| SAFETY DATA SHEET |
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| 1 : PRODUCT AND COMPANY IDENTIFICATION |
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| Product Code / Trade Name : | RW101388 / benzyl acetate |
| Supplier Details : | The Good Scents Company
1977 E. Montana Ave., Oak Creek, WI 53154 |
| Information : | 414-764-2659 |
| Version Date : | 09/03/2020 |
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| 2 : HAZARDS IDENTIFICATION |
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| 2.1 Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
Skin irritation (Category 2), H315
Eye irritation (Category 2A), H319
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Chronic aquatic toxicity (Category 2), H411
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| 2.2 GHS Label elements, including precautionary statements |
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| Pictogram |   |
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| Signal word | Warning |
| Hazard statement(s) |
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
H411 - Toxic to aquatic life with long lasting effects
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| Precautionary statement(s) |
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash hands thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 - IF ON SKIN: wash with plenty of soap and water.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P321 - Specific treatment (see supplemental first aid instructions on this msds).
P332 + P313 - IF SKIN irritation occurs: Get medical advice/attention.
P337 + P313 - IF eye irritation persists: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P391 - Collect spillage. Hazardous to the aquatic environment
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
P405 - Store locked up.
P501 - Dispose of contents/ container to an approved waste disposal plant.
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| 3 : COMPOSITION / INFORMATION ON INGREDIENTS |
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| Chemical characterization : |
| Hazardous ingredient(s) : |
| benzyl ethanoate 98.00 to 100.00 % |
| Hazard symbols : Xi R phrases : 36/37/38
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| mol./wt. : 150.1771000
formula : C9 H10 O2
cas: 140-11-4
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| einecs: 205-399-7 |
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| 4 : FIRST-AID MEASURES |
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| Remove contaminated soaked clothing immediately and dispose of safely. |
| After eye contact : |
| In case of contact with eyes, rinse immediately with plenty of water for at least 10 minutes and seek medical advice. |
| After skin contact : |
| After contact with skin, wash immediately affected area with soap and plenty of water. Seek medical advice if irritation persists. |
| After inhalation : |
| If inhaled, remove person to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. |
| After ingestion : |
| If swallowed, rinse mouth with water (only if the person is conscious). Obtain medical advice. |
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| 5 : FIRE-FIGHTING MEASURES |
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| Extinguishing media : |
| Carbon Dioxide; Dry Chemical; Universal-Type Foam. |
| Special firefighting procedures : |
| Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. |
| Unusual fire and explosion hazards : |
| Emits toxic fumes under fire conditions. |
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| 6 : ACCIDENTAL RELEASE MEASURES |
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| Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves. Keep people away, evacuate area. |
| To avoid possible contamination of the environment, Do not discharge into any drains, surface waters or groundwaters. |
| Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. |
| Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. Dispose of in accordance with current laws and regulations. |
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| 7 : HANDLING AND STORAGE |
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| Measures should be taken to prevent materials from being splashed into the eyes or on the skin. Wear eyeshields and protective clothing. Smoking should not be permitted in work areas. |
| Provide suitable air extraction ventilation in the work areas. Vapors may form explosive mixtures with air. Keep material away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges. |
| To be stored in tightly sealed and preferably full containers in cool, dry and ventilated area. Protect from heat/overheating and light sources. |
| Keep only in original container. |
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| 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION |
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| Occupational exposure limits : |
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OSHA TWA : Not determined |
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ACGIH TWA : 10.00 ppm |
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NIOSH TWA : Not determined |
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OSHA PEL : Not determined |
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ACGIH STEL : Not determined |
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NIOSH STEL : Not determined |
| Respiratory protection : |
| Do not breath vapors. Mechanical exhaust required. In confined or poorly ventilated areas, the use of an appropriate respiratory protection may be required. |
| Hand protection : |
| Compatible chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. |
| Eye protection : |
| Chemical safety goggles are recommended. Wash contaminated goggles before reuse. |
| Body protection : |
| Light protective clothing recommended. Wash contaminated clothing before reuse. |
| Hygiene measures : |
| Avoid inhalation and contact with skin and eyes. Good personal hygiene practices should be used. Wash after any contact, before breaks and meals, and at the end of the work period. Safety shower and eye bath recommended. |
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| 9 : PHYSICAL AND CHEMICAL PROPERTIES |
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| Appearance / odor : |
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colorless clear liquid / sweet floral fruity jasmin fresh |
| Melting point : | -51.00 to -50.00 °C. @ 760.00 mmHg
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| Boiling point : | 212.00 to 215.00°C. @ 760.00 mmHg
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| Flash point ( ° F. ) : | 203.00 °F. TCC ( 95.00 °C. )
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| Flammability : | Not determined
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| Autoflammability : | Not determined
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| Explosive properties : | Not determined
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| Oxidizing properties : | Not determined
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| Vapor pressure : | 0.17700 mm/Hg @ 25.00 °C.
