EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

fosetyl-aluminium
phosphonic acid, monoethyl ester, aluminum salt (3:1)

Supplier Sponsors

CAS Number: 39148-24-8Picture of molecule3D/inchi
Other(deleted CASRN):1135443-39-8
ECHA EINECS - REACH Pre-Reg:254-320-2
FDA UNII: 3979UH4J7X
Nikkaji Web:J4.387G
MDL:MFCD00144376
Molecular Weight:351.08117460
Formula:C6 H15 Al O9 P3
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
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Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Appearance:white crystals (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Flash Point: 32.00 °F. TCC ( 0.00 °C. ) (est)
Soluble in:
 water, 1.20E+05 mg/L @ 20 °C (exp)
 water, 6.559e+005 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
Fosetyl-aluminum 95%
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-dog LDLo > 2140 mg/kg
Defense des Vegetaux. Vol. 33, Pg. 224, 1979.

oral-guinea pig LD50 2780 mg/kg
Proceedings-British Crop Protection Conference-Pests and Diseases. Vol. -, Pg. 565, 1977.

oral-mouse LD50 3700 mg/kg
Pesticide Manual. Vol. 9, Pg. 443, 1991.

oral-quail LD50 4997 mg/kg
Proceedings-British Crop Protection Conference-Pests and Diseases. Vol. -, Pg. 565, 1977.

oral-rabbit LD50 2680 mg/kg
Proceedings-British Crop Protection Conference-Pests and Diseases. Vol. -, Pg. 565, 1977.

intraperitoneal-rat LD50 550 mg/kg
Proceedings-British Crop Protection Conference-Pests and Diseases. Vol. -, Pg. 565, 1977.

oral-rat LD50 5000 mg/kg
Farm Chemicals Handbook. Vol. -, Pg. C147, 1991.

Dermal Toxicity:
skin-mouse LD > 3200 mg/kg
Proceedings-British Crop Protection Conference-Pests and Diseases. Vol. -, Pg. 565, 1977.

skin-rabbit LD50 > 2000 mg/kg
Farm Chemicals Handbook. Vol. -, Pg. C147, 1991.

skin-rat LD50 > 3200 mg/kg
Pesticide Manual. Vol. 9, Pg. 443, 1991.

Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
herbicides / pesticides
Recommendation for fosetyl-aluminium usage levels up to:
 not for fragrance use.
 
Recommendation for fosetyl-aluminium flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Statement on the dietary risk assessment for proposed temporary maximum residue levels (t-MRLs) for fosetyl-Al in certain crops
View page or View pdf

Retrospective analysis of the immunotoxic effects of plant protection products as reported in the Draft Assessment Reports for their peer review at EU level
View page or View pdf

Modification of the existing maximum residue level for fosetyl in blackberry, celeriac and Florence fennel
View page or View pdf

Modification of the existing maximum residue levels for fosetyl-Al in tree nuts, pome fruit, peach and potato
View page or View pdf

EPI System: View
EPA-Iris:IRIS
Chemical Carcinogenesis Research Information System:Search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :6328269
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
aluminum;ethoxy-oxido-oxophosphanium
Chemidplus:0039148248
RTECS:SZ9640000 for cas# 39148-24-8
 
