EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes

trimethylolpropane trimethacrylate
methacrylic acid, triester with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol (8CI)

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Name:2,2-bis(2-methylprop-2-enoyloxymethyl)butyl 2-methylprop-2-enoate
CAS Number: 3290-92-4Picture of molecule3D/inchi
Other(deleted CASRN):102068-89-3
ECHA EINECS - REACH Pre-Reg:221-950-4
Nikkaji Web:J64.284C
Beilstein Number:5961805
XlogP3-AA:3.80 (est)
Molecular Weight:338.40042000
Formula:C18 H26 O6
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:film forming agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
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Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
DG SANTE Food Contact Materials:1,1,1-trimethylolpropane trimethacrylate
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:1.06400 to 1.06900 @ 20.00 °C.
Pounds per Gallon - (est).: 8.864 to 8.906
Refractive Index:1.47100 to 1.47500 @ 20.00 °C.
Boiling Point: 422.10 °C. @ 760.00 mm Hg (est)
Flash Point:> 230.00 °F. TCC ( > 110.00 °C. )
logP (o/w): 4.390
Soluble in:
 water, 13 mg/L @ 25 °C (exp)
 water, 1.297 mg/L @ 25 °C (est)
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: film formers
BOC Sciences
For experimental / research use only.
Trihydroxymethylpropyl trimethylacrylate 95%
Santa Cruz Biotechnology
For experimental / research use only.
Trimethylolpropane trimethacrylate
Sigma-Aldrich: Aldrich
For experimental / research use only.
Trimethylolpropane trimethacrylate
For experimental / research use only.
Trimethylolpropane Trimethacrylate (stabilized with MEHQ) >90.0%(GC)
Safety Information:
Preferred SDS: View
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
intraperitoneal-mouse LD50 2889 mg/kg
Journal of Dental Research. Vol. 51, Pg. 526, 1972.

intraperitoneal-rat LD50 3100 mg/kg
National Technical Information Service. Vol. OTS0571319

oral-rat LD50 5660 uL/kg
Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.

Dermal Toxicity:
skin-rabbit LD50 16 mL/kg
Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.

Inhalation Toxicity:
Not determined
Safety in Use Information:
film forming agents
Recommendation for trimethylolpropane trimethacrylate usage levels up to:
 not for fragrance use.
Recommendation for trimethylolpropane trimethacrylate flavor usage levels up to:
 not for flavor use.
Safety References:
EPI System: View
Chemical Carcinogenesis Research Information System:Search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):3290-92-4
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :18689
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
2,2-bis(2-methylprop-2-enoyloxymethyl)butyl 2-methylprop-2-enoate
RTECS:TY6675000 for cas# 3290-92-4
 2,2-bis(2-methylprop-2-enoyloxymethyl)butyl 2-methylprop-2-enoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:3290-92-4
Pubchem (cid):18689
Pubchem (sid):134983596
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Indirect Additives used in Food Contact Substances:View
KEGG (GenomeNet):C14538
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2918.99.5000
Potential Blenders and core components note
None Found
Potential Uses:
None Found
Occurrence (nature, food, other):note
 not found in nature
 blemmer PTT
2-ethyl-2-((methacryloyloxy)methyl)propane-1,3-diyl bis(2-methylacrylate)
2-ethyl-2-(hydroxymethyl)-1,3-propanediol trimethacrylate
2,2-bis(hydroxymethyl)butanol trimethacrylate
 methacrylic acid, 1,1,1-trihydroxymethyl propane triester
 methacrylic acid, triester with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol
 methacrylic acid, triester with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol (8CI)
2,2-bis[(methacryloyloxy)methyl]butyl methacrylate
2,2-bis(methacryloyloxymethyl)butyl methacrylate
2,2-bis{[(2-methylacryloyl)oxy]methyl}butyl 2-methylprop-2-enoate
2,2-bis[(2-methylprop-2-enoyloxy)methyl]butyl 2-methylprop-2-enoate
2,2-bis(2-methylprop-2-enoyloxymethyl)butyl 2-methylprop-2-enoate
1,3-propanediol, 2-ethyl-2-(hydroxymethyl)-, trimethacrylate
1,3-propanediol, 2-ethyl-2-hydroxymethyl-, trimethacrylate
2-propenoic acid, 2-methyl-, 2,2-bis[[(2-methyl-1-oxo-2-propen-1-yl)oxy]methyl]butyl ester
2-propenoic acid, 2-methyl-, 2-ethyl-2-(((2-methyl-1-oxo-2-propenyl)oxy)methyl)-1,3-propanediyl ester
2-propenoic acid, 2-methyl-, 2-ethyl-2-[[(2-methyl-1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester
 trimethylol propane trimethacrylate
1,1,1-trimethylolpropane trimethacrylate
 trimethylolpropane trimethancrylate


