| MATERIAL SAFETY DATA SHEET | |||
| Disclaimer | |||
| The information contained on the Material Data Sheet has been compiled from data considered accurate. ; This data is believed to be reliable, however, it must be pointed out that values for certain properties are known ; to vary from source to source. The Good Scents Company USA Expressly disclaims any warranty expressed or implied ; as well as any liability for any injury or loss arising from the use of this information or the materials described. ; This data is not to be construed as absolutely complete since additional data may be desirable when particular ; conditions or circumstances exist. It is the responsibility of the user to determine the best precautions ; necessary for the safe handling and use of this product for your application. This data relates only to the ; specific material designated and not to be used in combination with any other material. Many federal and state ; regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material. ; It is the purchaser's responsiblity to familiarize themselves with all applicable regulations. | |||
| For Manufacturing, Processing, or Repacking Only. | |||
| 1 : Identification of the substance / preparation and company | |||
| Product Code / Trade Name : | RW101367 / acetophenone | ||
| Supplier Details : | The Good Scents Company | ||
| Information : | 414-764-2659 | ||
| Version Date : | 06/06/2013 | ||
| 2 : Composition / information on ingredients | |||
| Chemical characterization : | |||
| Hazardous ingredient(s) : | |||
| acetophenone 98.00 to 100.00 % | |||
| Hazard symbols : Xn R phrases : 22 36 | |||
| mol./wt. : 120.1509600 formula : C8 H8 O cas : 98-86-2 | |||
| einecs number : 202-708-7 | |||
| epa-Iris Niosh ICSC NLM HSDB | |||
| 3 : Hazard identification | |||
| Most important hazards : | |||
| Harmful. Harmful if swallowed. Irritating to eyes. Keep out of the reach of children. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable clothing, gloves and eye/face protection. | |||
| 4 : First-aid measures | |||
| Remove contaminated soaked clothing and wash before reuse. | |||
| After eye contact : | |||
| In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes. | |||
| After skin contact : | |||
| After contact with skin, wash immediately affected area with soap and plenty of water. | |||
| After inhalation : | |||
| If inhaled, remove person to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. | |||
| After ingestion : | |||
| If swallowed, rinse mouth with water (only if the person is conscious). Obtain medical advice. | |||
| 5 : Fire-fighting measures | |||
| Extinguishing media : | |||
| Water spray, carbon dioxide, dry chemical powder or appropriate foam. For safety reasons do not use full water jet. | |||
| Special firefighting procedures : | |||
| Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. | |||
| Unusual fire and explosion hazards : | |||
| Emits toxic fumes under fire conditions. | |||
| 6 : Accidental release measures | |||
| Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves. Keep people away, evacuate area. | |||
| To avoid possible contamination of the environment, Do not discharge into any drains, surface waters or groundwaters. | |||
| Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash). Place in covered containers using non-sparking tools and transport outdoors. | |||
| Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site after material pickup is complete. Dispose of in accordance with current laws and regulations. | |||
| 7 : Handling and storage | |||
| Measures should be taken to prevent materials from being splashed into the eyes or on the skin. Wear eyeshields and protective clothing. Smoking should not be permitted in work areas. | |||
| Provide suitable air extraction ventilation in the work areas. Vapors may form explosive mixtures with air. Keep material away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges. | |||
| To be stored in tightly sealed and preferably full containers in cool, dry and ventilated area. Protect from heat/overheating and light sources. | |||
| Keep in glass, suitable plastic, aluminum or laquer-lined containers. | |||
| 8 : Exposure controls / personal protection | |||
| Occupational exposure limits : | |||
| Respiratory protection : | |||
| Do not breath vapors. Mechanical exhaust required. In confined or poorly ventilated areas, the use of an appropriate respiratory protection may be required. | |||
| Hand protection : | |||
| Compatible chemical-resistant gloves are recommended. Wash contaminated gloves before reuse. | |||
| Eye protection : | |||
| Chemical safety goggles are recommended. Wash contaminated goggles before reuse. | |||
| Body protection : | |||
| Light protective clothing recommended. Wash contaminated clothing before reuse. | |||
| Hygiene measures : | |||
| Avoid inhalation and contact with skin and eyes. Good personal hygiene practices should be used. Wash after any contact, before breaks and meals, and at the end of the work period. Safety shower and eye bath recommended. | |||
| 9 : Physical and chemical properties | |||
| Appearance / odor : | |||
| colorless to pale yellow clear liquid but solid at low temps / sweet pungent hawthorn mimosa almond acacia chemical | |||
| Melting point : | 19.00 to 20.00 °C. @ 760.00 mmHg | ||
| Boiling point : | 202.00 to 203.00°C. @ 760.00 mmHg | ||
| Flash point ( ° F. ) : | 179.00 °F. TCC ( 81.67 °C. ) | ||
