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kresoxim-methyl
benzeneacetic acid, a-(methoxyimino)-2-[(2-methylphenoxy)methyl]-, methyl ester, (aE)-

Supplier Sponsors

CAS Number: 143390-89-0Picture of molecule3D/inchi
FDA UNII: 0LXZ062TTB
Nikkaji Web:J588.356C
Beilstein Number:8330581
MDL:MFCD00871777
XlogP3-AA:4.10 (est)
Molecular Weight:313.35323000
Formula:C18 H19 N O4
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
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Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 99.00 °C. @ 760.00 mm Hg
Boiling Point: 429.43 °C. @ 760.00 mm Hg (est)
Vapor Pressure:1.720000 mmHg @ 1.72 °C. (est)
Flash Point: 340.00 °F. TCC ( 171.20 °C. ) (est)
logP (o/w): 3.400
Soluble in:
 water, 2 mg/L @ 20 °C (exp)
 water, 12.8 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
Kresoxim-methyl
Odor: characteristic
Use: An agricultural fungicide.
Santa Cruz Biotechnology
For experimental / research use only.
Kresoxim-methyl
Sigma-Aldrich
For experimental / research use only.
Kresoxim-methyl PESTANAL®, analytical standard
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
herbicides / pesticides
Recommendation for kresoxim-methyl usage levels up to:
 not for fragrance use.
 
Recommendation for kresoxim-methyl flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Reasoned opinion on the modification of the existing MRL for kresoxim-methyl in azaroles
View page or View pdf

Reasoned opinion on the review of the existing maximum residue levels (MRLs) for kresoxim-methyl according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf

Outcome of the consultation with Member States, the applicant and EFSA on the pesticide risk assessment of confirmatory data for the active substance kresoxim-methyl
View page or View pdf

Retrospective analysis of the immunotoxic effects of plant protection products as reported in the Draft Assessment Reports for their peer review at EU level
View page or View pdf

Modification of the existing maximum residue level for kresoxim-methyl in leeks
View page or View pdf

Evaluation of confirmatory data following the Article 12 MRL review for kresoxim-methyl
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :6112114
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
methyl (2E)-2-methoxyimino-2-[2-[(2-methylphenoxy)methyl]phenyl]acetate
Chemidplus:0143390890
 
References:
 methyl (2E)-2-methoxyimino-2-[2-[(2-methylphenoxy)methyl]phenyl]acetate
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):6112114
Pubchem (sid):135042284
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C11017
HMDB (The Human Metabolome Database):Search
ChemSpider:View
Wikipedia:View
Formulations/Preparations:
•usepaopp pesticide code 129111; trade names: bas 490f. •water dispersible granules; suspo-emulsion; suspension concentrate •mixtures: (kresoxim-methyl +) fenpropimorph; bas 480f; bas 480f+ fenpropimorph •enduse product is dry flowable formulation containing 50% active ingredient; formulating use product contains 94% active ingredient.
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 bas 490 F
 BAS 490F
 benzeneacetic acid, a-(methoxyimino)-2-((2-methylphenoxy)methyl)-, methyl ester, (E)-
 benzeneacetic acid, a-(methoxyimino)-2-[(2-methylphenoxy)methyl]-, methyl ester, (aE)-
 methyl (2E)-(methoxyimino){2-[(2-methylphenoxy)methyl]phenyl}acetate
 methyl (2E)-(methoxyimino){2-[(2-methylphenoxy)methyl]phenyl}ethanoate
 methyl (2E)-2-methoxyimino-2-[2-[(2-methylphenoxy)methyl]phenyl]acetate
 methyl (2E)-2-methoxyimino-2-[2-[(2-methylphenoxy)methyl]phenyl]ethanoate
 methyl (2E)-3-methoxy-2-{2-[(2-methylphenoxy)methyl]phenyl}-3-azaprop-2-enoate
 methyl (E)-a-(methoxyimino)-2-((2-methylphenoxy)methyl)benzeneacetate
 methyl (E)-a-(methoxyimino)-2-(2-methylphenoxymethyl)phenylacetate
(e)-methyl a-(methoxyimino)-2-((2-methylphenoxy)methyl)benzeneacetate
 methyl-(2E)-(methoxyimino){2-[(2-methylphenoxy)methyl]phenyl}acetat
 

