EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

tert-butyl acrylate
acrylic acid, tert-butyl ester

Supplier Sponsors

CAS Number: 1663-39-4Picture of molecule3D/inchi
Other(deleted CASRN):782475-36-9
ECHA EINECS - REACH Pre-Reg:216-768-7
FDA UNII: 92M2CD1O3G
Nikkaji Web:J82.107A
Beilstein Number:1742329
MDL:MFCD00008809
XlogP3-AA:1.70 (est)
Molecular Weight:128.17104000
Formula:C7 H12 O2
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:indirect food additives: adhesives and components of coatings
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
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DG SANTE Food Contact Materials:acrylic acid, tert-butyl ester
FDA Mainterm (IAUFC):1663-39-4 ; TERT-BUTYL ACRYLATE
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.87500 @ 25.00 °C.
Boiling Point: 133.01 °C. @ 760.00 mm Hg (est)
Vapor Pressure:8.637000 mmHg @ 25.00 °C. (est)
Flash Point: 63.00 °F. TCC ( 17.22 °C. )
logP (o/w): 2.062 (est)
Soluble in:
 water, 1534 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BASF
tert-Butyl Acrylate
Santa Cruz Biotechnology
For experimental / research use only.
tert-Butyl Acrylate 99%, stabilized with 15ppm 4-methoxyphenol
Sigma-Aldrich: Aldrich
For experimental / research use only.
tert-Butyl Acrylate 98%
contains 10-20 ppm monomethyl ether hydroquinone as inhibitor
TCI AMERICA
For experimental / research use only.
tert-Butyl Acrylate (stabilized with MEHQ) >98.0%(GC)
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
indirect food additives: adhesives and components of coatings
Recommendation for tert-butyl acrylate usage levels up to:
 not for fragrance use.
 
Recommendation for tert-butyl acrylate flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
Chemical Carcinogenesis Research Information System:Search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):1663-39-4
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :15458
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
tert-butyl prop-2-enoate
Chemidplus:0001663394
 
References:
 tert-butyl prop-2-enoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:1663-39-4
Pubchem (cid):15458
Pubchem (sid):134980702
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Indirect Additives used in Food Contact Substances:View
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2916.12.5030
ChemSpider:View
Formulations/Preparations:
commercial grade contains 100 ppm hydroquinone monomethyl ether as stabilizer.
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 acrylic acid t-butyl ester
 acrylic acid tert-butyl ester
 acrylic acid, tert-butyl ester
 acrylic acid, tert-butyl ester (8CI)
t-butyl acrylate
tert-butyl prop-2-enoate
tert-butyl propenoate
2-methyl-2-propanyl acrylate
2-propenoic acid, 1,1-dimethylethyl ester
 

Articles:

