EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

boscalid
3-pyridinecarboxamide, 2-chloro-N-(4'-chloro(1,1'-biphenyl)-2-yl)-

Supplier Sponsors

CAS Number: 188425-85-6Picture of molecule3D/inchi
FDA UNII: 32MS8ZRD1V
Nikkaji Web:J1.989.940C
MDL:MFCD06795150
XlogP3-AA:4.90 (est)
Molecular Weight:343.21084000
Formula:C18 H12 Cl2 N2 O
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
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Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Appearance:white crystalline (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 142.80 °C. @ 760.00 mm Hg (est)
Boiling Point: 447.70 °C. @ 760.00 mm Hg (est)
Vapor Pressure:5.400000 mmHg @ 20.00 °C. (est)
Flash Point: 436.00 °F. TCC ( 224.60 °C. ) (est)
logP (o/w): 4.310 (est)
Soluble in:
 water, 20.19 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
Boscalid
Santa Cruz Biotechnology
For experimental / research use only.
Boscalid
Sigma-Aldrich
For experimental / research use only.
Boscalid PESTANAL®, analytical standard
TCI AMERICA
For experimental / research use only.
Boscalid
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
herbicides / pesticides
Recommendation for boscalid usage levels up to:
 not for fragrance use.
 
Recommendation for boscalid flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Reasoned opinion on the review of the existing maximum residue levels (MRLs) for boscalid according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf

Reasoned opinion on the modification of the existing maximum residue levels (MRLs) for boscalid in beans and peas with pods
View page or View pdf

Modification of the existing maximum residue level for boscalid in honey
View page or View pdf

Modification of the existing maximum residue level for boscalid in pomegranates
View page or View pdf

EPI System: View
ClinicalTrials.gov:search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :213013
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
2-chloro-N-[2-(4-chlorophenyl)phenyl]pyridine-3-carboxamide
Chemidplus:0188425856
 
References:
 2-chloro-N-[2-(4-chlorophenyl)phenyl]pyridine-3-carboxamide
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):213013
Pubchem (sid):135187034
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C18547
HMDB (The Human Metabolome Database):Search
ChemSpider:View
Formulations/Preparations:
•emerald fungicide active ingredient 70.0% 3-pyridinecarboxamide, 2-chloro-n-(4'chloro[1,1'biphenyl]-2-yl) •endura fungicide active ingredient 70.0% 3-pyridinecarboxamide, 2-chloro-n-(4'chloro[1,1'biphenyl]-2-yl) •pristine fungicide active ingredient 12.8% pyraclostrobin and 25.2% 3-pyridinecarboxamide, 2-chloro-n-(4'chloro[1,1'biphenyl]-2-yl) •boscalid technical active ingredient 99.0% 3-pyridinecarboxamide, 2-chloro-n-(4'chloro[1,1'biphenyl]-2-yl) •endura fungicide contains 70% active ingredient, and the wettable granule (wg) pristine contains a mixture of boscalid (25.2% active) and pyraclostrobin (12.8% active). there is also a formulated 70% wettable granule end-use product named boscalid turf fungicide.
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 anilide
 cantus
2-chloro-N-[2-(4-chlorophenyl)phenyl]pyridine-3-carboxamide
 emerald
 endura
 nicobifen
 pristine
3-pyridinecarboxamide, 2-chloro-N-(4'-chloro(1,1'-biphenyl)-2-yl)-
 

Articles:

PubMed:A pleiotropic drug resistance transporter is involved in reduced sensitivity to multiple fungicide classes in Sclerotinia homoeocarpa (F.T. Bennett).
PubMed:Determination of 28 pesticides applied on two tomato cultivars with a different surface/weight ratio of the berries, using a multiresidue GC-MS/MS method.
PubMed:Effect of two anti-fungal treatments (metrafenone and boscalid plus kresoxim-methyl) applied to vines on the color and phenol profile of different red wines.
PubMed:[Professional risk assessment for modern pesticides during their application in the horticulture].
PubMed:Modelling the biphasic sorption of simazine, imidacloprid, and boscalid in water/soil systems.
PubMed:Design and development of heterologous competitive immunoassays for the determination of boscalid residues.
PubMed:Fungicide resistance of Botrytis cinerea in tomato greenhouses in the Canary Islands and effectiveness of non-chemical treatments against gray mold.
PubMed:Synthesis and Antifungal Activity of Nicotinamide Derivatives as Succinate Dehydrogenase Inhibitors.
PubMed:UV-visible degradation of boscalid--structural characterization of photoproducts and potential toxicity using in silico tests.
PubMed:Fitness measurement reveals contrasting costs in homologous recombinant mutants of Botrytis cinerea resistant to succinate dehydrogenase inhibitors.
PubMed:Part II: temporal and spatial distribution of multiclass pesticide residues in lake sediments of northern Greece: application of an optimized MAE-LC-MS/MS pretreatment and analytical method.
PubMed:Inhibitory effects of respiration inhibitors on aflatoxin production.
PubMed:Molecular characterisation and detection of resistance to succinate dehydrogenase inhibitor fungicides in Botryotinia fuckeliana (Botrytis cinerea).
PubMed:Genetic diversity in Monilinia laxa populations in stone fruit species in Hungary.
PubMed:[Determination of six novel amide fungicides in vegetables and fruits by liquid chromatography-tandem mass spectrometry].
PubMed:Spatial distribution of single-nucleotide polymorphisms related to fungicide resistance and implications for sampling.
PubMed:Behavior of pyrimethanil, pyraclostrobin, boscalid, cypermethrin and chlorpyrifos residues on raspberry fruit and leaves of Laszka variety.
PubMed:Mechanistic analysis of metabolomics patterns in rat plasma during administration of direct thyroid hormone synthesis inhibitors or compounds increasing thyroid hormone clearance.
PubMed:Occurrence of fungicide resistance in populations of Botryotinia fuckeliana (Botrytis cinerea) on table grape and strawberry in southern Italy.
PubMed:Effect of a fungicide and spray adjuvant on queen-rearing success in honey bees (Hymenoptera: Apidae).
PubMed:Influence of new generation fungicides on Saccharomyces cerevisiae growth, grape must fermentation and aroma biosynthesis.
PubMed:Fitness and competitive ability of Botrytis cinerea field isolates with dual resistance to SDHI and QoI fungicides, associated with several sdhB and the cytb G143A mutations.
PubMed:Influence of an intensive agricultural drainage basin on the seasonal distribution of organic pollutants in seawater from a Mediterranean coastal lagoon (Mar Menor, SE Spain).
PubMed:Site-directed mutagenesis of the P225, N230 and H272 residues of succinate dehydrogenase subunit B from Botrytis cinerea highlights different roles in enzyme activity and inhibitor binding.
PubMed:Environmental monitoring of pesticide residues from farms at a neighbouring primary and pre-school in the Western Cape in South Africa.
PubMed:Molecular characterization and detection of mutations associated with resistance to succinate dehydrogenase-inhibiting fungicides in Alternaria solani.
PubMed:Environmental fate of fungicides and other current-use pesticides in a central California estuary.
PubMed:Sorption of selected pesticides on soils, sediment and straw from a constructed agricultural drainage ditch or pond.
PubMed:Alteration of the content of primary and secondary metabolites in strawberry fruit by Colletotrichum nymphaeae infection.
PubMed:Finding of pesticides in fashionable fruit juices by LC-MS/MS and GC-MS/MS.
PubMed:Effect of nonpersistent pesticides on estrogen receptor, androgen receptor, and aryl hydrocarbon receptor.
PubMed:Occurrence and persistence of fungicides in bed sediments and suspended solids from three targeted use areas in the United States.
PubMed:Synthesis and antifungal activity of N-(substituted pyridinyl)-1-methyl(phenyl)-3-(trifluoromethyl)-1H-pyrazole-4-carboxamide derivatives.
PubMed:Method development and validation for boscalid in blueberries by solid-phase microextraction gas chromatography, and their degradation kinetics.
PubMed:Comparison of four extraction methods for the determination of fungicide residues in grapes through gas chromatography-mass spectrometry.
