EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

pivaloyl chloride
propanoyl chloride, 2,2-dimethyl-

Supplier Sponsors

Name:2,2-dimethylpropanoyl chloride
CAS Number: 3282-30-2Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:221-921-6
FDA UNII: JQ82J0O21T
Nikkaji Web:J33.810I
Beilstein Number:385668
MDL:MFCD00000709
XlogP3-AA:2.20 (est)
Molecular Weight:120.57793000
Formula:C5 H9 Cl O
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:pharmaceuticals / chemical synthisis
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.97900 @ 25.00 °C.
Refractive Index:1.41200 @ 20.00 °C.
Boiling Point: 107.00 °C. @ 760.00 mm Hg
Vapor Pressure:27.400000 mmHg @ 25.00 °C. (est)
Flash Point: 48.00 °F. TCC ( 8.89 °C. )
logP (o/w): 1.680 (est)
Soluble in:
 water, 1.735e+004 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BASF
Pivaloyl chloride
Charkit Chemical
PIVALOYL CHLORIDE
EMD Millipore
For experimental / research use only.
Pivaloyl Chloride
sds
Sigma-Aldrich: Aldrich
For experimental / research use only.
Trimethylacetyl chloride 99%
sds
TCI AMERICA
For experimental / research use only.
Pivaloyl Chloride >98.0%(T)
sds
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
pharmaceuticals / chemical synthisis
Recommendation for pivaloyl chloride usage levels up to:
 not for fragrance use.
 
Recommendation for pivaloyl chloride flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):3282-30-2
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :62493
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:1
2,2-dimethylpropanoyl chloride
Chemidplus:0003282302
EPA/NOAA CAMEO:hazardous materials
RTECS:AO7200000 for cas# 3282-30-2
 
References:
 2,2-dimethylpropanoyl chloride
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):62493
Pubchem (sid):135019745
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEMBL:View
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2915.90.5000
ChemSpider:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
2,2-dimethyl-propionyl chloride
2,2-dimethylpropanoyl chloride
2,2-dimethylpropionyl chloride
 pivalyl chloride
 propanoyl chloride, 2,2-dimethyl-
 trimethyl acetyl chloride
 trimethylacetyl chloride
 trimethylacetylchloride
 

Articles:

PubMed:Rapid acyl migration between pyrogallyl 1,2- and 1,3-dipivaloates.
PubMed:Ex situ generation of stoichiometric and substoichiometric 12CO and 13CO and its efficient incorporation in palladium catalyzed aminocarbonylations.
PubMed:Stereochemistry of internucleotide bond formation by the H-phosphonate method. 5. The role of Brønsted and H-bonding base catalysis in ribonucleoside H-phosphonate condensation-chemical and stereochemical consequences.
PubMed:Synthesis and structural investigation of N-acyl selenophosphoramides.
PubMed:O-Pivaloyl diphenyl-seleno-phosphinate.
PubMed:6-Coordinate tungsten(VI) tris-n-isopropylanilide complexes: products of terminal oxo and nitrido transformations effected by main group electrophiles.
PubMed:Boronated protohaemins: synthesis and in vivo antitumour efficacy.
PubMed:Oxonitriles: a grignard addition-acylation route to enamides.
PubMed:Formation of surface-bound acyl groups by reaction of acyl halides on ge(100)-2x1.
PubMed:Preparation of nucleoside H-phosphonoselenoate monoesters via the phosphinate approach.
PubMed:Organic nitriles from acid chlorides: an isovalent N for (O)CL exchange reaction mediated by a tungsten nitride complex.
PubMed:4'-pivaloyl substituted thymidine as a precursor for the thymyl radical: an EPR spectroscopic study.
PubMed:Side reactions in the H-phosphonate approach to oligonucleotide synthesis: a kinetic investigation on bisacylphosphite formation and 5'-O-acylation.
PubMed:Synthesis, intramolecular migrations and enzymic hydrolysis of partially pivaloylated methyl alpha-D-mannopyranosides.
PubMed:Analysis of isomeric long-chain hydroxy fatty acids by tandem mass spectrometry: application to the diagnosis of long-chain 3-hydroxyacyl CoA dehydrogenase deficiency.
PubMed:Regioselective Acylation of Hexopyranosides with Pivaloyl Chloride.
PubMed:Syntheses of anomerically phosphodiester-linked oligomers of the repeating units of the Haemophilus influenzae types c and f capsular polysaccharides.
PubMed:Generation of N-acylpyridinium ions from pivaloyl chloride and pyridine derivatives by means of silyl triflates
PubMed:Unexpected dipivaloylation of 9-lithiated fluorene: formation of 1-(fluoren-9-ylidene)-2,2-dimethylpropyl pivalate.
PubMed:Cross-linking of starch with bifunctional precursors of nitroalkenes.
PubMed:Selective pivaloylation and diphenylacetylation of cyclomalto-oligosaccharides.
PubMed:5'-Hydrogenphosphonates of anti-HIV nucleoside analogues revisited: controversial mode of action.
PubMed:[Synthesis of new pyrimidine 5'-H-thiophosphonates].
PubMed:A facile method for preparation of t-butyloxycarbonylamino acid p-nitroanilides.
PubMed:[N-phosphonate synthesis of oligodeoxyribonucleotides with the use of a p-nitrophenylethyl blocking group].
PubMed:[Synthesis of 5'-phosphorylated oligodeoxyribonucleotides by the H-phosphonate method].
PubMed:Selective pivaloylation of 2-acetamido-2-deoxy sugars.
PubMed:The preparation and application of functionalised synthetic oligonucleotides: III. Use of H-phosphonate derivatives of protected amino-hexanol and mercapto-propanol or -hexanol.
PubMed:[Synthesis of oligoribonucleotides via ribonucleoside-H-phosphonates].
PubMed:A model study directed towards the preparation of nucleopeptides via H-phosphonate intermediates.
PubMed:Studies on biologically active nucleosides and nucleotides. 5. Synthesis and antitumor activity of some 2,2'-anhydro-1-(3',5'-di-O-acyl-beta-D-arabinofuranosyl)cytosine salts and 2,2'-anhydro-1-(3'-O-acyl-beta-D-arabinofuranoxyl)cytosine 5'-phosphates.
PubMed:Synthesis and pharmacological screening of certain N-substituted amides structurally related to some local anesthetics.
 
Notes:
None found
Please share your Comments.
Email Address:
Top of Page Home
Copyright © 1980-2021 The Good Scents Company (tgsc) ™ Disclaimer Privacy Policy