Articles:

PubMed:Determination of fungicides in white grape bagasse by pressurized liquid extraction and gas chromatography tandem mass spectrometry.
PubMed:Inhibitory effects of respiration inhibitors on aflatoxin production.
PubMed:Use of benzo analogs to enhance antimycotic activity of kresoxim methyl for control of aflatoxigenic fungal pathogens.
PubMed:Sensitive monoclonal antibody-based immunoassays for kresoxim-methyl analysis in QuEChERS-based food extracts.
PubMed:Determination of strobilurin fungicides in cotton seed by combination of acetonitrile extraction and dispersive liquid-liquid microextraction coupled with gas chromatography.
PubMed:Dissipation kinetics, safety evaluation, and assessment of pre-harvest interval (PHI) and processing factor for kresoxim methyl residues in grape.
PubMed:Toxic effects of three strobilurins (trifloxystrobin, azoxystrobin and kresoxim-methyl) on mRNA expression and antioxidant enzymes in grass carp (Ctenopharyngodon idella) juveniles.
PubMed:Influence of new generation fungicides on Saccharomyces cerevisiae growth, grape must fermentation and aroma biosynthesis.
PubMed:Isolation and characterisation of azoxystrobin degrading bacteria from soil.
PubMed:Structure-immunogenicity relationship of kresoxim-methyl regioisomeric haptens.
PubMed:Environmental monitoring of pesticide residues from farms at a neighbouring primary and pre-school in the Western Cape in South Africa.
PubMed:Processing factor for a selected group of pesticides in a wine-making process: distribution of pesticides during grape processing.
PubMed:Fungicides transport in runoff from vineyard plot and catchment: contribution of non-target areas.
PubMed:[Determination of seven strobilurin fungicide residues in Chinese herbs by liquid chromatography-tandem mass spectrometry coupled with solid phase extraction].
PubMed:Effects of single pesticides and binary pesticide mixtures on estrone production in H295R cells.
PubMed:Ionic liquid-based ultrasound-assisted emulsification microextraction coupled with high performance liquid chromatography for the determination of four fungicides in environmental water samples.
PubMed:Residues and dissipation of kresoxim methyl in apple under field condition.
PubMed:Ultrasound-assisted surfactant-enhanced emulsification microextraction with solidification of floating organic droplet followed by high performance liquid chromatography for the determination of strobilurin fungicides in fruit juice samples.
PubMed:Simultaneous detection and degradation patterns of kresoxim-methyl and trifloxystrobin residues in citrus fruits by HPLC combined with QuEChERS.
PubMed:Determination of strobilurin fungicide residues in fruits and vegetables by micellar electrokinetic capillary chromatography with sweeping.
PubMed:Synergism of antifungal activity between mitochondrial respiration inhibitors and kojic acid.
PubMed:Analysis of isobaric pesticides in pepper with high-resolution liquid chromatography and mass spectrometry: complementary or redundant?
PubMed:Dissipation rates and final residues of kresoxim-methyl in strawberry and soil.
PubMed:Metabolism of strobilurins by wheat cell suspension cultures.
PubMed:Kresoxim methyl deposition, drift and runoff in a vineyard catchment.
PubMed:Analysis of kresoxim-methyl and its thermolabile metabolites in Korean plum: An application of pepper leaf matrix as a protectant for GC amenable metabolites.
PubMed:Occurrence and distribution study of residues from pesticides applied under controlled conditions in the field during rice processing.
PubMed:Influence of pesticides on yeasts colonizing leaves.
PubMed:Synthesis and bioactivity of novel coumarin derivatives.
PubMed:Removal of pesticide mixtures in a stormwater wetland collecting runoff from a vineyard catchment.
PubMed:Use of farming and agro-industrial wastes as versatile barriers in reducing pesticide leaching through soil columns.
