protection : B
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| Disclaimer |
| The information contained on the Material Data Sheet has been compiled from data considered accurate. ; This data is believed to be reliable, however, it must be pointed out that values for certain properties are known ; to vary from source to source. The Good Scents Company USA Expressly disclaims any warranty expressed or implied ; as well as any liability for any injury or loss arising from the use of this information or the materials described. ; This data is not to be construed as absolutely complete since additional data may be desirable when particular ; conditions or circumstances exist. It is the responsibility of the user to determine the best precautions ; necessary for the safe handling and use of this product for your application. This data relates only to the ; specific material designated and not to be used in combination with any other material. Many federal and state ; regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material. ; It is the purchaser's responsiblity to familiarize themselves with all applicable regulations. |