PubMed:Biomimetic piezoelectric quartz crystal sensor with chloramphenicol-imprinted polymer sensing layer.
PubMed:Molecularly imprinted polymer beads for clean-up and preconcentration of β-lactamase-resistant penicillins in milk.
PubMed:Robust naphthyl methacrylate monolithic column for high performance liquid chromatography of a wide range of solutes.
PubMed:Influence of the filler on thermal properties of porous VP-TRIM copolymers.
PubMed:Experimental mixture design as a tool for the synthesis of antimicrobial selective molecularly imprinted monodisperse microbeads.
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PubMed:Monolithic molecularly imprinted polymeric capillary columns for isolation of aflatoxins.
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PubMed:Molecularly imprinted polymer nanocarriers for sustained release of erythromycin.
PubMed:Preparation of Monolithic Capillary Chromatographic Columns Using Supercritical Fluid as a Porogen Solvent.
PubMed:Selective and simultaneous determination of trace bisphenol A and tebuconazole in vegetable and juice samples by membrane-based molecularly imprinted solid-phase extraction and HPLC.
PubMed:Development of sustained antimicrobial-release systems using poly(2-hydroxyethyl methacrylate)/trimethylolpropane trimethacrylate hydrogels.
PubMed:On the influence of crosslinker on template complexation in molecularly imprinted polymers: a computational study of prepolymerization mixture events with correlations to template-polymer recognition behavior and NMR spectroscopic studies.
PubMed:A new method of evaluation of fracture patterns following microtensile bond strength testing using polarized light microscopy.
PubMed:[Preparation of nicosulfuron molecularly imprinted microspheres and research of adsorption characteristics].
PubMed:Extraction of quercetin from Herba Lysimachiae by molecularly imprinted-matrix solid phase dispersion.
PubMed:Molecularly imprinted polymer microspheres containing photoswitchable spiropyran-based binding sites.
PubMed:Preparation of doxycycline-imprinted magnetic microspheres by inverse-emulsion suspension polymerization for magnetic dispersion extraction of tetracyclines from milk samples.
PubMed:Polymer monolithic capillary microextraction combined on-line with inductively coupled plasma MS for the determination of trace rare earth elements in biological samples.
PubMed:A facile approach for preparation of molecularly imprinted polymers layer on the surface of carbon nanotubes.
PubMed:Preparation of an amperometric sensor for norfloxacin based on molecularly imprinted grafting photopolymerization.
PubMed:Construction of a novel macroporous imprinted biosensor based on quartz crystal microbalance for ribonuclease A detection.
PubMed:Optimization of human serum albumin monoliths for chiral separations and high-performance affinity chromatography.
PubMed:Preparation and characterization of grafted imprinted monolith for capillary electrochromatography.
PubMed:Non-chromatographic mercury speciation and determination in wine by new core-shell ion-imprinted sorbents.
PubMed:Synthesis and evaluation of uniformly sized nalidixic acid-imprinted nanospheres based on precipitation polymerization method for analytical and biomedical applications.
PubMed:Rational design of molecularly imprinted polymer: the choice of cross-linker.
PubMed:Controlled synthesis of bulk polymer nanocomposites with tunable second order nonlinear optical properties.
PubMed:Modification and characterization of biodegradable methylcellulose films with trimethylolpropane trimethacrylate (TMPTMA) by γ radiation: effect of nanocrystalline cellulose.
PubMed:[Microchip-based reversed-phase liquid chromatography-tandem mass spectrometry platform for protein analysis].
PubMed:Photo-crosslinkable cyanoacrylate bioadhesive: shrinkage kinetics, dynamic mechanical properties, and biocompatibility of adhesives containing TMPTMA and POSS nanostructures as crosslinking agents.
PubMed:Properties of indirect composites reinforced with monomer-impregnated glass fiber.
PubMed:Microshear bond strength and interfacial morphology of etch-and-rinse and self-etch adhesive systems to superficial and deep dentin.
PubMed:Molecularly imprinted polymer grafted to porous polyethylene frits: a new selective solid-phase extraction format.
PubMed:Mixed ligand monolithic columns for reversed-phase capillary electrochromatography via hydrophobic and π interactions.
PubMed:[Spectroscopy study of binding mechanisms and molecular recognition of class-specific molecularly imprinted polymer beads].
PubMed:QSRR analysis of β-lactam antibiotics on a penicillin G targeted MIP stationary phase.
PubMed:Naphthyl methacrylate-phenylene diacrylate-based monolithic column for reversed-phase capillary electrochromatography via hydrophobic and π interactions.
