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carbosulfan
dibutylaminosulfenylcarbofuran

Supplier Sponsors

CAS Number: 55285-14-8Picture of molecule3D/inchi
Other(deleted CASRN):73468-61-8
ECHA EINECS - REACH Pre-Reg:259-565-9
FDA UNII: V1DGN4AK6G
Nikkaji Web:J1.070G
Beilstein Number:1397995
MDL:MFCD00128058
XlogP3:5.70 (est)
Molecular Weight:380.55164000
Formula:C20 H32 N2 O3 S
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
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Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Appearance:brown viscous liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Boiling Point: 462.50 °C. @ 760.00 mm Hg (est)
Flash Point: 452.00 °F. TCC ( 233.50 °C. ) (est)
logP (o/w): 6.050 (est)
Soluble in:
 water, 0.3 mg/L @ 25 °C (exp)
 water, 0.07041 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
Carbosulfan ≥95%
Odor: characteristic
Use: Carbosulfan is an organic compound adherent as a insecticide. Insecticide
Sigma-Aldrich
For experimental / research use only.
Carbosulfan PESTANAL®, analytical standard
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-bird - wild LD50 26 mg/kg
Pesticide Manual. Vol. 9, Pg. 129, 1991.

oral-duck LD50 8100 ug/kg
Pesticide Manual. Vol. 9, Pg. 129, 1991.

oral-mouse LD50 74 mg/kg
Journal of Agricultural and Food Chemistry. Vol. 30, Pg. 555, 1982.

oral-quail LD50 82 mg/kg
Pesticide Manual. Vol. 9, Pg. 129, 1991.

oral-rat LD50 51 mg/kg
Journal of Agricultural and Food Chemistry. Vol. 30, Pg. 555, 1982.

Dermal Toxicity:
skin-rabbit LD50 > 2000 mg/kg
Pesticide Manual. Vol. 9, Pg. 129, 1991.

skin-rat LD50 > 2000 mg/kg
Farm Chemicals Handbook. Vol. -, Pg. C9, 1991.

Inhalation Toxicity:
inhalation-rat LC50 1530 mg/m3/1H
Pesticide Manual. Vol. 9, Pg. 129, 1991.
 
Safety in Use Information:
Category:
herbicides / pesticides
Recommendation for carbosulfan usage levels up to:
 not for fragrance use.
 
Recommendation for carbosulfan flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Reasoned opinion on the review of the existing MRLs for carbofuran, carbosulfan, benfuracarb and furathiocarb and the setting of an import tolerance for carbofuran in cultivated mushrooms
View page or View pdf

EPI System: View
EPA-Iris:IRIS
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :41384
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
(2,2-dimethyl-3H-1-benzofuran-7-yl) N-(dibutylamino)sulfanyl-N-methylcarbamate
Chemidplus:0055285148
EPA/NOAA CAMEO:hazardous materials
RTECS:EZ3815000 for cas# 55285-14-8
 
References:
 (2,2-dimethyl-3H-1-benzofuran-7-yl) N-(dibutylamino)sulfanyl-N-methylcarbamate
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):41384
Pubchem (sid):135003062
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C18416
HMDB (The Human Metabolome Database):Search
ChemSpider:View
Wikipedia:View
EFSA Update of results on the monitoring of furan levels in food:Read Report
EFSA Previous report: Results on the monitoring of furan levels in food:Read Report
EFSA Report of the CONTAM Panel on provisional findings on furan in food:Read Report
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 carbamic acid, ((dibutylamino)thio)methyl-, 2,2-dimethyl-2,3-dihydro-7-benzofuranyl ester
 carbamic acid, ((dibutylamino)thio)methyl-, 2,3-dihydro-2,2-dimethyl-7-benzofuranyl ester
 carbamic acid, [(dibutylamino)thio]methyl-, 2,3-dihydro-2,2-dimethyl-7-benzofuranyl ester
 carbamic acid, N-[(dibutylamino)thio]-N-methyl-, 2,3-dihydro-2,2-dimethyl-7-benzofuranyl ester
((dibutylamino)thio)methylcarbamic acid 2,2-dimethyl-2,3-dihydro-7-benzofuranyl ester
((dibutylamino)thio)methylcarbamic acid 2,3-dihydro-2,2-dimethyl-7-benzofuranyl ester
((dibutylamino)thio)methylcarbamic acid, 2,2-dimethyl-2,3-dihydro-7-benzofuranyl ester
N-[(dibutylamino)thio]-N-methylcarbamic acid 2,3-dihydro-2,2-dimethyl; -7-benzofuranyl ester
 dibutylaminosulfenylcarbofuran
2,3-dihydro-2,2-dimethyl-7-benzofuranyl ((dibutylamino)thio)methylcarbamate
2,3-dihydro-2,2-dimethyl-7-benzofuranyl (di-n-butylaminosulfenyl)methylcarbamate
2,3-dihydro-2,2-dimethyl-7-benzofuranyl[(dibutylamino)thio]methyl carbamate
2,3-dihydro-2,2-dimethyl-7-benzofuryl [(dibutylamino)thio]methylcarbamate
2,2-dimethyl-2,3-dihydro-1-benzofuran-7-yl (dibutylamino)sulfanyl(methyl)carbamate
2,2-dimethyl-2,3-dihydro-1-benzofuran-7-yl [(dibutylamino)sulfanyl](methyl)carbamate
2,2-dimethyl-2,3-dihydro-1-benzofuran-7-yl [(dibutylamino)sulfanyl]methylcarbamate
(2,2-dimethyl-3H-1-benzofuran-7-yl) N-(dibutylamino)sulfanyl-N-methylcarbamate
 marshal 10G (salt/mix)
 marshal/suscon (salt/mix)
 marshall 10G (salt/mix)
 