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| Vapor density : | Not determined
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| Volatile by volume : | 100.00 %
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| Evaporation rate : | Not determined
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| Specific gravity : | 1.05200 to 1.05600 @ 25 °C.
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| PH of Product : | Not determined
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| Solubility in water : | Insoluble |
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| 10 : STABILITY AND REACTIVITY |
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| Stability : |
Stable
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| Conditions to avoid : |
Heat, excessive heat, open flames and other sources of ignition. |
| Incompatibility : |
Strong oxidizing agents, strong reducing agents. |
| Hazardous decomposition products : |
Hazardous combustion or decomposition products: carbon monoxide, carbon dioxide. Hazardous polymerization will not occur. |
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| 11 : TOXICOLOGICAL INFORMATION |
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| Acute effects : |
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation
Toxic to aquatic life with long lasting effects
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| Oral Toxicity(LD50) : |
oral-rabbit 2640 mg/kg (Graham & Kuizenga, 1945)
gavage-rat [sex: M,F] 2490 mg/kg (Jenner et al., 1964)
oral-rat 3690 mg/kg (Graham & Kuizenga, 1945)
oral-guinea pig 2200 mg/kg Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 50(7), Pg. 17, 1985.
oral-rat 2490 mg/kg Food and Cosmetics Toxicology. Vol. 2, Pg. 327, 1964.
oral-rabbit 2200 mg/kg Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 50(7), Pg. 17, 1985.
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| Dermal Toxicity(LD50) : |
skin-rabbit > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 11, Pg. 875, 1973.
skin-cat 10000 mg/kg Journal of Pharmacology and Experimental Therapeutics. Vol. 84, Pg. 358, 1945.
subcutaneous-guinea pig 3000 mg/kg Archiv fuer Gewerbepathologie und Gewerbehygiene. Vol. 5, Pg. 1, 1933.
subcutaneous-rabbit 4000 mg/kg Archiv fuer Gewerbepathologie und Gewerbehygiene. Vol. 5, Pg. 1, 1933.
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| Skin Irritation : |
skin-rabbit 100 mg/24hours moderate CTOIDG 94(8),41,79
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| Eye Irritation : |
Not determined
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| Inhalation data(LC50) : |
inhalation-cat 245 ppm/8H AMA Archives of Industrial Health. Vol. 21, Pg. 28, 1960.
inhalation-human 50 ppm "Handbook of Organic Industrial Solvents," 2nd ed., Chicago, National Assoc. of Mutual Casualty Companies, 1961Vol. 2, Pg. 31, 1961.
inhalation-mouse 1300 mg/m3/22 Archiv fuer Gewerbepathologie und Gewerbehygiene. Vol. 5, Pg. 1, 1933.
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| Mutagenicity data : |
Not determined
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| Phototoxicity data : |
Not determined
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| Human experience : |
32 % solution: no skin irritation.