PubMed:Sensitivity to strobilurin fungicides of Italian Venturia inaequalis populations with different origin and scab control.
PubMed:Coordination polymer adsorbent for matrix solid-phase dispersion extraction of pesticides during analysis of dehydrated Hyptis pectinata medicinal plant by GC/MS.
PubMed:Monitoring of QoI fungicide resistance in Plasmopara viticola populations in Japan.
PubMed:Use of chemosensitization to overcome fludioxonil resistance in Penicillium expansum.
PubMed:Toxicity of fungicides with different modes of action to Cladobotryum dendroides and Agaricus bisporus.
PubMed:Influence of several fungicides on the antioxidant activity of red wines (var. Monastrell).
PubMed:Solarization and biosolarization enhance fungicide dissipation in the soil.
PubMed:Subnanomolar inhibitor of cytochrome bc1 complex designed by optimizing interaction with conformationally flexible residues.
PubMed:Chemometric study and optimization of extraction parameters in single-drop microextraction for the determination of multiclass pesticide residues in grapes and apples by gas chromatography mass spectrometry.
PubMed:Photocatalytic degradation of eight pesticides in leaching water by use of ZnO under natural sunlight.
PubMed:Residue analysis of kresoxim-methyl and boscalid in fruits, vegetables and soil using liquid-liquid extraction and gas chromatography-mass spectrometry.
PubMed:Characterisation of QoI-resistant field isolates of Botrytis cinerea from citrus and strawberry.
PubMed:Baseline sensitivity to proquinazid in Blumeria graminis f. sp. tritici and Erysiphe necator and cross-resistance with other fungicides.
PubMed:[Study on the molecular recognization of fungicide of kresoxim-methyl with beta-cyclodextrin and its derivatives].
PubMed:The effect of fungicides on seed yield and disease control in Italian ryegrass.
PubMed:Method development and validation for strobilurin fungicides in baby foods by solid-phase microextraction gas chromatography-mass spectrometry.
PubMed:Control of strobilurin fungicides in wheat using direct analysis in real time accurate time-of-flight and desorption electrospray ionization linear ion trap mass spectrometry.
PubMed:Occurrence and molecular characterization of strobilurin resistance in cucumber powdery mildew and downy mildew.
PubMed:Synthesis and fungicidal activities of novel indene-substituted oxime ether strobilurins.
PubMed:Effect of the use of recent commercial fungicides [under good and critical agricultural practices] on the aroma composition of Monastrell red wines.
PubMed:Influence of fungicides on grape yeast content and its evolution in the fermentation.
PubMed:Management of apple scab (Venturia inaequalis) in Romania based on electronic warnings.
PubMed:Hapten synthesis and monoclonal antibody-based immunoassay development for the detection of the fungicide kresoxim-methyl.
PubMed:Assessing supercritical fluid extraction for the analysis of fipronil, kresoxim-methyl, acrinathrin, and pyridaben residues in melon.
PubMed:Validation and global uncertainty of a liquid chromatographic with diode array detection method for the screening of azoxystrobin, kresoxim-methyl, trifloxystrobin, famoxadone, pyraclostrobin and fenamidone in grapes and wine.
PubMed:Synthesis and fungicidal evaluation of novel chalcone-based strobilurin analogues.
PubMed:Safe apples for baby-food production: survey of pesticide treatment regimes leaving minimum residues.
PubMed:Determination of pesticide residues in foods by acetonitrile extraction and partitioning with magnesium sulfate: collaborative study.
PubMed:Capabilities of different liquid chromatography tandem mass spectrometry systems in determining pesticide residues in food. Application to estimate their daily intake.
PubMed:Design, synthesis, and fungicidal activities of new strobilurin derivatives.
PubMed:[Susceptibility of Trichogramma pretiosum Riley (Hymenoptera: Trichogrammatidae) adults to fungicides used to control apple diseases].