Articles:

PubMed:The combined toxicity assessment of carp (Cyprinus carpio) acetylcholinesterase activity by binary mixtures of chlorpyrifos and four other insecticides.
PubMed:Induction of micronuclei and nuclear lesions in Channa punctatus following exposure to carbosulfan, glyphosate and atrazine.
PubMed:Biochemical and molecular characterization and cross-resistance in field and laboratory chlorpyrifos resistant strains of Laodelphax striatellus (Hemiptera: Delphacidae) from eastern China.
PubMed:[Rapid screening of 176 pesticide residues in vegetables by ultra fast liquid chromatography-tandem mass spectrometry].
PubMed:Effects of chronic carbosulfan exposure on liver antioxidant enzyme activities in rainbow trout.
PubMed:Assessment of potential sublethal effects of various insecticides on key biological traits of the tobacco whitefly, Bemisia tabaci.
PubMed:Persistence behavior of imidacloprid and carbosulfan in mango (Mangifera indica L.).
PubMed:High-level of resistance to spinosad, emamectin benzoate and carbosulfan in populations of Thrips tabaci collected in Israel.
PubMed:Analysis of carbofuran, carbosulfan, isoprocarb, 3-hydroxycarbofuran, and 3-ketocarbofuran by micellar electrokinetic chromatography.
PubMed:[Toxicity and bioactivity of several alternative nematocides against Ditylenchus destructor].
PubMed:Acute toxicity of Roundup and carbosulfan to the Thai fairy shrimp, Branchinella thailandensis.
PubMed:Simultaneous quantification of carbamate insecticides in human plasma by liquid chromatography/tandem mass spectrometry.
PubMed:Development of a new QuEChERS method based on dry ice for the determination of 168 pesticides in paprika using tandem mass spectrometry.
PubMed:Influence of bioassay volume, water column height, and octanol-water partition coefficient on the toxicity of pesticides to rainbow trout.
PubMed:Fate of carbosulfan and monocrotophos in sandy loam soils of Pakistan under field conditions at different watertable depths.
PubMed:[Preliminary evaluation of the insecticide susceptibility in Anopheles gambiae and Culex quinquefasciatus from Lobito (Angola), using WHO standard assay].
PubMed:Insecticide resistance in the Anopheles gambiae complex in Benin: a nationwide survey.
PubMed:Effects of some pesticides on the vital organs of juvenile rainbow trout (Oncorhynchus mykiss).
PubMed:Distribution of ace-1R and resistance to carbamates and organophosphates in Anopheles gambiae s.s. populations from Côte d'Ivoire.
PubMed:Metabolism of carbosulfan II. Human interindividual variability in its in vitro hepatic biotransformation and the identification of the cytochrome P450 isoforms involved.
PubMed:Persistence and nematicidal efficacy of carbosulfan, cadusafos, phorate, and triazophos in soil and uptake by chickpea and tomato crops under tropical conditions.
PubMed:Behavioural and insecticidal effects of organophosphate-, carbamate- and pyrethroid-treated mosquito nets against African malaria vectors.
PubMed:Cross-resistance study and biochemical mechanisms of thiamethoxam resistance in B-biotype Bemisia tabaci (Hemiptera: Aleyrodidae).
PubMed:Use of semipermeable membrane devices for monitoring pesticides in indoor air.
PubMed:Insecticide resistance traits differ among and within host races in Aphis gossypii.
PubMed:Determination of pesticide residues in integrated pest management and nonintegrated pest management samples of apple (Malus pumila Mill.).
PubMed:Mutagenic and genotoxic effects of carbosulfan in freshwater fish Channa punctatus (Bloch) using micronucleus assay and alkaline single-cell gel electrophoresis.
PubMed:Virulence development and genetic polymorphism in Meloidogyne incognita (Kofoid & White) Chitwood after prolonged exposure to sublethal concentrations of nematicides and continuous growing of resistant tomato cultivars.
PubMed:Metabolism of carbosulfan. I. Species differences in the in vitro biotransformation by mammalian hepatic microsomes including human.
PubMed:Impact of some selected insecticides application on soil microbial respiration.
PubMed:Purification and partial characterization of glutathione S-transferase from insecticide-resistant field populations of Liposcelis paeta Pearman (Psocoptera: Liposcelididae).
PubMed:Multivariate analysis of toxicological and environmental properties of soil nematicides.
PubMed:Effects of carbosulfan administration schedules on estrous cycle and follicular dynamics in albino mice.