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| Carcinogenicity : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
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| Reproductive toxin : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
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| On the TSCA Inventory? : |
Yes |
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| 12 : ECOLOGICAL INFORMATION |
| Biodegradability |
| Readily biodegradable : |
Yes 100%
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| Inherently biodegradable : |
Not determined
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| Ecotoxicity |
| Fish : |
LC50 7.90 MG/L Brachydanio reri Anh. V,C.1 RL 67/548/EEC
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| Algae : |
Not determined
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| Daphnia : |
Not determined
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| Bacteria : |
EC50 885.00 MG/L Activated sludge ISO 8192-1986(E)/OECD 209
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| Further information : |
Prevent contamination of soil, ground and surface waters. Do not discharge product unmonitored into the environment. |
| Mixture reportable to : |
FIFRA-Inerts |
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| 13 : DISPOSAL CONSIDERATIONS |
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Dispose of in accordance with all federal, state and local environmental regulations.
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| 14 : TRANSPORT INFORMATION |
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| US DOT Hazard Class : |
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Benzyl acetate)
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| UN Number : |
3082
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| UN Pkg. Group : |
III
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| UN item : |
Not determined
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| ERG Number : |
Not determined
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| Land transport (ADR/RID) |
| Class : |
9
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| Transportfactor : |
Not determined
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| Marine transport (IMDG) |
| IMDG-class : |
Not determined
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| Page No. : |
Not determined
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| MFAG : |
Not determined
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| EmS-No. : |
Not determined
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| Air transport (IATA) |
| IATA-class : |
Not determined
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| Passenger : |
Not determined
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| Cargo : |
Not determined
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| 15 : REGULATORY INFORMATION |
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| Reviews, standards, and regulations : |
| ACGIH TLV-NOT CLASSIFIABLE AS A HUMAN CARCINOGEN DTLVS* TLV/BEI,1999
ACGIH TLV-TWA 10 PPM DTLVS* TLV/BEI,1999
IARC CANCER REVIEW:ANIMAL LIMITED EVIDENCE IMEMDT 40,109,1986
IARC CANCER REVIEW:ANIMAL LIMITED EVIDENCE IMEMDT 71,1255,1999
IARC CANCER REVIEW:HUMAN NO ADEQUATE DATA IMEMDT 40,109,1986
IARC CANCER REVIEW:HUMAN NO ADEQUATE DATA IMEMDT 71,1255,1999
IARC CANCER REVIEW:GROUP 3 IMEMDT 71,1255,1999
OEL-RUSSIA: STEL 5 MG/M3, JAN1993
NOHS 1974: HZD 01600; NIS 11; TNF 512; NOS 42; TNE 93580
NOES 1983: HZD 01600; NIS 107; TNF 17141; NOS 108; TNE 275806; TFE 133629
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
NTP CARCINOGENESIS STUDIES (GAVAGE);SOME EVIDENCE:MOUSE,RAT NTPTR* NTP-TR-250,1986
NTP CARCINOGENESIS STUDIES (FEED);NO EVIDENCE:MOUSE,RAT NTPTR* NTP-TR-431,1993
German Regulations on Flammable Liquids - VbF: not subject to the Regulations on Flammable Liquids.
Water pollution class (WGK = Classification in accordance with the German Water Resources Act): WGK 1 - slightly hazardous to water. (self classification)
log P = 1.96
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| 16 : OTHER INFORMATION |
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| Fema No. : | 2135 |
| Hazardous materials identification system : |
| Fire : 1 |
Health : 2 |
Reactivity : 0 |
Personal protection : C
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| Disclaimer |
| The information contained on the Material Data Sheet has been compiled from data considered accurate. ; This data is believed to be reliable, however, it must be pointed out that values for certain properties are known ; to vary from source to source. The Good Scents Company USA Expressly disclaims any warranty expressed or implied ; as well as any liability for any injury or loss arising from the use of this information or the materials described. ; This data is not to be construed as absolutely complete since additional data may be desirable when particular ; conditions or circumstances exist. It is the responsibility of the user to determine the best precautions ; necessary for the safe handling and use of this product for your application. This data relates only to the ; specific material designated and not to be used in combination with any other material. Many federal and state ; regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material. ; It is the purchaser's responsiblity to familiarize themselves with all applicable regulations. |