PubMed:Prioritization of pesticide environmental transformation products in drinking water supplies.
PubMed:Determination of fungicide kresoxim-methyl residues in cucumber and soil by capillary gas chromatography with nitrogen-phosphorus detection.
PubMed:Sensitivity of Venturia inaequalisto strobilurin fungicides in Italy.
PubMed:Fate of epoxiconazole and kresoxim-methyl in wheat according to time of application.
PubMed:Stereoselective synthesis and fungicidal activities of (E)-alpha-(methoxyimino)-benzeneacetate derivatives containing 1,3,4-oxadiazole ring.
PubMed:Determination of fungicide residues in field-grown strawberries following different fungicide strategies against gray mold (Botrytis cinerea).
PubMed:Screening of grapes and wine for azoxystrobin, kresoxim-methyl and trifloxystrobin fungicides by HPLC with diode array detection.
PubMed:Inhibition of efflux transporter-mediated fungicide resistance in Pyrenophora tritici-repentis by a derivative of 4'-hydroxyflavone and enhancement of fungicide activity.
PubMed:Signum, a new fungicide with interesting properties in resistance management of fungal diseases in strawberries.
PubMed:Molecular characterization and biological response to respiration inhibitors of Pyricularia isolates from ctenanthe and rice plants.
PubMed:Pesticide residues on the external surfaces of field crop sprayers: occupational exposure.
PubMed:Liquid chromatography-electrospray quadrupole ion-trap mass spectrometry of nine pesticides in fruits.
PubMed:Pesticide residues on the external surfaces of field-crop sprayers: environmental impact.
PubMed:Developing an ecotoxicological testing standard for predatory mites in Australia: acute and sublethal effects of fungicides on Euseius victoriensis and Galendromus occidentalis (Acarina: Phytoseiidae).
PubMed:Determination of pyrimethanil and kresoxim-methyl in soils by headspace solid-phase microextraction and gas chromatography-mass spectrometry.
PubMed:Activity of some chemicals in the control of Botrytis cinerea on roses.
PubMed:First detection of resistance to QoI fungicides in Mycosphaerella graminicola on winter wheat in Belgium.
PubMed:Application of liquid chromatography with electrospray tandem mass spectrometry to the determination of a new generation of pesticides in processed fruits and vegetables.
PubMed:Antifungal 3-butylisocoumarins from Asteraceae-Anthemideae.
PubMed:Distribution of multiple pesticide residues in apple segments after home processing.
PubMed:Multiple mechanisms account for variation in base-line sensitivity to azole fungicides in field isolates of Mycosphaerella graminicola.
PubMed:Cross-resistance to strobilurin fungicides in mitochondrial and nuclear mutants of Saccharomyces cerevisiae.
PubMed:Processing factors and variability of pyrimethanil, fenhexamid and tolylfluanid in strawberries.
PubMed:Impact of strobilurins on physiology and yield formation of wheat.
PubMed:Determination of pyrimethanil and kresoxim-methyl in green groceries by headspace solid-phase microextraction and gas chromatography-mass spectrometry.
PubMed:A non-Mendelian inheritance of resistance to strobilurin fungicides in Ustilago maydis.
PubMed:Semi-volatile organic compounds at the leaf/atmosphere interface: numerical simulation of dispersal and foliar uptake.
PubMed:Sensitivity of Venturia inaequalis to trifloxystrobin.
PubMed:Method validation for strobilurin fungicides in cereals and fruit.
PubMed:Characterization of laboratory mutants of Venturia inaequalis resistant to the strobilurin-related fungicide kresoxim-methyl.
PubMed:Pesticide residues in grapes, wine, and their processing products.
PubMed:Gas chromatographic determination of azoxystrobin, fluazinam, kresoxim-methyl, mepanipyrim, and tetraconazole in grapes, must, and wine.
 
Notes:
an oximether analog.
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