PubMed:Comparison of hollow fiber liquid phase microextraction and dispersive liquid-liquid microextraction for the determination of organosulfur pesticides in environmental and beverage samples by gas chromatography with flame photometric detection.
PubMed:Abamectin, pymetrozine and azadirachtin sequence as a unique solution to control the leafminer Liriomyza trifolii (Burgess) (Diptera: Agromyzidae) infesting garden beans (Phaseolus vulgaris L.) in Egypt.
PubMed:An approach for IPM program to control sucking pests infesting garden bean plants (Phaseolus vulgaris L.) in Egypt.
PubMed:Influence of organic matter on bio-availability of carbosulfan and its toxicity on a carabid beetle.
PubMed:Relationship between desert locust, Schistocerca gregaria (Forskål), infestation, environmental factors and control measures in Gazan and Makkah Regions, Saudi Arabia.
PubMed:Characterization of insensitive acetylcholinesterase (ace-1R) in Anopheles gambiae (Diptera: Culicidae): resistance levels and dominance.
PubMed:[Behavior of N-methylcarbamate pesticides during refinement processing of edible oils].
PubMed:Effects of biological and technical factors on brain and muscle cholinesterases in Nile tilapia, Oreochromis niloticus: implications for biomonitoring neurotoxic contaminations.
PubMed:Optimization of LC-MS/MS using triple quadrupole mass analyzer for the simultaneous analysis of carbosulfan and its main metabolites in oranges.
PubMed:Effect of application of different pesticides to soybean on the soil microflora.
PubMed:[Fitness cost associated with carbosulfan resistance in Aphis gossypii Glover (Hemiptera: Aphididae)].
PubMed:Liquid chromatography quadrupole time-of-flight mass spectrometry analysis of carbosulfan, carbofuran, 3-hydroxycarbofuran, and other metabolites in food.
PubMed:Synergism studies with binary mixtures of pyrethroid, carbamate and organophosphate insecticides on Frankliniella occidentalis (Pergande).
PubMed:Facile and sensitive spectrophotometric determination of carbosulfan in formulations and environmental samples.
PubMed:Comparison of four mass analyzers for determining carbosulfan and its metabolites in citrus by liquid chromatography/mass spectrometry.
PubMed:Body size-related differences in the inhibition of brain acetylcholinesterase activity in juvenile Nile tilapia (Oreochromis niloticus) by chlorpyrifos and carbosulfan.
PubMed:Differential responses of eight cyanobacterial and green algal species, to carbamate insecticides.
PubMed:Transformation and ecotoxicity of carbamic pesticides in water.
PubMed:Determination of carbosulfan and its metabolites in oranges by liquid chromatography ion-trap triple-stage mass spectrometry.
PubMed:Inhibitory effects of four carbamate insecticides on acetylcholinesterase of male and female Carassius auratus in vitro.
PubMed:Response of brain and liver cholinesterases of Nile tilapia, Oreochromis niloticus, to single and multiple exposures of chlorpyrifos and carbosulfan.
PubMed:Selectivity of pesticides used on cotton (Gossypium hirsutum) to Trichogramma pretiosum reared on two laboratory-reared hosts.
PubMed:Degradation and persistence of cotton pesticides in sandy loam soils from Punjab, Pakistan.
PubMed:Kinetics of carbosulfan hydrolysis to carbofuran and the subsequent degradation of this last compound in irrigated rice fields.
PubMed:Pesticide pollution remains severe after cleanup of a stockpile of obsolete pesticides at Vikuge, Tanzania.
PubMed:Forearm compartment syndrome after intravenous mannitol extravasation in a carbosulfan poisoning patient.
PubMed:Liquid chromatography-electrospray quadrupole ion-trap mass spectrometry of nine pesticides in fruits.
PubMed:Pressurized hot water extraction of insecticides from process dust--comparison with supercritical fluid extraction.
PubMed:Dinotefuran: a potential neonicotinoid insecticide against resistant mosquitoes.
PubMed:Experimental hut comparisons of nets treated with carbamate or pyrethroid insecticides, washed or unwashed, against pyrethroid-resistant mosquitoes.
PubMed:Efficacy of mosquito nets treated with insecticide mixtures or mosaics against insecticide resistant Anopheles gambiae and Culex quinquefasciatus (Diptera: Culicidae) in Côte d'Ivoire.
PubMed:Development of a simultaneous analysis method for carbofuran and its three derivative pesticides in water by GC/MS with temperature programmable inlet on-column injection.
