| SAFETY DATA SHEET |
| |
| 1 : PRODUCT AND COMPANY IDENTIFICATION |
| |
| Product Code / Trade Name : | RW101381 / iso amyl acetate |
| Supplier Details : | The Good Scents Company
1977 E. Montana Ave., Oak Creek, WI 53154 |
| Information : | 414-764-2659 |
| Version Date : | 05/21/2018 |
| |
| 2 : HAZARDS IDENTIFICATION |
| |
| 2.1 Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
Flammable liquids (Category 3), H226
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Acute aquatic toxicity (Category 3), H402
|
| 2.2 GHS Label elements, including precautionary statements |
| |
| Pictogram |   |
| |
| Signal word | Warning |
| Hazard statement(s) |
H226 - Flammable liquid and vapour
H335 - May cause respiratory irritation
H402 - Harmful to aquatic life
|
| Precautionary statement(s) |
P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/ container to an approved waste disposal plant.
|
| |
| 3 : COMPOSITION / INFORMATION ON INGREDIENTS |
| |
| Chemical characterization : |
| Hazardous ingredient(s) : |
| 3-methyl butyl acetate 99.00 to 100.00 % |
| Hazard symbols : Xi R phrases : 10 66
|
| mol./wt. : 130.1869800
formula : C7 H14 O2
cas: 123-92-2
|
| einecs: 204-662-3 |
| |
| 4 : FIRST-AID MEASURES |
| |
| Remove contaminated soaked clothing and wash before reuse. |
| After eye contact : |
| In case of contact with eyes, rinse immediately with plenty of water for at least 10 minutes. Assure adequate flushing by separating the eyelids with fingers and seek medical advice. |
| After skin contact : |
| After contact with skin, wash immediately affected area with soap and plenty of water. |
| After inhalation : |
| If inhaled, remove person to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. |
| After ingestion : |
| If swallowed, rinse mouth with water (only if the person is conscious). Do not induce vomiting. Obtain immediate medical advice. |
| |
| 5 : FIRE-FIGHTING MEASURES |
| |
| Extinguishing media : |
| Carbon Dioxide; Dry Chemical; Universal-Type Foam. |
| Special firefighting procedures : |
| Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. |
| Unusual fire and explosion hazards : |
| Vapor may travel considerable distance to source of ignition and flash back. |
| |
| 6 : ACCIDENTAL RELEASE MEASURES |
| |
| Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves. Keep people away, evacuate area. |
| To avoid possible contamination of the environment, Do not discharge into any drains, surface waters or groundwaters. |
| Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. |
| Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. Dispose of in accordance with current laws and regulations. |
| |
| 7 : HANDLING AND STORAGE |
| |
| Measures should be taken to prevent materials from being splashed into the eyes or on the skin. Wear eyeshields and protective clothing. Smoking should not be permitted in work areas. |
| Provide suitable air extraction ventilation in the work areas. Vapors may form explosive mixtures with air. Keep material away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges. |
| To be stored in tightly sealed and preferably full containers in cool, dry and ventilated area. Protect from heat/overheating and light sources. |
| Keep only in original container. |
| |
| 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION |
| |
| Occupational exposure limits : |
|
OSHA TWA : Not determined |
|
ACGIH TWA : 50.00 PPM |
|
NIOSH TWA : Not determined |
|
OSHA PEL : 100.00 PPM |
|
ACGIH STEL : Not determined |
|
NIOSH STEL : Not determined |
| Respiratory protection : |
| Do not breath vapors. Mechanical exhaust required. In confined or poorly ventilated areas, the use of an appropriate respiratory protection may be required. |
| Hand protection : |
| Compatible chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. |
| Eye protection : |
| Chemical safety goggles are recommended. Wash contaminated goggles before reuse. |
| Body protection : |
| Light protective clothing recommended. Wash contaminated clothing before reuse. |
| Hygiene measures : |
| Avoid inhalation and contact with skin and eyes. Good personal hygiene practices should be used. Wash after any contact, before breaks and meals, and at the end of the work period. Safety shower and eye bath recommended. |
| |
| 9 : PHYSICAL AND CHEMICAL PROPERTIES |
| |
| Appearance / odor : |
|
colorless clear liquid / sweet fruity banana solvent |
| Melting point : | -78.00 °C. @ 760.00 mmHg
|
| Boiling point : | 142.00 °C. @ 756.00 mmHg
|
| Flash point ( ° F. ) : | 77.00 °F. TCC ( 25.00 °C. )
|
| Explosion limits in air : |
Upper :7.50 | Lower :1.00
| | Flammability : | Not determined
|
| Autoflammability : | 680.00
|
| Explosive properties : | Not determined
|
| Oxidizing properties : | Not determined
|
| Vapor pressure : | 5.60000 mm/Hg @ 25.00 °C.
