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Category:herbicides / pesticides
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | white crystalline powder (est) |
| Assay: | 95.00 to 100.00
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| Food Chemicals Codex Listed: | No |
| Boiling Point: | 546.22 °C. @ 760.00 mm Hg (est)
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| Flash Point: | 543.00 °F. TCC ( 284.10 °C. ) (est)
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| logP (o/w): | 6.443 (est) |
| Soluble in: |
| | water, 0.1185 mg/L @ 25 °C (est) |
Organoleptic Properties:
| Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-mouse LD50 440 mg/kg
Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 17, Pg. S261, 1992.
oral-rat LD50 245 mg/kg
Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 17, Pg. S261, 1992.
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| Dermal Toxicity: |
skin-rat LD50 > 2000 mg/kg
Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 17, Pg. S261, 1992.
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| Inhalation Toxicity: |
inhalation-rat LC50 330 mg/m3/4H
Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 17, Pg. S261, 1992.
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Safety in Use Information:
| Category: | | herbicides / pesticides |
| Recommendation for fenpyroximate usage levels up to: | | | not for fragrance use.
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| Recommendation for fenpyroximate flavor usage levels up to: |
| | not for flavor use.
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Safety References:
European Food Safety Authority (EFSA) reference(s):
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Reasoned opinion on the modification of the existing MRLs for fenpyroximate in various crops
View page or View pdf
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Conclusion on the peer review of the pesticide risk assessment of the active substance fenpyroximate
View page or View pdf
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Retrospective analysis of the immunotoxic effects of plant protection products as reported in the Draft Assessment Reports for their peer review at EU level
View page or View pdf
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Review of the existing maximum residue levels for fenpyroximate according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf
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| EPI System: View |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :9576412 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:3 |
| tert-butyl4-[[(E)-(1,3-dimethyl-5-phenoxypyrazol-4-yl)methylideneamino]oxymethyl]benzoate |
| Chemidplus:0111812589 |
References:
| | tert-butyl4-[[(E)-(1,3-dimethyl-5-phenoxypyrazol-4-yl)methylideneamino]oxymethyl]benzoate |
| NIST Chemistry WebBook: | Search Inchi |
| Pubchem (cid): | 9576412 |
| Pubchem (sid): | 135263619 |
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | benzoic acid, 4-((((E)-((1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene)amino)oxy)methyl)-, 1,1-dimethylethyl ester | | | benzoic acid, 4-[[[[(1E)-(1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino]oxy]methyl]-, 1,1-dimethylethyl ester | | tert- | butyl (E)-a-(1,3-dimethyl-5-phenoxypyrazol-4-ylmethyleneaminooxy)-p-toluate | | t- | butyl (E)-alpha-(1,3-dimethyl-5-phenoxypyrazol-4-ylmethyleneaminooxy)-p-toluate | | tert- | butyl 4-[({[(1E)-(1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino}oxy)methyl]benzoate | | tert- | butyl 4-[({[(1E)-(1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylidene]amino}oxy)methyl]benzoate | | tert- | butyl 4-[({[(E)-(1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino}oxy)methyl]benzoate | | tert- | butyl 4-[({[(E)-(1,3-dimethyl-5-phenoxy-1Hh-pyrazol-4-yl)methylidene]amino}oxy)methyl]benzoate | | tert- | butyl 4-[[(E)-(1,3-dimethyl-5-phenoxy-pyrazol-4-yl)methylideneamino]oxymethyl]benzoate | | tert- | butyl4-[[(E)-(1,3-dimethyl-5-phenoxypyrazol-4-yl)methylideneamino]oxymethyl]benzoate | | | danitron | | (E)-4-[[[[(1,3- | dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino]oxy]methyl]benzoic acid 1,1-dimethylethyl ester | | 4-[[(E)-(1,3- | dimethyl-5-phenoxy-4-pyrazolyl)methylideneamino]oxymethyl]benzoic acid tert-butyl ester | | 1,1- | dimethylethyl 4-[[[[(1E)-(1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino]oxy]methyl]benzoate | | | fujimite | | 2- | methyl-2-propanyl 4-[({[(E)-(1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino}oxy)methyl]benzoate |
Articles:
| PubMed:Development of a methodology and evaluation of pesticides against Aceria litchii and its predator Phytoseius intermedius (Acari: Eriophyidae, Phytoseiidae). |
| PubMed:Ionic liquid-based totally organic solvent-free emulsification microextraction coupled with high performance liquid chromatography for the determination of three acaricides in fruit juice. |
| PubMed:[Determination of ten pesticides of pyrazoles and pyrroles in tea by accelerated solvent extraction coupled with gas chromatography-tandem mass spectrometry]. |
| PubMed:Acaricide, fungicide and drug interactions in honey bees (Apis mellifera). |
| PubMed:Comparative toxicity of acaricides to honey bee (Hymenoptera: Apidae) workers and queens. |