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PubMed:High-speed atomic force microscope imaging: adaptive multiloop mode.
PubMed:Toward pH-responsive coating materials--high-throughput study of (meth)acrylic copolymers.
PubMed:Micro and macrorheology at fluid-fluid interfaces.
PubMed:Rapid and quantitative detection of prostate specific antigen with a quantum dot nanobeads-based immunochromatography test strip.
PubMed:Antimicrobial activity of poly(acrylic acid) block copolymers.
PubMed:Monolithic silica rods grafted with thermoresponsive anionic polymer brushes for high-speed separation of basic biomolecules and peptides.
PubMed:Copper(II)/tertiary amine synergy in photoinduced living radical polymerization: accelerated synthesis of ω-functional and α,ω-heterofunctional poly(acrylates).
PubMed:Synthetic scope and DFT analysis of the chiral binap-gold(I) complex-catalyzed 1,3-dipolar cycloaddition of azlactones with alkenes.
PubMed:Divergent dendrimer synthesis via the Passerini three-component reaction and olefin cross-metathesis.
PubMed:Revival of the R-group approach: a "CTA-shuttled" grafting from approach for well-defined cylindrical polymer brushes via RAFT polymerization.
PubMed:Nanoparticle Formation from Hybrid, Multiblock Copolymers of Poly(Acrylic Acid) and VPGVG Peptide.
PubMed:Separation and composition distribution determination of triblock copolymers by thermal field-flow fractionation.
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PubMed:Photoinduced disorder in strongly segregated block copolymer composite films for hierarchical pattern formation.
PubMed:Protein immobilization onto poly(acrylic acid) functional macroporous polyHIPE obtained by surface-initiated ARGET ATRP.
PubMed:Preparation of copolymer paclitaxel covalently linked via a disulfide bond and its application on controlled drug delivery.
PubMed:Simultaneous coating of silica particles by two diblock copolymers.
PubMed:Pressure-sensitive adhesion system using acrylate block copolymers in response to photoirradiation and postbaking as the dual external stimuli for on-demand dismantling.
PubMed:Surface-grafted poly(acrylic acid) brushes as a precursor layer for biosensing applications: effect of graft density and swellability on the detection efficiency.
PubMed:Mimicking conjugated polymer thin-film photophysics with a well-defined triblock copolymer in solution.
PubMed:Oleic acid based heterolipid synthesis, characterization and application in self-microemulsifying drug delivery system.
PubMed:Functional polyolefins: poly(ethylene)-graft-poly(tert-butyl acrylate) via atom transfer radical polymerization from a polybrominated alkane.
PubMed:Planar chiral (η6-arene)Cr(CO)3 containing carboxylic acid derivatives: synthesis and use in the preparation of organometallic analogues of the antibiotic platensimycin.
PubMed:Scanning thermal lithography of tailored tert-butyl ester protected carboxylic acid functionalized (meth)acrylate polymer platforms.
PubMed:Chiral gold(I) vs chiral silver complexes as catalysts for the enantioselective synthesis of the second generation GSK-hepatitis C virus inhibitor.
PubMed:Thiol-alkyne chemistry for the preparation of micelles with glycopolymer corona: dendritic surfaces versus linear glycopolymer in their ability to bind to lectins.
PubMed:Theoretical studies on the mechanism and stereoselectivity of Rh(Phebox)-catalyzed asymmetric reductive aldol reaction.
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PubMed:Chemical surface modification of parylene C for enhanced protein immobilization and cell proliferation.
PubMed:Synthesis of drug/dye-incorporated polymer-protein hybrids.
PubMed:Development of a new open-tubular capillary electrochromatography method for in vitro monitoring of toxic aromatic amines distribution in rat blood.
PubMed:Poly(Acrylic Acid-b-Styrene) Amphiphilic Multiblock Copolymers as Building Blocks for the Assembly of Discrete Nanoparticles.
PubMed:Diels-Alder reactions as an efficient route to high purity cyclic polymers.
PubMed:Introducing surface-tethered poly(acrylic acid) brushes as 3D functional thin film for biosensing applications.
PubMed:Chiral imprinting of diblock copolymer single-chain particles.
PubMed:Temperature and pH dual-responsive cross-linked polymeric nanocapsules with controllable structures via surface-initiated atom transfer radical polymerization from templates.
PubMed:Molecular friction dissipation and mode coupling in organic monolayers and polymer films.
PubMed:Hybrid rigid/soft and biologic/synthetic materials: polymers grafted onto cellulose microcrystals.
PubMed:A novel hyperbranched poly(acrylic acid) for improved resin-modified glass-ionomer restoratives.