References:
 aluminum;ethoxy-oxido-oxophosphanium
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):6328269
Pubchem (sid):135001064
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
CHEMBL:View
HMDB (The Human Metabolome Database):Search
ChemSpider:View
Wikipedia:View
Formulations/Preparations:
•mixed formulations: (fosetyl-aluminum +) folpet; mancozeb; captan + thiabendazole; bendiocarb + captan + thiabendazole. •'aliette', wettable powder (800 g fosetyl-aluminumkg). mixtures include: 'aliette extra', 'hy-cote', water dispersible powder for slurry treatment (fosetyl-aluminum + captan + thiabendazole); 'hy-tona', water dispersible powder for slurry treatment (300 g fosetyl-aluminum + 300 g bendiocarb + 100 g captan + 75 g thiabendazolekg); 'mikal', wettable powder (500 g fosetyl-aluminum + 250 g folpetkg). •water dispersable granule, wettable powder, liquid injectable •valiant (50% fosetyl al, 25% folpet, 4% cymoxanil); keeper triplo (32.5% fosetyl al, 26% mancozeb, 25% cymoxanil). •selected products: ...fosim; manaus; valete; vialphos; fosbel; fosetal; prudence; terronate. mixtures: altigan flash (+folpet); artimon (+mancozeb); elicio (+fenamidone); equation system (+famoxadone); impresario (+famoxadone); mildex (+fenamidone); rhodax express (+mancozeb); rhodax m (+mancozeb); sillage (+metiram); tertio (+cymoxanil+fenamidone). •discontinued products mixtures: carlit (+benalaxyl+mancozeb); chipco (+iprodione). •technical is > or = 95% pure.
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 aluminium triethyl triphosphonate
 aluminum triethyl triphosphonate
 aluminum tris(ethyl phosphite)
 aluminum tris(O-ethyl phosphonate)
 aluminum;ethoxy-oxido-oxophosphanium
 fosetyl-Al
 phosphonic acid monoethyl ester aluminum salt
 phosphonic acid, monoethyl ester, aluminum salt (3:1)
 

Articles:

PubMed:Rapid detection of pesticides not amenable to multi-residue methods by flow injection-tandem mass spectrometry.
PubMed:Fosetyl-Al photo-Fenton degradation and its endogenous catalyst inhibition.
PubMed:Effects of an innovative strategy to contain grapevine Bois noir: field treatment with resistance inducers.
PubMed:Persistence and dissipation of fluopicolide in/on grape berries and soil under semi arid tropical climatic conditions of India.
PubMed:[Determination of fosetyl-aluminium by ion-pair reversed phase-high performance liquid chromatography with evaporative light scattering detection].
PubMed:Reduction in bacterial ooze formation on immature fruitlets after preventive treatments of Fosethyl-Al against fire blight Erwinia amylovora.
PubMed:A new selective medium for the recovery and enumeration of Monilinia fructicola, M. fructigena, and M. laxa from stone fruits.
PubMed:Chemical control of downy mildew on lettuce and basil under greenhouse.
PubMed:Comparison of two vibrational procedures for the direct determination of mancozeb in agrochemicals.
PubMed:In vitro selection of an effective fungicide against Armillaria mellea and control of white root rot of grapevine in the field.
PubMed:Effect of dose rate and mixtures of fungicides on selection for QoI resistance in populations of Plasmopara viticola.
PubMed:Enhancement of natural disease resistance in potatoes by chemicals.
PubMed:Phosphorous acid residues in apples after foliar fertilization: results of field trials.
PubMed:Evaluation of fungicides for the control of carrot cavity spot.
PubMed:Responses of two ladybeetles to eight fungicides used in Florida citrus: implications for biological control.
PubMed:Effects of greenhouse pesticides on the soil-dwelling predatory mite Stratiolaelaps scimitus (Acari: Mesostigmata: Laelapidae) under laboratory conditions.
PubMed:Rapid determination of fosetyl-aluminum residues in lettuce by liquid chromatography/electrospray tandem mass spectrometry.
PubMed:The effect of foliar application of phosphonate formulations on the susceptibility of potato tubers to late blight.
PubMed:Effect of fosetyl-A1 on peroxidase from grapevine (Vitis vinifera) cells.
PubMed:Safety/risk assessment of pesticides: principles, procedures and examples.
PubMed:Evaluation of the carcinogenic potential of pesticides. 3. Aliette.
PubMed:Occupational exposure to fosetyl-Al fungicide during spraying of ornamentals in greenhouses.
 
Notes:
None found
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