EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

tau-fluvalinate
D-valine, N-[2-chloro-4-(trifluoromethyl)phenyl]-, cyano(3-phenoxyphenyl)methyl ester

Supplier Sponsors

CAS Number: 102851-06-9Picture of molecule3D/inchi
FDA UNII: R533F643E8
Nikkaji Web:J59.569A
Beilstein Number:8092907
MDL:MFCD00871307
XlogP3-AA:7.70 (est)
Molecular Weight:502.92014960
Formula:C26 H22 Cl F3 N2 O3
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Boiling Point: 566.20 °C. @ 760.00 mm Hg (est)
Flash Point: 565.00 °F. TCC ( 296.20 °C. ) (est)
logP (o/w): 7.310 (est)
Soluble in:
 water, 0.0005691 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
(a-RS,2R)-Fluvalinate 95%
Santa Cruz Biotechnology
For experimental / research use only.
Mavrik
Sigma-Aldrich
For experimental / research use only.
t-Fluvalinate PESTANAL®, analytical standard
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
herbicides / pesticides
Recommendation for tau-fluvalinate usage levels up to:
 not for fragrance use.
 
Recommendation for tau-fluvalinate flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Reasoned opinion on the modification of the existing MRLs for tau-fluvalinate in various crops
View page or View pdf

Modification of the existing maximum residue levels for tau-fluvalinate in citrus fruits
View page or View pdf

Review of the existing maximum residue levels for tau-fluvalinate according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf

Modification of the existing maximum residue levels for tau-fluvalinate in tomatoes and watermelons
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :91768
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
[cyano-(3-phenoxyphenyl)methyl] (2R)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate
Chemidplus:0102851069
 
References:
 [cyano-(3-phenoxyphenyl)methyl] (2R)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):91768
Pubchem (sid):135049582
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C18790
HMDB (The Human Metabolome Database):Search
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
(2R)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoic acid [cyano-(3-phenoxyphenyl)methyl] ester
N-[2-chloro-4-(trifluorométhyl)phényl]-D-valinate de cyano(3-phénoxyphényl)méthyle
N-[2-chloro-4-(trifluoromethyl)phenyl]-D-valine cyano(3-phenoxyphenyl)methyl ester
[cyano-(3-phenoxyphenyl)methyl] (2R)-2-[[2-chloranyl-4-(trifluoromethyl)phenyl]amino]-3-methyl-butanoate
[cyano-(3-phenoxyphenyl)methyl] (2R)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate
(RS)-a-cyano-3-phenoxybenzyl N-(2-chloro-a,a,a-trifluoro-p-tolyl)-D-valinate
 cyano(3-phenoxyphenyl)methyl (2R)-2-{[2-chloro-4-(trifluoromethyl)phenyl]amino}-3-methylbutanoate
 cyano(3-phenoxyphenyl)methyl N-[2-chloro-4-(trifluoromethyl)phenyl]-D-valinate
 fluvarol
 fluwarol
D-valine, N-[2-chloro-4-(trifluoromethyl)phenyl]-, cyano(3-phenoxyphenyl)methyl ester
 

Articles:

