lithium hydroxide
lithium hydrate
 
Notes:
used for tryptophan determinations in proteins & foods.
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      LITHIUM HYDROXIDE, ANHYDROUS
       
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    • TCI AMERICA
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      L0225 Lithium Hydroxide Anhydrous >98.0%(T)
       
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lithium;hydroxide (Click)
CAS Number: 1310-65-2Picture of molecule
ECHA EINECS - REACH Pre-Reg: 215-183-4
FDA UNII: 903YL31JAS
Nikkaji Web: J43.856A
MDL: MFCD00011095
Molecular Weight: 23.94817000
Formula: Li H O
NMR Predictor: Predict (works with chrome or firefox)
Category: buffering agents
 
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Physical Properties:
Assay: 95.00 to 100.00 % 
Food Chemicals Codex Listed: No
Flash Point: 32.00 °F. TCC ( 0.00 °C. ) (est)
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Organoleptic Properties:
  
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: buffering agents
hair straightening agents
hair waving agents
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Suppliers:
Charkit Chemical
LITHIUM HYDROXIDE, ANHYDROUS
Santa Cruz Biotechnology
For experimental / research use only.
Lithium Hydroxide 98%
Sigma-Aldrich
For experimental / research use only.
Lithium Hydroxide powder, reagent grade, ≥98%
Strem Chemicals
For experimental / research use only.
Lithium hydroxide, anhydrous, 95%
TCI AMERICA
For experimental / research use only.
Lithium Hydroxide Anhydrous >98.0%(T)
Universal Preserv-A-Chem Inc.
LITHIUM HYDROXIDE ANHYDROUS
Odor: characteristic
Use: Lithium hydroxide is mainly consumed for the production of lithium greases. A popular lithium grease is lithium stearate, which is a general-purpose lubricating grease due to its high resistance to water and usefulness at both high and low temperatures. Lithium hydroxide is used in breathing gas purification systems for spacecraft, submarines, and rebreathers to remove carbon dioxide from exhaled gas by producing lithium carbonate and water.
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Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-mouse LD50  363 mg/kg
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 152, 1999.

intratracheal-rat LD50  8200 ug/kg
BLOOD: HEMORRHAGE LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 152, 1999.

oral-rat LD50  210 mg/kg
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
"Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 152, 1999.

Dermal Toxicity:
subcutaneous-mouse LDLo 300 mg/kg
Pharmacology and Toxicology. English translation of FATOAO. Vol. 21, Pg. 419, 1958.

Inhalation Toxicity:
inhalation-rat LC50 960 mg/m3/4H
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Fundamental and Applied Toxicology. Vol. 7, Pg. 58, 1986.

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Safety in Use Information:
Category: buffering agents
Recommendation for lithium hydroxide usage levels up to:
 not for fragrance use.
 
Recommendation for lithium hydroxide flavor usage levels up to:
 not for flavor use.
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Safety References:
EPI System: View
NIOSH International Chemical Safety Cards: search
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 1310-65-2
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 3939
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 lithium;hydroxide
Chemidplus: 0001310652
EPA/NOAA CAMEO: hazardous materials
RTECS: 1310-65-2
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References:
 lithium;hydroxide
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 1310-65-2
Pubchem (cid): 3939
Pubchem (sid): 135020592
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
CHEBI: View
HMDB (The Human Metabolome Database): Search
Export Tariff Code: 2825.20.0000
Haz-Map: View
ChemSpider: View
Wikipedia: View
RSC Learn Chemistry: View
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Potential Blenders and core components note
 