PubMed:A novel, neutral hydroxylated octadecyl acrylate monolith with fast electroosmotic flow velocity and its application to the separation of various solutes including peptides and proteins in the absence of electrostatic interactions.
PubMed:Capillary electrophoresis characterization of molecularly imprinted polymer particles in fast binding with 17β-estradiol.
PubMed:Class-specific molecularly imprinted polymers for the selective extraction and determination of sulfonylurea herbicides in maize samples by high-performance liquid chromatography-tandem mass spectrometry.
PubMed:Feedback regulated drug delivery vehicles: carbon dioxide responsive cationic hydrogels for antidote release.
PubMed:pCEC coupling with ESI-MS for the analysis of beta(2)-agonists and narcotics using a poly-(1-hexadecene-co-TMPTMA) monolithic column.
PubMed:[Preparation of bovine serum albumin immobilized adsorbent for specific adsorption of bilirubin].
PubMed:Development of a molecularly imprinted polymer for selective extraction of bisphenol A in water samples.
PubMed:Preparation of polyamine-functionalized copper specific adsorbents for selective adsorption of copper.
PubMed:Synthesis of a novel camphorquinone derivative having acylphosphine oxide group, characterization by UV-VIS spectroscopy and evaluation of photopolymerization performance.
PubMed:Molecularly imprinted polymer/cryogel composites for solid-phase extraction of bisphenol A from river water and wine.
PubMed:Preparation and evaluation of a contact lens vehicle for puerarin delivery.
PubMed:Preparation and evaluation of the highly cross-linked poly(1-hexadecane-co-trimethylolpropane trimethacrylate) monolithic column for capillary electrochromatography.
PubMed:Macroradical initiated polymerisation of acrylic and methacrylic monomers.
PubMed:Molecularly imprinted solid-phase extraction of fumonisin B analogues in bell pepper, rice and corn flakes.
PubMed:Cyclodextrin-containing hydrogels for contact lenses as a platform for drug incorporation and release.
PubMed:Migration of bacteria through a monolith.
PubMed:Electrochemical formation of stable p-i-n junction in conjugated polymer thin films.
PubMed:Magnetic molecularly imprinted polymer for aspirin recognition and controlled release.
PubMed:Isolation and detection of steroids from human urine by molecularly imprinted solid-phase extraction and liquid chromatography.
PubMed:Effect of filler type and polishing on the discoloration of composite resin artificial teeth.
PubMed:Ion-imprinted polymethacrylic microbeads as new sorbent for preconcentration and speciation of mercury.
PubMed:Neutral polar methacrylate-based monoliths for normal phase nano-LC and CEC of polar species including N-glycans.
PubMed:A facile route to bulk high-Z polymer composites for gamma ray scintillation.
PubMed:Analysis of recognition of fructose by imprinted polymers.
PubMed:Anti-Her-2 monoclonal antibody conjugated polymer fluorescent nanoparticles probe for ovarian cancer imaging.
PubMed:Neutral octadecyl monolith for reversed phase capillary electrochromatography of a wide range of solutes.
PubMed:Development of new bone cement utilizing low toxicity monomers.
PubMed:Effect of the template and functional monomer on the textural properties of molecularly imprinted polymers.
PubMed:Preparation of molecularly imprinted solid phase extraction using bensulfuron-methyl imprinted polymer and clean-up for the sulfonylurea-herbicides in soybean.
PubMed:New biomedical devices with selective peptide recognition properties. Part 1: Characterization and cytotoxicity of molecularly imprinted polymers.
PubMed:Selective removal of copper and lead ions by diethylenetriamine-functionalized adsorbent: behaviors and mechanisms.
PubMed:In situ synthesis of molecularly imprinted polymers on glass microspheres in a column.
PubMed:Development of fructosyl valine binding polymers by covalent imprinting.
PubMed:Solid phase selective separation and preconcentration of Cu(II) by Cu(II)-imprinted polymethacrylic microbeads.
PubMed:Molecularly imprinted polymer films for reflectometric interference spectroscopic sensors.
PubMed:Fabrication and characterization of rigid magnetic monodisperse microspheres for protein adsorption.
PubMed:Selective molecularly imprinted polymer obtained from a combinatorial library for the extraction of bisphenol A.
PubMed:Quantification of organic eluates from polymerized resin-based dental restorative materials by use of GC/MS.
PubMed:Nanoparticle-based continuous full filling capillary electrochromatography/electrospray ionization-mass spectrometry for separation of neutral compounds.
PubMed:Development and evaluation of spherical molecularly imprinted polymer beads.
PubMed:Final report of the safety assessment of methacrylate ester monomers used in nail enhancement products.
