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Category:herbicides / pesticides
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | white powder (est) |
| Assay: | 95.00 to 100.00
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| Food Chemicals Codex Listed: | No |
| Melting Point: | 143.00 °C. @ 760.00 mm Hg
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| Boiling Point: | 391.90 °C. @ 760.00 mm Hg (est)
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| Flash Point: | 375.00 °F. TCC ( 190.80 °C. ) (est)
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| logP (o/w): | 3.590 |
| Soluble in: |
| | water, 4.7 mg/L @ 25 °C (exp) | | | water, 10.51 mg/L @ 25 °C (est) |
Organoleptic Properties:
| Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-chicken LD50 > 3000 mg/kg
Pesticide Manual. Vol. 9, Pg. 665, 1991.
oral-dog LD50 > 4000 mg/kg
Pesticide Manual. Vol. 9, Pg. 665, 1991.
oral-guinea pig LD50 > 4000 mg/kg
Pesticide Manual. Vol. 9, Pg. 665, 1991.
unreported-mammal (species unspecified) LD50 3000 mg/kg
"Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 204, 1971.
oral-mouse LD50 > 8000 mg/kg
Pesticide Manual. Vol. 9, Pg. 665, 1991.
oral-rat LD50 4000 mg/kg
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 49(4), Pg. 16, 1984.
unreported-rat LD50 800 mg/kg
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 26(6), Pg. 21, 1982.
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| Dermal Toxicity: |
skin-rabbit LD50 10 mL/kg
"Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A319, Pg. 1983
skin-rat LD50 > 500 mg/kg
World Review of Pest Control. Vol. 9, Pg. 119, 1970.
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| Inhalation Toxicity: |
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Not determined
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Safety in Use Information:
| Category: | | herbicides / pesticides |
| Recommendation for phenmedipham usage levels up to: | | | not for fragrance use.
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| Recommendation for phenmedipham flavor usage levels up to: |
| | not for flavor use.
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Safety References:
European Food Safety Authority (EFSA) reference(s):
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Reasoned opinion on the modification of the existing MRL for phenmedipham in lettuce
View page or View pdf
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Reasoned opinion on the review of the existing maximum residue levels (MRLs) for phenmedipham according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf
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Peer review of the pesticide risk assessment of the active substance phenmedipham
View page or View pdf
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Modification of the existing maximum residue level for phenmedipham in strawberries
View page or View pdf
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Modification of the existing maximum residue level for phenmedipham in celeriac
View page or View pdf
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| EPI System: View |
| EPA-Iris:IRIS |
| Chemical Carcinogenesis Research Information System:Search |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA GENetic TOXicology:Search |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :24744 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:2 |
| [3-(methoxycarbonylamino)phenyl] N-(3-methylphenyl)carbamate |
| Chemidplus:0013684634 |
| EPA/NOAA CAMEO:hazardous materials |
| RTECS:FD9050000 for cas# 13684-63-4 |
References:
| | [3-(methoxycarbonylamino)phenyl] N-(3-methylphenyl)carbamate |
| NIST Chemistry WebBook: | Search Inchi |
| Pubchem (cid): | 24744 |
| Pubchem (sid): | 134990701 |
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | betanal | | | carbanilic acid, m-hydroxy-, methyl ester, m-methylcarbanilate | | | carbanilic acid, m-hydroxy, methyl ester, m-methylcarbanilate (ester) | | 3-( | carbomethoxyamino)phenyl 3-methylcarbanilate | | | fenmedifam | | m- | hydroxycarbanilic acid methyl ester m-methylcarbanilate | | | kemifam | | 3-(( | methoxycarbonyl)amino)phenyl (3-methylphenyl)carbamate | | 3- | methoxycarbonylaminophenyl 3'-methylcarbanilate | | 3- | methoxycarbonylaminophenyl N-3'-methylphenylcarbamate | | | methyl 3-(3-methylcarbaniloyloxy)carbanilate | | | methyl 3-(m-tolylcarbamoyloxy)phenylcarbamate | | | methyl m-hydroxycarbanilate m-methylcarbanilate (ester) (8CI) | | | methyl m-hydroxycarbanilate, m-methylcarbanilate | | | methyl N-(3-(N-(3-methylphenyl)carbamoyloxy)phenyl)carbamate | | | methyl-3-hydroxycarbanilate-3-methylcarbanilate | | | methyl-3-m-tolycarbamoloxyphenyl carbamate | | 3-( | methylphenyl)carbamic acid 3-((methoxycarbonyl)amino)phenyl ester | | | morton EP 452 | | | phenmediphame | | | schering 4072 | | | schering-38584 | | | synbetan P |
Articles:
| PubMed:Differential gene expression analysis in Enchytraeus albidus exposed to natural and chemical stressors at different exposure periods. |
| PubMed:Acute and chronic toxicity of Betanal(®)Expert and its active ingredients on nontarget aquatic organisms from different trophic levels. |
| PubMed:Development of a microarray for Enchytraeus albidus (Oligochaeta): preliminary tool with diverse applications. |
| PubMed:Biochemical characterization of cholinesterases in Enchytraeus albidus and assessment of in vivo and in vitro effects of different soil properties, copper and phenmedipham. |
| PubMed:Can avoidance in Enchytraeus albidus be used as a screening parameter for pesticides testing? |