PubMed:A novel amphipathic block copolymer coating forming micelle-like aggregates for separation of steroids in open tubular capillary electrochromatography.
PubMed:Rheological properties of aqueous micellar gels of a thermo- and pH-sensitive ABA triblock copolymer.
PubMed:RAFT "grafting-through" approach to surface-anchored polymers: Electrodeposition of an electroactive methacrylate monomer.
PubMed:Temperature-responsive ionic-crosslinked polymeric nanocapsules via 'self-templating' approach.
PubMed:Star-shaped nano-conjugates of cisplatin with high drug payload.
PubMed:Water-soluble organo-silica hybrid nanotubes templated by cylindrical polymer brushes.
PubMed:Investigation of thermally responsive block copolymer thin film morphologies using gradients.
PubMed:Amphiphilic polyethylenes leading to surfactant-free thermoresponsive nanoparticles.
PubMed:Hyperbranched alternating block copolymers using thiol-yne chemistry: materials with tuneable properties.
PubMed:Synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers.
PubMed:SiO2 nanodot arrays using functionalized block copolymer templates and selective silylation.
PubMed:Shaping gold nanocomposites with tunable optical properties.
PubMed:Perfluorocarbon-loaded Shell Crosslinked Knedel-like Nanoparticles: Lessons regarding polymer mobility and self assembly.
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PubMed:Inkless microcontact printing on SAMs of Boc- and TBS-protected thiols.
PubMed:A general methodology toward drug/dye incorporated living copolymer-protein hybrids: (NIRF dye-glucose) copolymer-avidin/BSA conjugates as prototypes.
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PubMed:N-heterocycle carbene (NHC)-ligated cyclopalladated N,N-dimethylbenzylamine: a highly active, practical and versatile catalyst for the Heck-Mizoroki reaction.
PubMed:Polymer brush covalently attached to OH-functionalized mica surface via surface-initiated ATRP: control of grafting density and polymer chain length.
PubMed:Coating and structural locking of dipolar chains of cobalt nanoparticles.
PubMed:Gold nanoparticles protected with thiol-derivatized amphiphilic poly(epsilon-caprolactone)-b-poly(acrylic acid).
PubMed:19F- and fluorescently labeled micelles as nanoscopic assemblies for chemotherapeutic delivery.
PubMed:ATRP from an amino acid-based initiator: A facile approach for α-functionalized polymers.
PubMed:Adsorption of well-defined fluorine-containing polymers onto poly(tetrafluoroethylene).
PubMed:Amphiphilic hyperbranched fluoropolymers as nanoscopic 19F magnetic resonance imaging agent assemblies.
PubMed:Atomic force microscopy based thermal lithography of poly(tert-butyl acrylate) block copolymer films for bioconjugation.
PubMed:Amphiphilic Janus gold nanoparticles via combining "solid-state grafting-to" and "grafting-from" methods.
PubMed:Fabrication of block copolymer monolayers by adsorption from supercritical fluids: a versatile concept for modification and functionalization of polymer surfaces.
PubMed:Synthesis of dense poly(acrylic acid) brushes and their interaction with amine-functional silsesquioxane nanoparticles.
PubMed:Inverted microcontact printing on polystyrene-block-poly(tert-butyl acrylate) films: a versatile approach to fabricate structured biointerfaces across the length scales.
PubMed:Noncovalently connected micelles, nanoparticles, and metal-functionalized nanocages using supramolecular self-assembly.
PubMed:Phase separation in poly(tert-butyl acrylate)/polyhedral oligomeric silsesquioxane (POSS) thin film blends.
PubMed:A Proximal Bisnitroxide Initiator: Studies in Low-Temperature Nitroxide-Mediated Polymerizations.
PubMed:Patterning on nonplanar substrates: flexible honeycomb films from a range of self-assembling star copolymers.
PubMed:Unprecedented covalently attached ATRP initiator onto OH-functionalized mica surfaces.
PubMed:Thermomechanical formation and recovery of nanoindents in a shape memory polymer studied using a heated tip.
PubMed:Comb polymers prepared by ATRP from hydroxypropyl cellulose.
PubMed:Polystyrene-b-poly(tert-butyl acrylate) and polystyrene-b-poly(acrylic acid) dendrimer-like copolymers: two-dimensional self-assembly at the air-water interface.
PubMed:Unconstrained recovery characterization of shape-memory polymer networks for cardiovascular applications.
PubMed:Stille-Heck coupling sequences applied in a versatile new access to steroid skeletons.
PubMed:Reactive microCP on ultrathin block copolymer films: investigation of the microCP mechanism and application to sub-microm (bio)molecular patterning.
PubMed:Dip-pen nanolithography on (bio)reactive monolayer and block-copolymer platforms: deposition of lines of single macromolecules.