| PubMed:Toxicity of acaricides to Raoiella indica and their selectivity for its predator, Amblyseius largoensis (Acari: Tenuipalpidae: Phytoseiidae). |
| PubMed:Survival and behavioural response to acaricides of the coconut mite predator Neoseiulus baraki. |
| PubMed:A case of near-fatal fenpyroximate intoxication: the role of percutaneous cardiopulmonary support and therapeutic hypothermia. |
| PubMed:Residual bioassay to assess the toxicity of Acaricides against Aceria guerreronis (Acari: Eriophyidae) under laboratory conditions. |
| PubMed:Evidence of the in vitro genotoxicity of methyl-pyrazole pesticides in human cells. |
| PubMed:Risk assessment of selected insecticides on Tamarixia triozae (Hymenoptera: Eulophidae), a parasitoid of Bactericera cockerelli (Hemiptera: Trizoidae). |
| PubMed:Acute toxic effects of fenpyroximate acaricide on Guppy (Poecilia reticulata Peters, 1859). |
| PubMed:Toxicity assessment of 45 pesticides to the epigeic earthworm Eisenia fetida. |
| PubMed:Resistance to acaricides in Italian strains of Tetranychus urticae: toxicological and enzymatic assays. |
| PubMed:Fenpyroximate binds to the interface between PSST and 49 kDa subunits in mitochondrial NADH-ubiquinone oxidoreductase. |
| PubMed:Acute and population level toxicity of imidacloprid and fenpyroximate on an important egg parasitoid, Trichogramma cacoeciae (Hymenoptera: Trichogrammatidae). |
| PubMed:Pyrethroid resistance in the tomato red spider mite, Tetranychus evansi, is associated with mutation of the para-type sodium channel. |
| PubMed:Sublethal effects of fenpyroximate and pyridaben on two predatory mite species, Neoseiulus womersleyi and Phytoseiulus persimilis (Acari, Phytoseiidae). |
| PubMed:DJ-1 deficiency in astrocytes selectively enhances mitochondrial Complex I inhibitor-induced neurotoxicity. |
| PubMed:Residue analysis of multi-class pesticides in watermelon by LC-MS/MS. |
| PubMed:A review: oxidative stress in fish induced by pesticides. |
| PubMed:In vitro and in vivo acute toxicity of fenpyroximate to flounder Paralichthys olivaceus and its gill cell line FG. |
| PubMed:Characterization of the inhibitor binding site in mitochondrial NADH-ubiquinone oxidoreductase by photoaffinity labeling using a quinazoline-type inhibitor. |
| PubMed:Resistance mechanisms to mitochondrial electron transport inhibitors in a field-collected strain of Tetranychus urticae Koch (Acari: Tetranychidae). |
| PubMed:Mechanism of toxicity of pesticides acting at complex I: relevance to environmental etiologies of Parkinson's disease. |
| PubMed:tert-Butyl 4-({[(E)-1,3-dimethyl-5-phen-oxy-pyrazol-4-yl]meth-yl}amino-oxymeth-yl)benzoate. |
| PubMed:Complete maternal inheritance of bifenazate resistance in Tetranychus urticae Koch (Acari: Tetranychidae) and its implications in mode of action considerations. |
| PubMed:Multiple resistance and biochemical mechanisms of pyridaben resistance in Tetranychus urticae (Acari: Tetranychidae). |
| PubMed:Side effects of five new acaricides on the predator Galendromus occidentalis (Acari, Phytoseiidae). |
| PubMed:Evaluation of resistance pattern to fenpyroximate and pyridaben in Tetranychus urticae collected from greenhouses and apple orchards using lethal concentration-slope relationship. |
| PubMed:Similar patterns of mitochondrial vulnerability and rescue induced by genetic modification of alpha-synuclein, parkin, and DJ-1 in Caenorhabditis elegans. |
| PubMed:Significance of habitat type for the genetic population structure of Panonychus citri (Acari: Tetranychidae). |
| PubMed:Fenpyroximate resistance in Tetranychus urticae (Acari: Tetranychidae): cross-resistance and biochemical resistance mechanisms. |
| PubMed:Application of liquid chromatography with electrospray tandem mass spectrometry to the determination of a new generation of pesticides in processed fruits and vegetables. |
| PubMed:Potentiation of a propargite and fenpyroximate mixture against two-spotted spider mite, Tetranychus urticae (Acari: Tetranychidae). |
| PubMed:Amiloride inhibition of the proton-translocating NADH-quinone oxidoreductase of mammals and bacteria. |
| PubMed:The ND5 subunit was labeled by a photoaffinity analogue of fenpyroximate in bovine mitochondrial complex I. |
| PubMed:Cross-resistance, inheritance, and biochemistry of mitochondrial electron transport inhibitor-acaricide resistance in Tetranychus urticae (Acari: Tetranychidae). |
| PubMed:Acaricide toxicity and resistance in larvae of different strains of Tetranychus urticae and Panonychus ulmi (Acari: Tetranychidae). |
| PubMed:Incidence and inheritance of resistance to METI-acaricides in European strains of the two-spotted spider mite (Tetranychus urticae) (Acari: Tetranychidae). |
| PubMed:Determination of fenpyroximate in apples by supercritical fluid extraction and packed capillary liquid chromatography with UV detection. |
| PubMed:A laboratory-based method to measure relative pesticide and spray oil efficacy against broad mite, Polyphagotarsonemus latus (Banks)(Acari: Tarsonemidae). |
| PubMed:Two binding sites of inhibitors in NADH: ubiquinone oxidoreductase (complex I). Relationship of one site with the ubiquinone-binding site of bacterial glucose:ubiquinone oxidoreductase. |
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3D/inchi