|
| Vapor density : | 4.4 ( Air = 1 )
|
| Volatile by volume : | 100.00 %
|
| Evaporation rate : | Not determined
|
| Specific gravity : | 0.86800 to 0.87800 @ 25 °C.
|
| PH of Product : | Not determined
|
| Solubility in water : | Slightly Soluble |
| |
| 10 : STABILITY AND REACTIVITY |
| |
| Stability : |
Stable
|
| Conditions to avoid : |
Heat, excessive heat, open flames and other sources of ignition. |
| Incompatibility : |
Strong oxidizing agents, strong reducing agents. |
| Hazardous decomposition products : |
Carbon monoxide, carbon dioxide. Hazardous polymerization will not occur. |
| |
| 11 : TOXICOLOGICAL INFORMATION |
| |
| Acute effects : |
Flammable liquid and vapour
May cause respiratory irritation
Harmful to aquatic life
|
| Oral Toxicity(LD50) : |
oral-rat 16600 mg/kg Yakkyoku. Pharmacy. Vol. 32, Pg. 1241, 1981.
oral-rabbit 7422 mg/kg Industrial Medicine and Surgery. Vol. 41, Pg. 31, 1972.
|
| Dermal Toxicity(LD50) : |
skin-rabbit > 5000 mg/kg National Technical Information Service. Vol. OTS0573010
subcutaneous-guinea pig 5000 mg/kg Archiv fuer Gewerbepathologie und Gewerbehygiene. Vol. 5, Pg. 1, 1933.
|
| Skin Irritation : |
Not determined
|
| Eye Irritation : |
Not determined
|
| Inhalation data(LC50) : |
inhalation-cat 35000 mg/m3 Archiv fuer Gewerbepathologie und Gewerbehygiene. Vol. 5, Pg. 1, 1933.
|
| Mutagenicity data : |
Not determined
|
| Phototoxicity data : |
Not determined
|
| Human experience : |
8 % solution: no irritation or sensitization
|
| Carcinogenicity : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
|
| Reproductive toxin : |
Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No
|
| On the TSCA Inventory? : |
Yes |
| |
| 12 : ECOLOGICAL INFORMATION |
| Biodegradability |
| Readily biodegradable : |
Yes to OECD criteria
|
| Inherently biodegradable : |
Not determined
|
| Ecotoxicity |
| Fish : |
Not determined
|
| Algae : |
EC50 450.00 MG/L/72H Algae
|
| Daphnia : |
EC50 42.00 MG/L/48H Daphnia
|
| Bacteria : |
EC50 1020.00 MG/L/0,5H Bacteria
|
| Further information : |
Prevent contamination of soil, ground and surface waters. Do not discharge product unmonitored into the environment. |
| Mixture reportable to : |
CERCLA, CAA 111, FIFRA-Inerts |
| |
| 13 : DISPOSAL CONSIDERATIONS |
| |
Dispose of in accordance with all federal, state and local environmental regulations.
