EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

phosphorus tribromide
phosphorous bromide

Supplier Sponsors

Name:tribromophosphane
CAS Number: 7789-60-8Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:232-178-2
FDA UNII: 58R3866PUA
Nikkaji Web:J95.136F
MDL:MFCD00011436
XlogP3-AA:2.80 (est)
Molecular Weight:270.68576200
Formula:Br3 P
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:pharmaceuticals / chemical synthisis
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
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Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Appearance:colorless fuming liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:2.85000 @ 25.00 °C.
Melting Point: -41.50 °C. @ 760.00 mm Hg (est)
Boiling Point: 172.90 °C. @ 760.00 mm Hg (est)
Vapor Pressure:1.737000 mmHg @ 25.00 °C. (est)
Flash Point: 32.00 °F. TCC ( 0.00 °C. ) (est)
logP (o/w): 2.394 (est)
Soluble in:
 water, 205.3 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
Penta International
PHOSPHORUS TRIBROMIDE
Sigma-Aldrich: Aldrich
For experimental / research use only.
Phosphorus tribromide 99%
Strem Chemicals
For experimental / research use only.
Phosphorus(III) bromide, 97+%
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LDLo 50 mg/kg
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: DYSPNEA BEHAVIORAL: MUSCLE WEAKNESS
National Technical Information Service. Vol. OTS0555394

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
pharmaceuticals / chemical synthisis
Recommendation for phosphorus tribromide usage levels up to:
 not for fragrance use.
 
Recommendation for phosphorus tribromide flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):7789-60-8
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :24614
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:1
tribromophosphane
Chemidplus:0007789608
EPA/NOAA CAMEO:hazardous materials
RTECS:TH4460000 for cas# 7789-60-8
 
References:
 tribromophosphane
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:7789-60-8
Pubchem (cid):24614
Pubchem (sid):134989034
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2812.90.0000
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 phosphorous bromide
 phosphorous tribromide
 phosphorustribromide
 tribromophosphane
 tribromophosphine
 

Articles:

PubMed:Practical, laboratory-scale synthesis of N(in) -formyl tryptophan hydrobromide.
PubMed:Reaction of perfluoroalkyl grignard reagents with phosphorus trihalides: a new route to perfluoroalkyl-phosphonous and -phosphonic acids.
PubMed:Room temperature, copper-catalyzed amination of bromonaphthyridines with aqueous ammonia.
PubMed:One-pot cyclizations of dilithiated oximes and hydrazones with epibromohydrin. Efficient synthesis of 6-hydroxymethyl-5,6-dihydro-4H-1,2-oxazines and oxazolo[3,4-b]pyridazin-7-ones.
PubMed:Synthesis of Optically Active beta-Amino Acid N-Carboxyanhydrides.
PubMed:Chiral Pyridine-Based Macrobicyclic Clefts: Synthesis and Enantiomeric Recognition of Ammonium Salts.
PubMed:Synthesis of 2-[18F]fluoro-2-deoxy-L-glucose and positron emission tomography studies in monkeys.
PubMed:Synthesis and in vitro biological activity of new deaza analogues of folic acid, aminopterin, and methotrexate with an L-ornithine side chain.
PubMed:Researches on antibacterial and antifungal agents. IX--Pyrrole analogues of bifonazole with potent antifungal activities.
PubMed:Chemical pneumonitis due to exposure to bromine compounds.
PubMed:Gas chromatographic determination of fluridone aquatic herbicide and its major metabolite in fish.
PubMed:[Immobilization of pectawamorine G10x on silichromes].
PubMed:Dehydration of 2-hydroxy(ethoxy)-2-aryl-N.N-penta(tetra) methylenemorpholinium bromides.
 
Notes:
None found
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