| Explosion limits in air : | Upper :5.20 | Lower :1.40 | |
| Flammability : | Not determined | ||
| Autoflammability : | 1058.00 | ||
| Explosive properties : | Not determined | ||
| Oxidizing properties : | Not determined | ||
| Vapor pressure : | 0.39700 mm/Hg @ 25.00 °C. | ||
| Vapor density : | 4.1 ( Air = 1 ) | ||
| Volatile by volume : | 100.00 % | ||
| Evaporation rate : | Not determined | ||
| Specific gravity : | 1.02500 to 1.03200 @ 25 °C. | ||
| PH of Product : | Not determined | ||
| Solubility in water : | Insoluble | ||
| 10 : Stability and reactivity | |||
| Stability : | Stable | ||
| Conditions to avoid : | Heat, excessive heat, open flames and other sources of ignition. | ||
| Incompatibility : | Moisture, light, heat, strong oxidizing agents, strong reducing agents, strong bases. | ||
| Hazardous decomposition products : | Carbon monoxide, carbon dioxide. Hazardous polymerization will not occur. | ||
| 11 : Toxicological information | |||
| Acute effects : |
Harmful. Harmful if swallowed. Irritating to eyes. | ||
| Oral Toxicity(LD50) : |
gavage-rat [sex: M] 3000 mg/kg (Smyth & Carpenter, 1944) gavage-rat [sex: M,F] 3200 ml/kg (Jenner et al., 1964) oral-rat [sex: F] 2.48 ml/kg (Smyth et al., 1969b) oral-rat 900 mg/kg (Smyth & Carpenter, 1948) oral-mouse 1780 mg/kg (Damment, 1992) oral-mammal (species unspecified) 2700 mg/kg Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 32(10), Pg. 25, 1988. intraperitoneal-mouse 200 mg/kg National Technical Information Service. Vol. AD277-689 oral-mouse 740 mg/kg Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 26(8), Pg. 53, 1982. oral-rat 815 mg/kg Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 26(8), Pg. 53, 1982. | ||
| Dermal Toxicity(LD50) : |
skin-rabbit 15900 ul/kg Union Carbide Data Sheet. Vol. 12/27/1971 skin-guinea pig > 20 ml/kg Journal of Industrial Hygiene and Toxicology. Vol. 26, Pg. 269, 1944. subcutaneous-mouse 330 mg/kg "Pharmakologische Prufung von Analgetika, Dissertation," Herrlen, G., Pharmakologischen Institut der Universitat Tubingen, Fed. Rep. Ger., 1933Vol. -, Pg. -, 1933. | ||
| Skin Irritation : |
skin-rabbit 10 mg/24hours JPETAB 26,269,1944 | ||
| Eye Irritation : | Not determined | ||
| Inhalation data(LC50) : |
inhalation-rat > 210 ppm/8H Union Carbide Data Sheet. Vol. 12/27/1971 inhalation-mammal (species unspecified) 1200 mg/m3 Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 32(10), Pg. 25, 1988. | ||
| Mutagenicity data : | Not determined | ||
| Phototoxicity data : | Not determined | ||
| Human experience : | 2 % solution: no irritation or sensitization. | ||
| Carcinogenicity : | Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No | ||
| Reproductive toxin : | Per OSHA, IARC, NTP, ACGIH, OEHHA-Prop 65, RTECS : No | ||
| On the TSCA Inventory? : | Yes | ||
| 12 : Ecological information | |||
| Biodegradability | |||
| Readily biodegradable : | Not determined | ||
| Inherently biodegradable : | Not determined | ||
| Ecotoxicity | |||
| Fish : |
LC50 140.00 MG/L Idus melanotus | ||
| Algae : | Not determined | ||
| Daphnia : |
EC50 50.00 MG/L Daphnia | ||
| Bacteria : | Not determined | ||
| Further information : | Prevent contamination of soil, ground and surface waters. Do not discharge product unmonitored into the environment. | ||
| Mixture reportable to : | SARA 313, CERCLA, RCRA, CAA 112(b), CAA 111, FIFRA-Inerts | ||
| 13 : Disposal considerations | |||
Dispose of in accordance with all federal, state and local environmental regulations. | |||
| 14 : Transport information | |||
| US DOT Hazard Class : | LIQUID, N.O.S. (ACETOPHENONE) | ||
| UN Number : | 3334 | ||
| UN Pkg. Group : | Not determined | ||
| UN item : | Not determined | ||
| ERG Number : | Not determined | ||
| Land transport (ADR/RID) | |||
| Class : | Not determined | ||
| Transportfactor : | Not determined | ||
| Marine transport (IMDG) | |||
| IMDG-class : | Not determined | ||
| Page No. : | Not determined | ||
| MFAG : | Not determined | ||
| EmS-No. : | Not determined | ||
| Air transport (IATA) | |||
| IATA-class : | 9 | ||
| Passenger : | 906 100,0 L | ||
| Cargo : | 906 220,0 L | ||
| 15 : Regulatory inforamtion | |||
| European information : | |||
| Xn - Harmful. R 22 - Harmful if swallowed. R 36 - Irritating to eyes. S 02 - Keep out of the reach of children. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection. | |||
| Reviews, standards, and regulations : | |||
| ACGIH TLV-TWA 10 PPM DTLVS* TLV/BEI,1999 OEL-HUNGARY: TWA 15 MG/M3, STEL 30 MG/M3, SKIN, JAN1993 OEL-RUSSIA: STEL 5 MG/M3, SKIN, JAN1993 NOES 1983: HZD 80265; NIS 48; TNF 4433; NOS 61; TNE 78624; TFE 31148 EPA GENETOX PROGRAM 1988, NEGATIVE: E COLI POLA WITHOUT S9; E COLI POLA WITH S9 EPA TSCA SECTION 8(B) CHEMICAL INVENTORY EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES ON EPA IRIS DATABASE EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JANUARY 2001 U.S. INFORMATION THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS. German Regulations on Flammable Liquids - VbF: class AIII. Water pollution class (WGK = Classification in accordance with the German Water Resources Act): WGK 1 - slightly hazardous to water. Index number: 735 . Classification according to the German Technical Guidline-Air: Number 3.1.7,Class II | |||
| 16 : Other information | |||
| Fema No. : | 2009 | ||
| Hazardous materials identification system : | |||
| Fire : 2 | Health : 3 | Reactivity : 0 | Personal protection : C |