|
| |
| 14 : TRANSPORT INFORMATION |
| |
| US DOT Hazard Class : |
AMYL ACETATES
|
| UN Number : |
1104
|
| UN Pkg. Group : |
III
|
| UN item : |
31 C
|
| ERG Number : |
129
|
| Land transport (ADR/RID) |
| Class : |
3
|
| Transportfactor : |
1
|
| Marine transport (IMDG) |
| IMDG-class : |
3.3
|
| Page No. : |
3307
|
| MFAG : |
330
|
| EmS-No. : |
3-07
|
| Air transport (IATA) |
| IATA-class : |
3
|
| Passenger : |
309 60,0 L
|
| Cargo : |
310 220,0 L
|
| |
| 15 : REGULATORY INFORMATION |
| |
| Reviews, standards, and regulations : |
| OEL=MAK
ACGIH TLV-TWA 50 PPM; STEL 100 PPM DTLVS* TLV/BEI,1999
MSHA STANDARD-AIR:TWA 100 PPM (525 MG/M3)
DTLVS* 3,138,1971
OSHA PEL (GEN INDU):8H TWA 100 PPM (525 MG/M3)
CFRGBR 29,1910.1000,1994
OSHA PEL (CONSTRUC):8H TWA 100 PPM (525 MG/M3)
CFRGBR 29,1926.55,1994
OSHA PEL (SHIPYARD):8H TWA 100 PPM (525 MG/M3)
CFRGBR 29,1915.1000,1993
OSHA PEL (FED CONT):8H TWA 100 PPM (525 MG/M3)
CFRGBR 41,50-204.50,1994
OEL-AUSTRALIA: TWA 100 PPM (525 MG/M3), JAN1993
OEL-BELGIUM: TWA 100 PPM (532 MG/M3), JAN1993
OEL-DENMARK: TWA 100 PPM (525 MG/M3), JAN1999
OEL-FRANCE: VME 100 PPM (525 MG/M3), JAN1999
OEL-JAPAN: OEL 100 PPM (530 MG/M3), JAN1999
OEL-THE NETHERLANDS: MAC-K 100 PPM (530 MG/M3), JAN1999
OEL-NORWAY: TWA 50 PPM (260 MG/M3), JAN1999
OEL-THE PHILIPPINES: TWA 100 PPM (525 MG/M3), JAN1993
OEL-RUSSIA: TWA 100 PPM, JAN1993
OEL-SWITZERLAND: MAK-W 50 PPM (270 MG/M3), SKIN, JAN1999
OEL-UNITED KINGDOM: LTEL 100 PPM (525 MG/M3), STEL 125 PPM, JAN1993
OEL IN ARGENTINA, BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV;
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV
NIOSH REL TO ISOAMYL ACETATE-AIR:10H TWA 100 PPM
NIOSH* DHHS #92-100,1992
NOHS 1974: HZD 40370; NIS 93; TNF 11016; NOS 75; TNE 96405
NOES 1983: HZD 40370; NIS 62; TNF 7677; NOS 79; TNE 97668; TFE 32512
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JANUARY 2001
NIOSH ANALYTICAL METHOD, 1994: ESTERS I, 1450 |
| |
| 16 : OTHER INFORMATION |
| |
| Fema No. : | 2055 |
| Hazardous materials identification system : |
| Fire : 3 |
Health : 2 |
Reactivity : 0 |
Personal protection : B
|
| |
| Disclaimer |
| The information contained on the Material Data Sheet has been compiled from data considered accurate. ; This data is believed to be reliable, however, it must be pointed out that values for certain properties are known ; to vary from source to source. The Good Scents Company USA Expressly disclaims any warranty expressed or implied ; as well as any liability for any injury or loss arising from the use of this information or the materials described. ; This data is not to be construed as absolutely complete since additional data may be desirable when particular ; conditions or circumstances exist. It is the responsibility of the user to determine the best precautions ; necessary for the safe handling and use of this product for your application. This data relates only to the ; specific material designated and not to be used in combination with any other material. Many federal and state ; regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material. ; It is the purchaser's responsiblity to familiarize themselves with all applicable regulations. |