PubMed:Xenobiotic effects on intestinal stem cell proliferation in adult honey bee (Apis mellifera L) workers.
PubMed:Target-site resistance to pyrethroid insecticides in German populations of the cabbage stem flea beetle, Psylliodes chrysocephala L. (Coleoptera: Chrysomelidae).
PubMed:An amino acid substitution (L925V) associated with resistance to pyrethroids in Varroa destructor.
PubMed:Molecular and functional characterization of CYP6BQ23, a cytochrome P450 conferring resistance to pyrethroids in European populations of pollen beetle, Meligethes aeneus.
PubMed:Point mutations in the sodium channel gene conferring tau-fluvalinate resistance in Varroa destructor.
PubMed:Field-level sublethal effects of approved bee hive chemicals on Honey Bees (Apis mellifera L).
PubMed:The impact of insecticides applied in apple orchards on the predatory mite Kampimodromus aberrans (Acari: Phytoseiidae).
PubMed:Currently used pesticides and their mixtures affect the function of sex hormone receptors and aromatase enzyme activity.
PubMed:The development of an economic threshold for Nasonovia ribisnigri (Hemiptera: Aphididae) on lettuce in central Spain.
PubMed:Fate of dermally applied miticides fluvalinate and amitraz within honey bee (Hymenoptera: Apidae) bodies.
PubMed:Effects of fluvalinate on honey bee learning, memory, responsiveness to sucrose, and survival.
PubMed:Acaricide, fungicide and drug interactions in honey bees (Apis mellifera).
PubMed:Proteolysis on the body surface of pyrethroid-sensitive and resistant Varroa destructor.
PubMed:Comparative toxicity of acaricides to honey bee (Hymenoptera: Apidae) workers and queens.
PubMed:Incidence of pyrethroid-resistant oilseed rape pests in Germany.
PubMed:Immune-related gene expression in nurse honey bees (Apis mellifera) exposed to synthetic acaricides.
PubMed:Simultaneous determination of pesticides and 5-hydroxymethylfurfural in honey by the modified QuEChERS method and liquid chromatography coupled to tandem mass spectrometry.
PubMed:Effects of a naturally occurring and a synthetic synergist on toxicity of three insecticides and a phytochemical to navel orangeworm (Lepidoptera: Pyralidae).
PubMed:Estimation of measurement uncertainty associated to the determination of pesticide residues: a case study.
PubMed:Identification of mutations associated with pyrethroid resistance in the voltage-gated sodium channel of the tomato leaf miner (Tuta absoluta).
PubMed:Using video-tracking to assess sublethal effects of pesticides on honey bees (Apis mellifera L.).
PubMed:Ecologically appropriate xenobiotics induce cytochrome P450s in Apis mellifera.
PubMed:The effect of a piperonyl butoxide/tau-fluvalinate mixture on pollen beetle (Meligethes aeneus) and honey bees (Apis mellifera).
PubMed:Direct effect of acaricides on pathogen loads and gene expression levels in honey bees Apis mellifera.
PubMed:Killing them with kindness? In-hive medications may inhibit xenobiotic efflux transporters and endanger honey bees.
PubMed:Acaricide treatment affects viral dynamics in Varroa destructor-infested honey bee colonies via both host physiology and mite control.
PubMed:Simultaneous analysis of pesticides from different chemical classes by using a derivatisation step and gas chromatography-mass spectrometry.
PubMed:CYP9Q-mediated detoxification of acaricides in the honey bee (Apis mellifera).
PubMed:Fluorinated monolithic column for CEC.
PubMed:Acaricides and their residues in Spanish commercial beeswax.
PubMed:A rapid and sensitive analytical method for the determination of 14 pyrethroids in water samples.
PubMed:Synergistic interactions between in-hive miticides in Apis mellifera.
PubMed:Study of the degradation products of bromopropylate, chlordimeform, coumaphos, cymiazole, flumethrin and tau-fluvalinate in aqueous media.
PubMed:New multiresidue method using solid-phase extraction and gas chromatography-micro-electron-capture detection for pesticide residues analysis in royal jelly.
PubMed:Residual effectiveness of three pyrethroids on vegetation against adult Aedes albopictus and Culex quinquefasciatus in screened field cages.
PubMed:Determination of 23 pesticide residues in leafy vegetables using gas chromatography-ion trap mass spectrometry and analyte protectants.
PubMed:Application of solid-phase microextraction for determination of pyrethroids in groundwater using liquid chromatography with post-column photochemically induced fluorimetry derivatization and fluorescence detection.
PubMed:Solid-phase microextraction (SPME) for the determination of pyrethroids in cucumber and watermelon using liquid chromatography combined with post-column photochemically induced fluorimetry derivatization and fluorescence detection.
PubMed:Pesticide residues in beeswax samples collected from honey bee colonies (Apis mellifera L.) in France.
PubMed:Efficacy of various pyrethroid structures against a highly metabolically resistant isogenic strain of Helicoverpa armigera (Lepidoptera: Noctuidae) from China.
PubMed:Efficacy of strips coated with Metarhizium anisopliae for control of Varroa destructor (Acari: Varroidae) in honey bee colonies in Texas and Florida.
PubMed:Mediation of pyrethroid insecticide toxicity to honey bees (Hymenoptera: Apidae) by cytochrome P450 monooxygenases.
PubMed:A survey of pesticide residues in pollen loads collected by honey bees in France.
PubMed:Determination of nine pyrethroid insecticides by high-performance liquid chromatography with post-column photoderivatization and detection based on acetonitrile chemiluminescence.
PubMed:Determination of acaricide residues in saudi arabian honey and beeswax using solid phase extraction and gas chromatography.
PubMed:Comparative sublethal toxicity of nine pesticides on olfactory learning performances of the honeybee Apis mellifera.
PubMed:[Determination of tau-fluvalinate residue in honey by GC].
PubMed:Field trials using the fungal pathogen, Metarhizium anisopliae (Deuteromycetes: Hyphomycetes) to control the ectoparasitic mite, Varroa destructor (Acari: Varroidae) in honey bee, Apis mellifera (Hymenoptera: Apidae) colonies.
PubMed:Effects of methoxyfenozide, indoxacarb, and other insecticides on the beneficial egg parasitoid Trichogramma nr. brassicae (Hymenoptera: Trichogrammatidae) under laboratory and field conditions.
PubMed:Insecticide-resistant pollen beetles (Meligethes aeneus F) found in Danish oilseed rape (Brassica napus L) fields.
PubMed:Biological monitoring of workers after the application of insecticidal pyrethroids.
PubMed:Application of solid-phase microextraction for the determination of pyrethroid residues in vegetable samples by GC-MS.
PubMed:Study of acaricide stability in honey. Characterization of amitraz degradation products in honey and beeswax.
PubMed:Study of tau-fluvalinate persistence in honey.
PubMed:A veterinary approach to the European honey bee (Apis mellifera)
PubMed:Field evaluation of neem and canola oil for the selective control of the honey bee (Hymenoptera: Apidae) mite parasites Varroa jacobsoni (Acari: Varroidae) and Acarapis woodi (Acari: Tarsonemidae).
PubMed:Comparative laboratory toxicity of neem pesticides to honey bees (Hymenoptera: Apidae), their mite parasites Varroa jacobsoni (Acari: Varroidae) and Acarapis woodi (Acari: Tarsonemidae), and brood pathogens Paenibacillus larvae and Ascophaera apis.
PubMed:Laboratory evaluation of miticides to control Varroa jacobsoni (Acari: Varroidae), a honey bee (Hymenoptera: Apidae) parasite.
PubMed:First detection in Israel of fluvalinate resistance in the varroa mite using bioassay and biochemical methods.
PubMed:Clean-up of aqueous acetone vegetable extracts by solid-matrix partition for pyrethroid residue determination by gas chromatography-electron-capture detection.
 
Notes:
None found
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