None Found
 
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Potential Uses:
 buffering agents 
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
 lithium hydrate
 lithium hydroxide anhydrous
 lithium hydroxide, solution [UN2679] [Corrosive]
 lithium;hydroxide
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Articles:
PubMed: Mesoporous Li4Ti5O12-x/C submicrospheres with comprehensively improved electrochemical performances for high-power lithium-ion batteries.
PubMed: Lithium hydroxide, LiOH, at elevated densities.
PubMed: Molecular-level insights into the reactivity of siloxane-based electrolytes at a lithium-metal anode.
PubMed: Bactericidal effect of polyethyleneimine capped ZnO nanoparticles on multiple antibiotic resistant bacteria harboring genes of high-pathogenicity island.
PubMed: Monitoring the Electrochemical Processes in the Lithium-Air Battery by Solid State NMR Spectroscopy.
PubMed: Hierarchical Li4Ti5O12/TiO2 composite tubes with regular structural imperfection for lithium ion storage.
PubMed: Ultrafiltration of uranyl peroxide nanoclusters for the separation of uranium from aqueous solution.
PubMed: Cellulose-clay layered nanocomposite films fabricated from aqueous cellulose/LiOH/urea solution.
PubMed: Synthetic and DFT studies towards a unified approach to phlegmarine alkaloids: aza-Michael intramolecular processes leading to 5-oxodecahydroquinolines.
PubMed: Reversibility of anodic lithium in rechargeable lithium-oxygen batteries.
PubMed: Synthesis of a trisaccharide repeat of the zwitterionic Sp1 capsular polysaccharide utilizing 2-Azido-4-benzylamino-4N,3-O-carbonyl-2,4,6-trideoxy-d-galactopyranosyl trichloroacetimidate.
PubMed: Ion exchange and structural aging in the layered perovskite phases H(1-x)Li(x)LaTiO4.
PubMed: The influence of two lithium forms on the growth, L-ascorbic acid content and lithium accumulation in lettuce plants.
PubMed: Feasibility of manufacturing geopolymer bricks using circulating fluidized bed combustion bottom ash.
PubMed: Beam-assisted large elongation of in situ formed Li₂O nanowires.
PubMed: Simultaneous determination of NH4+, NO2(-) and NO3(-) by ion-exclusion/anion-exchange chromatography on a strongly basic anion-exchange resin with basic eluent.
PubMed: Gas phase chemistry of Li+ with amides: the observation of LiOH loss in mass spectrometry.
PubMed: Topologically unique heterometallic Cu(II)/Li coordination polymers self-assembled from N,N-bis(2-hydroxyethyl)-2-aminoethanesulfonic acid biobuffer: versatile catalyst precursors for mild hydrocarboxylation of alkanes to carboxylic acids.
PubMed: Synthesis of oxygenated fuel additives via the solventless etherification of glycerol.
PubMed: Color-tunable photoluminescent fullerene nanoparticles.
PubMed: Flower-like surface modification of titania materials by lithium hydroxide solution.
PubMed: A study of the hydration of the alkali metal ions in aqueous solution.
PubMed: Highly sensitive analysis of boron and lithium in aqueous solution using dual-pulse laser-induced breakdown spectroscopy.
PubMed: Preparation and electrochemical performance of hyper-networked Li4Ti5O12/carbon hybrid nanofiber sheets for a battery-supercapacitor hybrid system.
PubMed: Transparent cellulose films with high gas barrier properties fabricated from aqueous alkali/urea solutions.
PubMed: Assignment of the vibrational spectra of lithium hydroxide monohydrate, LiOH·H2O.
PubMed: Lithium hydroxide dihydrate: a new type of icy material at elevated pressure.
PubMed: Synthesis of Heterogeneous Li(4)Ti(5)O(12) Nanostructured Anodes with Long-Term Cycle Stability.
PubMed: Tri- and tetranuclear nickel(II) inverse metallacrown complexes involving oximato oxygen linkers: role of the guest anion (oxo versus alkoxo) in controlling the size of the ring topology.
PubMed: Photocatalytic degradation in aqueous solution using quantum-sized ZnO particles supported on sepiolite.
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PubMed: Mechanism of a reversible CO2 capture monitored by the layered perovskite Li2SrTa2O7.
PubMed: Reaction mechanisms of Li(0.30)La(0.57)TiO3 powder with ambient air: H+/Li+ exchange with water and Li2CO3 formation.
PubMed: Lithographically patterned silicon nanowire arrays for matrix free LDI-TOF/MS analysis of lipids.
PubMed: Spontaneous formation of crystalline lithium molybdate from solid reagents at room temperature.
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PubMed: Synthesis of zeolite Li-ABW from fly ash by fusion method.