PubMed:Comparative evaluation of carbosulfan- and permethrin-impregnated curtains for preventing house-entry by the malaria vector Anopheles gambiae in Burkina Faso.
PubMed:Insecticide resistance in Egyptian populations of the cotton whitefly, Bemisia tabaci (Hemiptera: Aleyrodidae).
PubMed:In vitro dermal penetration study of carbofuran, carbosulfan, and furathiocarb.
PubMed:Resistance to carbosulfan in Anopheles gambiae from Ivory Coast, based on reduced sensitivity of acetylcholinesterase.
PubMed:Multiple dose-activated charcoal as a cause of acute appendicitis.
PubMed:Induction of sister chromatid exchanges by cypermethrin and carbosulfan in bone marrow cells of mice in vivo.
PubMed:Insecticide mixtures for mosquito net impregnation against malaria vectors.
PubMed:Mutagenic effects of carbosulfan, a carbamate pesticide.
PubMed:Influence of clay minerals on the hydrolysis of carbamate pesticides.
PubMed:Combined pyrethroid and carbamate 'two-in-one' treated mosquito nets: field efficacy against pyrethroid-resistant Anopheles gambiae and Culex quinquefasciatus.
PubMed:Risk assessment of etofenprox (Vectron) on non-target aquatic fauna compared with other pesticides used as Simulium larvicide in a tropical environment.
PubMed:Supercritical fluid extraction of the pesticides carbosulfan and imidacloprid from process dust waste.
PubMed:Experimental and molecular genetic analysis of the impact of pyrethroid and non-pyrethroid insecticide impregnated bednets for mosquito control in an area of pyrethroid resistance.
PubMed:The kdr pyrethroid resistance gene in Anopheles gambiae: tests of non-pyrethroid insecticides and a new detection method for the gene.
PubMed:Microbial degradation of carbosulfan by carbosulfan--and carbofuran-retreated rice soil suspension.
PubMed:Distribution of organophosphate and carbamate resistance in Culex pipiens quinquefasciatus (Diptera: Culicidae) in West Africa.
PubMed:In vivo chromosomal aberrations in bone marrow cells of rats treated with Marshal.
PubMed:Genotoxic evaluation of three heterocyclic N-methylcarbamate pesticides using the mouse bone marrow micronucleus assay and the Saccharomyces cerevisiae strains D7 and D61.M.
PubMed:Determination of carbosulfan in oranges by high-performance liquid chromatography with post-column fluorescence.
PubMed:Effects of benzofuran and seven benzofuran derivatives including four carbamate insecticides in the in vitro porcine brain tubulin assembly assay and description of a new approach for the evaluation of the test data.
PubMed:Short-term effects of carbosulfan on drifting invertebrates in the Black Volta, Ghana.
PubMed:Chromosomal aberrations in cultured human lymphocytes treated with Marshal and its effective ingredient Carbosulfan.
PubMed:Effect of moisture regime, temperature, and organic matter on soil persistence of carbosulfan.
PubMed:Laboratory toxicity of potential blackfly larvicides on some African fish species in the Onchocerciasis Control Programme area.
PubMed:A simple spectrophotometric method for determination of carbosulfan and propoxur.
PubMed:Persistence of carbamate insecticides, carbosulfan and carbofuran in soils as influenced by temperature and microbial activity.
PubMed:Insecticidal activity of carbosulfan (OMS 3022) and pyraclofos (OMS 3040) against mosquitoes.
PubMed:Maintenance of effective control of Simulium damnosum in the face of insecticide resistance.
PubMed:Management of insecticide resistance in control of the Simulium damnosum complex by the Onchocerciasis Control Programme, West Africa: potential use of negative correlation between organophosphate resistance and pyrethroid susceptibility.
PubMed:Sublethal acute toxicity of carbosulfan [2,3-dihydro-2,2-dimethyl-7-benzofuranyl(d i-n-butylaminosulfenyl)(methyl)carbamate] in the rat after intravenous and oral exposures.
PubMed:Leaf, fruit, and soil surface residues of carbosulfan and its metabolites in Florida citrus groves.
PubMed:Metabolism of carbosulfan in Valencia orange tree leaves and fruit.
PubMed:Worker reentry research for carbosulfan applied to California citrus trees.
PubMed:Determination of carbosulfan and carbofuran residues in plants, soil, and water by gas chromatography.
PubMed:Alteration of carbosulfan [2,3-dihydro-2,2-dimethyl-7-benzofuranyl (Di-n-butylaminosulfenyl)methylcarbamate] in the rat stomach.
 
Notes:
None found
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