EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

4-O-methyl glucuronic acid
glucuronic acid, 4-O-methyl-

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Name:(2S,3S,4R,5R)-2,4,5-trihydroxy-3-methoxy-6-oxohexanoic acid
CAS Number: 2463-49-2Picture of molecule3D/inchi
FDA UNII: Search
Nikkaji Web:J573.357J
XlogP3:-2.00 (est)
Molecular Weight:208.16704000
Formula:C7 H12 O7
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:natural substances and extractives
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
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Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Soluble in:
 water, 1e+006 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
4-O-Methyl-D-glucuronic acid
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
natural substances and extractives
Recommendation for 4-O-methyl glucuronic acid usage levels up to:
 not for fragrance use.
 
Recommendation for 4-O-methyl glucuronic acid flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :151010
National Institute of Allergy and Infectious Diseases:Data
(2S,3S,4R,5R)-2,4,5-trihydroxy-3-methoxy-6-oxohexanoic acid
Chemidplus:0002463492
 
References:
 (2S,3S,4R,5R)-2,4,5-trihydroxy-3-methoxy-6-oxohexanoic acid
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):151010
Pubchem (cas):2463-49-2
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
FooDB:FDB003760
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 cashew sap
Search Trop Picture
 plum fruit
Search Trop Picture
 
Synonyms:
 glucuronic acid, 4-O-methyl-
4-O-methylglucuronic acid
(2S,3S,4R,5R)-2,4,5-trihydroxy-3-methoxy-6-oxohexanoic acid
 

Articles:

PubMed:Structure analysis of a novel heteroxylan from the stem of Dendrobium officinale and anti-angiogenesis activities of its sulfated derivative.
PubMed:Structure elucidation of an immunostimulatory arabinoxylan-type polysaccharide prepared from young barley leaves (Hordeum vulgare L.).
PubMed:Prebiotic potential of neutral oligo- and polysaccharides from seed mucilage of Hyptis suaveolens.
PubMed:Conservation in the mechanism of glucuronoxylan hydrolysis revealed by the structure of glucuronoxylan xylanohydrolase (CtXyn30A) from Clostridium thermocellum.
PubMed:In situ enzyme aided adsorption of soluble xylan biopolymers onto cellulosic material.
PubMed:Modifying solubility of polymeric xylan extracted from Eucalyptus grandis and sugarcane bagasse by suitable side chain removing enzymes.
PubMed:The role of the glucuronoxylan carboxyl groups in the action of endoxylanases of three glycoside hydrolase families: A study with two substrate mutants.
PubMed:The GH67 α-glucuronidase of Paenibacillus curdlanolyticus B-6 removes hexenuronic acid groups and facilitates biodegradation of the model xylooligosaccharide hexenuronosyl xylotriose.
PubMed:Effect of xylan structure on reactivity in graft copolymerization and subsequent binding to cellulose.
PubMed:Degradation mechanism of monosaccharides and xylan under pyrolytic conditions with theoretic modeling on the energy profiles.
PubMed:GUX1 and GUX2 glucuronyltransferases decorate distinct domains of glucuronoxylan with different substitution patterns.
PubMed:Quantitation of 4-O-methylglucuronic acid from plant cell walls.
PubMed:Substituent-specific antibody against glucuronoxylan reveals close association of glucuronic acid and acetyl substituents and distinct labeling patterns in tree species.
PubMed:Separation and characterization of acetyl and non-acetyl hemicelluloses of Arundo donax by ammonium sulfate precipitation.
PubMed:Biochemical characterization and relative expression levels of multiple carbohydrate esterases of the xylanolytic rumen bacterium Prevotella ruminicola 23 grown on an ester-enriched substrate.
PubMed:Studies on the starch and hemicelluloses fractionated by graded ethanol precipitation from bamboo Phyllostachys bambusoides f. shouzhu Yi.
PubMed:Absence of branches from xylan in Arabidopsis gux mutants reveals potential for simplification of lignocellulosic biomass.
PubMed:Structural and physico-chemical characterization of hemicelluloses from ultrasound-assisted extractions of partially delignified fast-growing poplar wood through organic solvent and alkaline solutions.
PubMed:Purification, characterization and mass spectrometric sequencing of a thermophilic glucuronoyl esterase from Sporotrichum thermophile.
PubMed:Cloning and expression analysis of a wood-associated xylosidase gene (PtaBXL1) in poplar tension wood.
PubMed:Structural characterization and cytotoxic properties of a 4-O-methylglucuronoxylan from castanea sativa. 2. Evidence of a structure-activity relationship.
PubMed:Identification of genes encoding microbial glucuronoyl esterases.
PubMed:Structural characterization and cytotoxic properties of a 4-O-methylglucuronoxylan from Castanea sativa.
PubMed:Evidence of the presence of 2-O-beta-D-xylopyranosyl-alpha-l-arabinofuranose side chains in barley husk arabinoxylan.
PubMed:A polysaccharide from a tea (infusion) of Maytenus ilicifolia leaves with anti-ulcer protective effects.
PubMed:Electrospray tandem mass spectrometry of underivatised acetylated xylo-oligosaccharides.
PubMed:Arabidopsis fragile fiber8, which encodes a putative glucuronyltransferase, is essential for normal secondary wall synthesis.
PubMed:Chemical composition and structural features of the macromolecular components of plantation Acacia mangium wood.
PubMed:Extraction and characterization of original lignin and hemicelluloses from wheat straw.
PubMed:Xylans from the medicinal herb Phyllanthus niruri.
PubMed:Cloning, characterization, and functional expression of the Klebsiella oxytoca xylodextrin utilization operon (xynTB) in Escherichia coli.
PubMed:Isolation and characterization of water-soluble hemicelluloses from flax shive.
PubMed:Structure of a highly substituted beta-xylan of the gum exudate of the palm Livistona chinensis (Chinese fan).
PubMed:Chemical compositions of hardwood and softwood pulps employing photoacoustic Fourier transform infrared spectroscopy in combination with partial least-squares analysis.
PubMed:Structural characterisation of underivatised olive pulp xylo-oligosaccharides by mass spectrometry using matrix-assisted laser desorption/ionisation and electrospray ionisation.
PubMed:In vitro fermentability of differently substituted xylo-oligosaccharides.
PubMed:Patterns of methyl and O-acetyl esterification in spinach pectins: new complexity.
PubMed:Immunomodulatory activity of acidic xylans in relation to their structural and molecular properties.
PubMed:Characterization of O-acetyl-(4-O-methylglucurono)xylan isolated from birch and beech.
PubMed:Distribution of uronic acids in xylans from various species of soft- and hardwood as determined by MALDI mass spectrometry.
PubMed:Structural features of a water soluble gum polysaccharide from Murraya paniculata fruits.
PubMed:Composition and effect of salt on rheological and gelation properties of Enterolobium contortisilliquum gum exudate.
PubMed:Three-dimensional structure of the catalytic core of acetylxylan esterase from Trichoderma reesei: insights into the deacetylation mechanism.
PubMed:Effects of purified endo-beta-1,4-xylanases of family 10 and 11 and acetyl xylan esterases on eucalypt sulfite dissolving pulp.
PubMed:Inverting character of alpha-glucuronidase A from Aspergillus tubingensis.
PubMed:An alpha-glucuronidase of Schizophyllum commune acting on polymeric xylan.
PubMed:A (1-->3,6)-beta-d-galactosyl epitope containing uronic acids associated with bioactive pectins occurs in discrete cell wall domains in hypocotyl and root tissues of flax seedlings.
PubMed:Similarity of monosaccharide, oligosaccharide and polysaccharide structures in gum exudate of Anacardium occidentale.
PubMed:aguA, the gene encoding an extracellular alpha-glucuronidase from Aspergillus tubingensis, is specifically induced on xylose and not on glucuronic acid.
PubMed:Isolation and analysis of a gene encoding alpha-glucuronidase, an enzyme with a novel primary structure involved in the breakdown of xylan.
PubMed:An HPLC method for the quantitative determination of hexeneuronic acid groups in chemical pulps.
PubMed:Characterisation of 4-deoxy-beta-L-threo-hex-4-enopyranosyluronic acid attached to xylan in pine kraft pulp and pulping liquor by 1H and 13C NMR spectroscopy.
PubMed:Isolation and structural characterization of beta-D-glucosyluronic acid and 4-O-methyl beta-D-glucosyluronic acid-containing oligosaccharides from the cell-wall pectic polysaccharide, rhamnogalacturonan I.
PubMed:[Estimated structure of the polysaccharide related eye lesions, and biological actions of 4-O-methylaldobiouronic acid and it's partially acetylated derivative].
PubMed:Formation of Novel Polysaccharides by Bradyrhizobium japonicum Bacteroids in Soybean Nodules.
PubMed:Enzymic Studies of the Distribution Pattern of 4-O-Methylglucuronic Acid Residues in Glucuronoxylans from Sunflower Hulls.
PubMed:Structural analysis of papaya polysaccharide II.
PubMed:Isolation and characterization of a soybean lectin having 4-O-methylglucuronic acid specificity.
PubMed:Extracellular polysaccharide composition, ex planta nitrogenase activity, and DNA homology in Rhizobium japonicum.
PubMed:The localization of 4-O-methylglucuronic acid-containing glycosphingolipid on the cell surface of bivalve spermatozoa by use of an immunological method.
PubMed:A soybean lectin having 4-O-methyl-D-glucuronic acid specificity.
PubMed:Isolation and characterization of a 4-O-methylglucuronic acid-containing glycosphingolipid from spermatozoa of a fresh water bivalve, Hyriopsis schlegelii.
PubMed:The isolation and characterization of 4-O-methylglucuronic acid-containing glycosphingolipid from spermatozoa of a fresh water bivalve, hyriopsis schlegelii.
PubMed:Inhibition of glucuronokinase by substrate analogs.
PubMed:The immunological specificity of type II Pneumococcus and its separation into partial specificities. II.
 
Notes:
None found
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