PubMed:Synthesis and aggregation behavior of four-arm star amphiphilic block copolymers in water.
PubMed:Interactions of poly(tert-butyl acrylate)-poly(styrene) diblock copolymers with lipids at the air-water interface.
PubMed:Self-assembly of well-defined mono and dual end-capped C(60) containing polyacrylic acids in aqueous solution.
PubMed:Pattern formation in dewetting poly(tert-butyl acrylate)/polyhedral oligomeric silsesquioxane (POSS) bilayer films.
PubMed:Rapid growth of polymer brushes from immobilized initiators.
PubMed:Tandem synthesis of core-shell brush copolymers and their transformation to peripherally cross-linked and hollowed nanostructures.
PubMed:Synthesis of degradable model networks via ATRP and click chemistry.
PubMed:High-capacity binding of proteins by poly(acrylic acid) brushes and their derivatives.
PubMed:Nanoscale phase separation in mixed poly(tert-butyl acrylate)/polystyrene brushes on silica nanoparticles under equilibrium melt conditions.
PubMed:Reversible stimuli-responsive nanostructures assembled from amphiphilic block copolymers.
PubMed:Preparation of platinum nanoparticles using star-block copolymer with a carboxylic core.
PubMed:Copper(I) and -(II) complexes of neutral and deprotonated N-(2,6-diisopropylphenyl)-3-[bis(2-pyridylmethyl)amino]propanamide.
PubMed:Self-assembly of pODMA-b-ptBA-b-pODMA triblock copolymers in bulk and on surfaces. A quantitative SAXS/AFM comparison.
PubMed:Directed assembly of cylinder-forming block copolymer films and thermochemically induced cylinder to sphere transition: a hierarchical route to linear arrays of nanodots.
PubMed:Antigen-decorated shell cross-linked nanoparticles: synthesis, characterization, and antibody interactions.
PubMed:Stimuli-responsive mixed grafted polymer films with gradually changing properties: direct determination of chemical composition.
PubMed:Mono- and beta,beta-double-Heck reactions of alpha,beta-unsaturated carbonyl compounds in aqueous media.
PubMed:Environmentally responsive "hairy" nanoparticles: mixed homopolymer brushes on silica nanoparticles synthesized by living radical polymerization techniques.
PubMed:Three-dimensionally ordered porous membranes prepared via self-assembly and reverse micelle formation from well-defined amphiphilic block copolymers.
PubMed:Photochemical modification and patterning of polymer surfaces by surface adsorption of photoactive block copolymers.
PubMed:Thermomechanics of the shape memory effect in polymers for biomedical applications.
PubMed:Interfacial reactions in confinement: kinetics and temperature dependence of the surface hydrolysis of polystyrene-block-poly(tert-butyl acrylate) thin films.
PubMed:Interactions between brushlike polyacrylic acid side chains on a polyacrylate backbone in dioxane-water.
PubMed:Synthesis and characterization of polyester dendrimers from acetoacetate and acrylate.
PubMed:Monitoring surface thermal transitions of ABA triblock copolymers with crystalline segments using phase contrast tapping mode atomic force microscopy.
PubMed:Synthesis of tethered-polymer brush by atom transfer radical polymerization from a plasma-polymerized-film-coated quartz crystal microbalance and its application for immunosensors.
PubMed:Metalloinitiation routes to biocompatible poly(lactic acid) and poly(acrylic acid) stars with luminescent ruthenium tris(bipyridine) cores.
PubMed:Polymerization from the surface of single-walled carbon nanotubes - preparation and characterization of nanocomposites.
PubMed:Y-shaped amphiphilic brushes with switchable micellar surface structures.
PubMed:Use of highly active palladium-phosphinous acid catalysts in Stille, Heck, amination, and thiation reactions of chloroquinolines.
PubMed:Synthesis of poly(tert-butyl acrylate)-block-polystyrene-block-poly(4-vinylpyridine) by living anionic polymerization.
PubMed:Synthesis and characterization of luminescent rod-coil block copolymers by atom transfer radical polymerization: utilization of novel end-functionalized terfluorenes as macroinitiators.
PubMed:Water-soluble fluorescent diblock nanospheres.
PubMed:Amphiphilic block copolymers as bile acid sorbents: 1. Synthesis of polystyrene-b-poly(N,N,N-trimethylammoniumethylene acrylamide chloride).
PubMed:An improved synthesis of a trifurcated newkome-type monomer and orthogonally protected two-generation dendrons.
PubMed:Patterning of hyperbranched polymer films.
PubMed:Metal- and Ligand-Accelerated Catalysis of the Baylis-Hillman Reaction.
PubMed:Block Copolymer Nanotubes.
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Notes:
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