PubMed:Molecular engineering of fluorescent penicillins for molecularly imprinted polymer assays.
PubMed:Synthesis and characterization of peptide grafted porous polymer microstructures.
PubMed:Selective extraction of organophosphorus nerve agent degradation products by molecularly imprinted solid-phase extraction.
PubMed:Interactions of bupivacaine with a molecularly imprinted polymer in a monolithic format studied by NMR.
PubMed:Molecularly imprinted polymers grafted to flow through poly(trimethylolpropane trimethacrylate) monoliths for capillary-based solid-phase extraction.
PubMed:Using paramagnetic particles as repulsive templates for the preparation of membranes of controlled porosity.
PubMed:Light-directed movement of polymer microstructures.
PubMed:Control of particle assisted wetting by an external magnetic field.
PubMed:Effects of filler composition on flexibility of microfilled resin composite.
PubMed:Affinity depletion of albumin from human cerebrospinal fluid using Cibacron-blue-3G-A-derivatized photopatterned copolymer in a microfluidic device.
PubMed:Methacrylates in dental restorative materials.
PubMed:Determination of albumin concentration by MIP-QCM sensor.
PubMed:A chemiluminescence flow immunosensor based on a porous monolithic metacrylate and polyethylene composite disc modified with protein G.
PubMed:[Molecularly imprinted polymeric microspheres prepared by seed swelling and suspension polymerization].
PubMed:Synthesis and screening of a molecularly imprinted polymer library targeted for penicillin G.
PubMed:Nanoparticles as pseudostationary phase in capillary electrochromatography/ESI-MS.
PubMed:Capillary LC-MS2 at the attomole level for monitoring and discovering endogenous peptides in microdialysis samples collected in vivo.
PubMed:Semipreparative capillary electrochromatography.
PubMed:Strength of relined denture base polymers subjected to long-term water immersion.
PubMed:Influence of mobile phase composition and cross-linking density on the enantiomeric recognition properties of molecularly imprinted polymers.
PubMed:Imprinted polymers as tools for the recovery of secondary metabolites produced by fermentation
PubMed:Beaded reactive polymers. 3. Effect of triacrylates as crosslinkers on the physical properties of glycidyl methacrylate copolymers and immobilization of penicillin G acylase.
PubMed:Magnetic molecularly imprinted polymer beads for drug radioligand binding assay.
PubMed:Effect of resin monomer composition on toothbrush wear resistance.
PubMed:Preparation of an effective light-cured bonding agent for orthodontic application.
PubMed:Chiral recognition in adrenergic receptor binding mimics prepared by molecular imprinting.
PubMed:The effects of cross-linking agents on the water sorption and solubility characteristics of denture base resin.
PubMed:Photopolymerized multifunctional (meth)acrylates as model polymers for dental applications.
PubMed:Effect of light-exposure duration on the amount of leachable monomers from light-activated reline material.
PubMed:Review: Selective ligand-exchange adsorbents prepared by template polymerization.
PubMed:A new copolymerized composite resin system: a multiphased evaluation.
PubMed:The effects of cross-linking agents on some properties of HEMA-based resins.
PubMed:Laboratory evaluation of experimental restorative systems containing 4-META.
PubMed:An in vitro evaluation of a copolymerizable type of microfilled composite resin.
PubMed:In vitro and in vivo behaviour of narciclasine released from matrices based on poly (2-hydroxyethyl methacrylate).
PubMed:Genotoxicity of multifunctional acrylates in the Salmonella/mammalian-microsome assay and mouse lymphoma TK+/-assay.
PubMed:Immobilization of fatty acid synthetase from Mycobacterium smegmatis by radiation-induced polymerization.
PubMed:Analysis of the genotoxicity of nine acrylate/methacrylate compounds in L5178Y mouse lymphoma cells.
PubMed:[The effect of composition on the mechanical properties of composite resin].
PubMed:[Fundamental study on photocured resin for crown and bridge].
PubMed:Radiation-induced polymerization for the immobilization of penicillin acylase.
PubMed:Immunogenicity of acrylate chemicals as assessed by antibody induction.
PubMed:The evaluation of new dental resins prepared with polyfunctional methacrylate monomers.
PubMed:Trimethylolpropane trimethacrylate.
PubMed:[Preparation of hard crown and bridge resin without PMMA powder (III) (author's transl)].
PubMed:Allergenicity of trimethylol propane triacrylate in ultraviolet curing inks in the guinea pig.
PubMed:[Effect of cross-linking agents on mechanical properties of a fluid resin (author's transl)].
acrylate derivative found in ultraviolet curing inks.
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