PubMed:Optimization and validation of a simple and fast method for the determination of fungicides in must and wine samples by SPE and GC/MS.
PubMed:Fungicide resistance status in French populations of the wheat eyespot fungi Oculimacula acuformis and Oculimacula yallundae.
PubMed:A sensitive and selective method for the determination of selected pesticides in fruit by gas chromatography/mass spectrometry with negative chemical ionization.
PubMed:Micronuclei, nucleoplasmic bridges, and nuclear buds induced in human lymphocytes by the fungicide signum and its active ingredients (boscalid and pyraclostrobin).
PubMed:Occurrence of boscalid and other selected fungicides in surface water and groundwater in three targeted use areas in the United States.
PubMed:Biological activity of the succinate dehydrogenase inhibitor fluopyram against Botrytis cinerea and fungal baseline sensitivity.
PubMed:Pre-harvest treatments with fungicides and post-harvest dips in sodium bicarbonate to control postharvest decay in stone fruit.
PubMed:Molecular characterization of boscalid- and penthiopyrad-resistant isolates of Didymella bryoniae and assessment of their sensitivity to fluopyram.
PubMed:Remediation of fungicide residues on fresh produce by use of gaseous ozone.
PubMed:Impact of vineyard pesticides on a beneficial arthropod, Typhlodromus pyri (Acari: Phytoseiidae), in laboratory bioassays.
PubMed:Stability and fitness of pyraclostrobin- and boscalid-resistant phenotypes in field isolates of Botrytis cinerea from apple.
PubMed:Use of soft and hard ionization techniques for elucidation of unknown compounds by gas chromatography/time-of-flight mass spectrometry.
PubMed:Fate of iprovalicarb, indoxacarb, and boscalid residues in grapes and wine by GC-ITMS analysis.
PubMed:Glove accumulation of pesticide residues for strawberry harvester exposure assessment.
PubMed:Molecular characterization of boscalid resistance in field isolates of Botrytis cinerea from apple.
PubMed:Lack of cross-resistance to a novel succinate dehydrogenase inhibitor, fluopyram, in highly boscalid-resistant isolates of Corynespora cassiicola and Podosphaera xanthii.
PubMed:Multiple resistance of Botrytis cinerea from kiwifruit to SDHIs, QoIs and fungicides of other chemical groups.
PubMed:Response surface optimization for determination of pesticide residues in grapes using MSPD and GC-MS: assessment of global uncertainty.
PubMed:Minor crops for export: a case study of boscalid, pyraclostrobin, lufenuron and lambda-cyhalothrin residue levels on green beans and spring onions in Egypt.
PubMed:High levels of miticides and agrochemicals in North American apiaries: implications for honey bee health.
PubMed:Residue analysis of multi-class pesticides in watermelon by LC-MS/MS.
PubMed:Dissipation and residues of boscalid in strawberries and soils.
PubMed:Description of Cryptosporiopsis kienholzii and species profiles of Neofabraea in major pome fruit growing districts in the Pacific Northwest USA.
PubMed:Residue analysis of kresoxim-methyl and boscalid in fruits, vegetables and soil using liquid-liquid extraction and gas chromatography-mass spectrometry.
PubMed:Multiresidue determination of 11 new fungicides in grapes and wines by liquid-liquid extraction/clean-up and programmable temperature vaporization injection with analyte protectants/gas chromatography/ion trap mass spectrometry.
PubMed:Effectiveness of control strategies against Botrytis cinerea in vineyard and evaluation of the residual fungicide concentrations.
PubMed:Baseline sensitivity of Stemphylium vesicarium, the causal agent of pear brown spot, to boscalid.
PubMed:Characterization of mutations in the iron-sulphur subunit of succinate dehydrogenase correlating with Boscalid resistance in Alternaria alternata from California pistachio.
PubMed:On-line electrochemistry/liquid chromatography/mass spectrometry for the simulation of pesticide metabolism.
PubMed:Palladium-catalyzed direct arylation of nitro-substituted aromatics with aryl halides.
PubMed:Toxicity of six novel fungicides and sulphur to Galendromus occidentalis (Acari: Phytoseiidae).
PubMed:Diagnostic tools to identify black aspergilli.
PubMed:Pesticides selectivity list to beneficial arthropods in four field vegetable crops.
PubMed:Screening preharvest/postharvest strategies to prevent fruit rot decay.
PubMed:Synthesis of biaryls via catalytic decarboxylative coupling.
PubMed:Signum, a new fungicide for control of leaf diseases in outdoor vegetables.
PubMed:Signum, a new fungicide with interesting properties in resistance management of fungal diseases in strawberries.
PubMed:Developing an ecotoxicological testing standard for predatory mites in Australia: acute and sublethal effects of fungicides on Euseius victoriensis and Galendromus occidentalis (Acarina: Phytoseiidae).
PubMed:Use of PRZM-3 to validate a laboratory to field degradation conceptual model.
 
Notes:
None found
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