PubMed: Liquid chromatographic determination of acetylcholine based on pre-column alkaline cleavage reaction and post-column tris(2,2'-bipyridyl)ruthenium(III) chemiluminescence detection.
PubMed: Generation of high-purity hydrogen from cellulose by its mechanochemical treatment.
PubMed: Chitosan-LiOH-urea aqueous solution--a novel water-based system for chitosan processing.
PubMed: Alkali-hydroxide-doped matrices for structural characterization of neutral underivatized oligosaccharides by MALDI time-of-flight mass spectrometry.
PubMed: Lithium monoxide anion: a ground-state triplet with the strongest base to date.
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PubMed: Ultrasound assisted synthesis of nano-sized lithium cobalt oxide.
PubMed: High performance ion chromatography of haloacetic acids on macrocyclic cryptand anion exchanger.
PubMed: Enantiospecific syntheses of copper cubanes, double-stranded copper/palladium helicates, and a (dilithium)-dinickel coronate from enantiomerically pure bis-1,3-diketones--solid-state self-organization towards wirelike copper/palladium strands.
PubMed: Copper(II) coordination polymers derived from triethanolamine and pyromellitic acid for bioinspired mild peroxidative oxidation of cyclohexane.
PubMed: Protection of lithium metal surfaces using chlorosilanes.
PubMed: Hydrogen-bond-induced inclusion complex in aqueous cellulose/LiOH/urea solution at low temperature.
PubMed: Carbonate assignment and calibration in the Raman spectrum of apatite.
PubMed: Large-scale, surfactant-free, hydrothermal synthesis of lithium aluminate nanorods: optimization of parameters and investigation of growth mechanism.
PubMed: Synthesis of some members of the hydroxylated phenanthridone subclass of the Amaryllidaceae alkaloid family.
PubMed: Hydrogen bonding-induced aromatic oligoamide foldamers as spherand analogues to accelerate the hydrolysis of nitro-substituted anisole in aqueous media.
PubMed: Synthetic studies on novel benzimidazolopeptides with antimicrobial, cytotoxic and anthelmintic potential.
PubMed: Synthesis and spectroscopic studies on iron(III) complexes of 1-benzotriazol-1-yl-1-[(p-X-phenyl)hydrazono]propan-2-one.
PubMed: Compound A and carbon monoxide production from sevoflurane and seven different types of carbon dioxide absorbent in a patient model.
PubMed: Alkali-metalated forms of thiacalix[4]arenes.
PubMed: Total synthesis of the hydroxyketone kurasoin A using asymmetric phase-transfer alkylation.
PubMed: Methanolysis as a route to gallium(III) clusters: synthesis and structural characterization of a decanuclear molecular wheel.
PubMed: The removal and recovery of Cr(VI) by Li/Al layered double hydroxide (LDH).
PubMed: Solid-state phase transition induced by pressure in LiOH x H2O.
PubMed: Infrared spectroscopy of the Li+(H2O)Ar complex: the role of internal energy and its dependence on ion preparation.
PubMed: A study of gas-phase cationization in matrix-assisted laser desorption/ionization time-of-flight mass spectrometry.
PubMed: N-sulfonyloxy carbamates as reoxidants for the tethered aminohydroxylation reaction.
PubMed: Lithium hydroxide phase transition under high pressure: an ab initio molecular dynamics study.
PubMed: Preparation of cadmium sulfide nanoparticles in self-reproducing reversed micelles.
PubMed: Dissolution nature of the lithium hydroxide by water molecules.
PubMed: Convenient synthesis of N-methylamino acids compatible with Fmoc solid-phase peptide synthesis.
PubMed: Carbon monoxide production from desflurane and six types of carbon dioxide absorbents in a patient model.
PubMed: Rapid dissolution of cellulose in LiOH/urea and NaOH/urea aqueous solutions.
PubMed: A novel versatile phosphoramidite building block for the synthesis of 5'- and 3'-hydrazide modified oligonucleotides.
PubMed: Synthesis of (-)-9,10-epi-stemoamide.
PubMed: Novel fragmentation reaction of 2-alkyl- and 2,4-dialkyl-3-iodo-1-oxocyclohexan-2,4-carbolactones.
PubMed: O-Protected 3-hydroxy-oxazolidin-2,4-diones: novel precursors in the synthesis of alpha-hydroxyhydroxamic acids.
PubMed: Lithium-catalyzed hydroxide attack at the carbon atom of methyl phosphate.
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PubMed: Synthesis and metal-ion binding properties of monoazathiacrown ethers.
PubMed: Only carbon dioxide absorbents free of both NaOH and KOH do not generate compound A during in vitro closed-system sevoflurane: evaluation of five absorbents.