| PubMed:Mining biologically-active molecules for inhibitors of fatty acid amide hydrolase (FAAH): identification of phenmedipham and amperozide as FAAH inhibitors. |
| PubMed:Effects of natural and chemical stressors on Enchytraeus albidus: can oxidative stress parameters be used as fast screening tools for the assessment of different stress impacts in soils? |
| PubMed:Analysis of carbamate pesticides in water samples using single-drop microextraction and gas chromatography-mass spectrometry. |
| PubMed:Avoidance test with Enchytraeus albidus (Enchytraeidae): effects of different exposure time and soil properties. |
| PubMed:Enchytraeus albidus (Enchytraeidae): a test organism in a standardised avoidance test? Effects of different chemical substances. |
| PubMed:Selected stormwater priority pollutants: a European perspective. |
| PubMed:Monitoring the efficacy and metabolism of phenylcarbamates in sugar beet and black nightshade by chlorophyll fluorescence parameters. |
| PubMed:Use of growth regulator of cytokinin type for enhancement and modification of herbicide activity. |
| PubMed:Comparison of different sorbents for multiresidue solid-phase extraction of 16 pesticides from groundwater coupled with high-performance liquid chromatography. |
| PubMed:Effect of tank mixed adjuvants on the drift potential of phenmedipham formulations. |
| PubMed:Fate of the herbicides glyphosate, glufosinate-ammonium, phenmedipham, ethofumesate and metamitron in two Finnish arable soils. |
| PubMed:[Analysis of phenmedipham in agricultural products by HPLC]. |
| PubMed:Effects of the benzoxazoid DIMBOA, selected degradation products, and structure-related pesticides on soil organisms. |
| PubMed:Drift of 10 herbicides after tractor spray application. 1. Secondary drift (evaporation). |
| PubMed:Effect of different soil types on the enchytraeids Enchytraeus albidus and Enchytraeus luxuriosus using the herbicide Phenmedipham. |
| PubMed:Effects of different soil types on the Collembolans Folsomia candida and Hypogastrura assimilis using the herbicide Phenmedipham. |
| PubMed:Avoidance behaviour of Enchytraeus albidus: effects of benomyl, carbendazim, phenmedipham and different soil types. |
| PubMed:Evaluation of herbicide combinations for livid amaranth (Amaranthus blitum) control in tuberous begonia (Begonia x tuberhybrida). |
| PubMed:Adsorption of sugar beet herbicides to Finnish soils. |
| PubMed:The influence of lipophilicity and formulation on the distribution of pesticides in laboratory-scale sediment/water systems. |
| PubMed:Ethoxylated rapeseed oil derivatives as novel adjuvants for herbicides. |
| PubMed:Liquid chromatographic/mass spectrometric determination of desmedipham and phenmedipham and their metabolites in soil. |
| PubMed:Biological monitoring of phenmedipham: determination of m-toluidine in urine. |
| PubMed:Soil thin-layer chromatography and pesticide mobility through soil microstructures. New technical approach. |
| PubMed:Automated determination of phenylcarbamate herbicides in environmental waters by on-line trace enrichment and reversed-phase liquid chromatography-diode array detection. |
| PubMed:A methodological approach to the application of a vermiculite modified carbon paste electrode in interaction studies: Influence of some pesticides on the uptake of Cu(II) from a solution to the solid phase. |
| PubMed:Expression of a bacterial gene in transgenic plants confers resistance to the herbicide phenmedipham. |
| PubMed:Purification and properties of an Arthrobacter oxydans P52 carbamate hydrolase specific for the herbicide phenmedipham and nucleotide sequence of the corresponding gene. |
| PubMed:Comparison of sublethal and lethal criteria for nine different chemicals in standardized toxicity tests using the earthworm Eisenia andrei. |
| PubMed:[Evaluation of the effectiveness of vitamin and amino acid mixtures for increasing body resistance to pesticides in experimental studies]. |
| PubMed:[Photoallergic dermatitis caused by the herbicide phenmedipham]. |
| PubMed:Analysis of herbicide residues in sugar beet and sugar. |
| PubMed:[Epicutaneous testing with plant protective and pest control agents (pesticides)]. |
| PubMed:[Basis for the maximum permissible exposure level of betanale taking into account its toxicologic hazardousness level]. |
| PubMed:[The effect of pesticides on the protozoan Tetrahymena pyriformis]. |
| PubMed:[Potential hazardousness of the embryotoxic action of the herbicide betanal (experimental data)]. |
| PubMed:[In vivo and in vitro actions of biscarbamates on the photosynthetic activity of chloroplasts]. |
| PubMed:Microbial degradation of the carbamate pesticides desmedipham, phenmedipham, promecarb, and propamocarb. |
| PubMed:[Herbicide residues in some herbs (author's transl)]. |
| PubMed:Herbicidal treatments for control of Papaver somniferum L. |
| PubMed:[Experience in the field of gas chromatographic herbicide residue analysis illustrated by using phenmedipham and fenuron as examples]. |
| PubMed:Allergic contact dermatitis from Betanal (phenmedipham). |
| PubMed:Relationship between inhibitor binding by chloroplasts and inhibition of photosynthetic electron transport. |
| PubMed:Herbicidal treatments for control of Cannabis sativa L. |
| PubMed:[Radiometric determination of 11 carbamate pesticides in the nanogram and subnanongram ranges by means of cholinesterase inhibition]. |
| PubMed:[Determination of residual quantities of betanal (phenmedipham) in sugar beets]. |
| PubMed:Phenmedipham and m-aminophenol decomposition in alkaline soil. |
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3D/inchi