PubMed: Retention behavior of transition metals on a bifunctional ion-exchange column with oxalic acid as eluent.
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PubMed: A multicomponent mobile phase for ion chromatography applied to the separation of anions from the residue of low explosives
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PubMed: Asymmetric Samarium-Reformatsky Reaction of Chiral alpha-Bromoacetyl-2-oxazolidinones with Aldehydes.
PubMed: [The use of lithium hydroxide for carbon dioxide absorption prevents formation of compound A during sevoflurane anesthesia].
PubMed: Formation of lithiated adducts of glycerophosphocholine lipids facilitates their identification by electrospray ionization tandem mass spectrometry.
PubMed: Separation of inorganic and organic anions by capillary zone electrophoresis with simultaneous indirect UV and conductivity detection.
PubMed: The structure of streptonigrin semiquinone in solution.
PubMed: Peak shape distortions in the capillary electrophoretic separations of strong electrolytes when the background electrolyte contains two strong electrolyte co-ions.
PubMed: Synthesis of 3 alpha- and 3 beta-dimers from selected bile acids.
PubMed: Synthesis of Protein Farnesyltransferase and Protein Geranylgeranyltransferase Inhibitors: Rapid Access to Chaetomellic Acid A and Its Analogues.
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PubMed: Solid-phase synthesis of a nucleopeptide from the linking site of adenovirus-2 nucleoprotein, -Ser(p5'CATCAT)-Gly-Asp-. Convergent versus stepwise strategy.
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PubMed: Possible alternatives to soda lime.
PubMed: Analysis of conjugated bile acids in human biological fluids. Synthesis of hyodeoxycholic acid 3- and 6-glycosides and related compounds.
PubMed: A comparison of gradient capacity anion chromatography using macrocycles D-2.2.2 and D-2.2.1 in constant or variable temperature mode.
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PubMed: The use of microwave oven for the rapid hydrolysis of bile acid methyl esters.
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PubMed: Lithium hydroxide/aqueous methanol: mild reagent for the hydrolysis of bile acid methyl esters.
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PubMed: Preparation of deuterium and tritium labelled norethynodrel, norethindrone, and 6-methyleneandrostenedione.
PubMed: [A polarographic method of determining the microlevels of furfural in the air of the work area].
PubMed: The carbohydrate chains of influenza virus hemagglutinin.
PubMed: Quantitation of hemoglobin with the Vision Analyzer by use of the alkaline hematin reaction.
PubMed: Acute inhalation toxicopathology of lithium combustion aerosols in rats.
PubMed: Inhalation toxicity of lithium combustion aerosols in rats.
PubMed: Dehydrohalogenation of atmospheric contaminants in the space cabin.
PubMed: Residence time and carbon dioxide scrubbing efficiency in life support systems.
PubMed: Effect of different alkalies, temperature, and hydrolysis times on tryptophan determination of pure proteins and of foods.
PubMed: Synthesis of glycopeptides containing the amino acid sequence 17-23 of bovine pancreatic deoxyribonuclease.
PubMed: [Improvement of fluorimetric estimation of delta 4-3-ketosteroids by means of lithium hydroxide reaction for analysis at the nanogram level (author's transl)].
PubMed: Coulometric titration of acids in isopropanol-II Electrode reactions with lithium chloride and tetraethylammonium bromide as supporting electrolytes.
PubMed: Lethal but non-pyrogenic products of endotoxin obtained after hydrolysis with lithium hydroxide.
PubMed: [Use of lithium hydroxide as an absorbent of carbon dioxide. Value in aviation and space flight].
PubMed: Linkage of carbohydrate to hydroxyamino acids in mucopolysaccharides and mucoproteins.
PubMed: [FLUOROMETRIC MICRODETERMINATION OF DELTA-4-3-KETOSTEROIDS WITH THE LITHIUM HYDROXIDE REACTION].
PubMed: STUDIES ON THE MUCIN DERIVED FROM HUMAN COLLOID BREAST CARCINOMA.
PubMed: [Demonstration and spectroscopic study of fluorescence chromogens of delta4-3-ketosteroids on lithium hydroxide molds].
PubMed: Taxonomically significant color reactions of Brevibacterium linens.
PubMed: [Obtaining lithium hydroxide by means of electrolysis of the lithium chloride solution].
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