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Category:food contact resinous and polymeric coatings
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Assay: | 95.00 to 100.00
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| Food Chemicals Codex Listed: | No |
| Melting Point: | 205.00 °C. @ 760.00 mm Hg
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| Boiling Point: | 117.10 °C. @ 760.00 mm Hg (est)
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| Vapor Pressure: | 13.900000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 104.00 °F. TCC ( 40.00 °C. ) (est)
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| logP (o/w): | -0.285 (est) |
Organoleptic Properties:
| Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-mouse LD50 2100 mg/kg
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
GASTROINTESTINAL: ULCERATION OR BLEEDING FROM STOMACH
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 51(12), Pg. 88, 1986.
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| Dermal Toxicity: |
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Not determined
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| Inhalation Toxicity: |
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Not determined
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Safety in Use Information:
| Category: | | food contact resinous and polymeric coatings |
| Recommendation for palladium(II) acetate usage levels up to: | | | not for fragrance use.
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| Recommendation for palladium(II) acetate flavor usage levels up to: |
| | not for flavor use.
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Safety References:
European Food Safety Authority (EFSA) reference(s):
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Scientific Opinion on the safety evaluation of the active substances, sodium borohydride and palladium acetate for use in active food contact materials
View page or View pdf
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| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA Substance Registry Services (TSCA):3375-31-3 |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :167845 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:2 |
| palladium(2+) diacetate |
| Chemidplus:0003375313 |
| RTECS:AJ1900000 for cas# 3375-31-3 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | acetic acid palladium(2+) salt (2:1) | | | acetic acid palladium(II) salt | | | acetic acid, palladium(2+) salt (2:1) | | | diacetatopalladium | | | palladium(2+) acetate | | | palladium(2+) diacetate | | | palladous acetate |
Articles:
| PubMed:Organo-palladium(ii) complexes bearing unsymmetrical N,N,N-pincer ligands: synthesis, structures and oxidatively induced coupling reactions. |
| PubMed:O,N,N-Pincer ligand effects on oxidatively induced carbon-chlorine coupling reactions at palladium. |
| PubMed:Regioselective direct C-3 arylation of imidazo[1,2-a]pyridines with aryl tosylates and mesylates promoted by palladium-phosphine complexes. |
| PubMed:Synthesis and metalation of dimethoxybenziporphyrins, thiabenziporphyrins, and dibenziporphyrins. |
| PubMed:Chiral palladacycle catalysts generated on a single-handed helical polymer skeleton for asymmetric arylative ring opening of 1,4-epoxy-1,4-dihydronaphthalene. |
| PubMed:Mechanochemical C-H bond activation: rapid and regioselective double cyclopalladation monitored by in situ Raman spectroscopy. |
| PubMed:Synthesis and reactivity of carbachlorins and carbaporphyrins. |
| PubMed:ortho-Metallated triphenylphosphine chalcogenide complexes of platinum and palladium: synthesis and catalytic activity. |
| PubMed:Palladium-catalyzed direct C2 arylation of N-substituted indoles with 1-aryltriazenes. |
| PubMed:Facile preparation of Pd nanoparticles supported on single-layer graphene oxide and application for the Suzuki-Miyaura cross-coupling reaction. |
| PubMed:Synthesis of an adj-dicarbaporphyrin and the formation of an unprecedented tripalladium sandwich complex. |
| PubMed:Synthesis, structural characterization, aromatic characteristics, and metalation of neo-confused porphyrins, a newly discovered class of porphyrin isomers. |
| PubMed:Synthesis, crystal structure, fluorescence and electrochemical studies of a new tridentate Schiff base ligand and its nickel(II) and palladium(II) complexes. |
| PubMed:Synthesis of multi-substituted pyrroles using enamides and alkynes catalyzed by Pd(OAc)2 with molecular oxygen as an oxidant. |
| PubMed:6-Oxopyriphlorins. |
| PubMed:Synthesis of dienyl ketones via palladium(II)-catalyzed direct cross-coupling reactions between simple alkenes and vinyl ketones: application to the synthesis of vitamin A1 and bornelone. |
| PubMed:Synthesis of benziporphyrins and heterobenziporphyrins and an assessment of the diatropic characteristics of the protonated species. |
| PubMed:Pd(OAc)2-catalyzed C-H activation/C-O cyclization: mechanism, role of oxidant-probed by density functional theory. |
| PubMed:Palladium(II)-catalyzed synthesis of 2H,3'H-spiro[benzofuran-3,2'-naphthoquinones]. |
| PubMed:2-Tosyl-2,3,3a,4,9,9a-hexa-hydro-1H-benzo[f]isoindol-1-one. |
| PubMed:C-H functionalization logic enables synthesis of (+)-hongoquercin A and related compounds. |
| PubMed:Microwave assisted Suzuki-Miyaura and Ullmann type homocoupling reactions of 2- and 3-halopyridines using a Pd(OAc)2/benzimidazolium salt and base catalyst system. |
| PubMed:N,N-Chelate-control on the regioselectivity in acetate-assisted C-H activation. |
| PubMed:Grafting control of mainstay terpyridine self-assembled monolayers for the preparation of planar silicon surfaces with variable catalytic loadings. |
| PubMed:Pd(OAc)2 catalyzed direct arylation of electron-deficient arenes without ligands or with monoprotected amino acid assistance. |
| PubMed:Palladium(II) acetate mediated oxidative cyclization of ω-unsaturated α-cyano ketones for facile construction of methylenecyclohexane ring system. |
| PubMed:Theoretical analysis of the mechanism of palladium(II) acetate-catalyzed oxidative Heck coupling of electron-deficient arenes with alkenes: effects of the pyridine-type ancillary ligand and origins of the meta-regioselectivity. |
| PubMed:Palladium-catalyzed hydroacyloxylation of ynamides. |
| PubMed:Palladium-catalyzed synthesis of dibenzophosphole oxides via intramolecular dehydrogenative cyclization. |
| PubMed:Unexpected alkyl group migration in palladium(II) benzocarbaporphyrins. |
| PubMed:Regioselective orthopalladation of (Z)-2-aryl-4-arylidene-5(4H)-oxazolones: scope, kinetico-mechanistic, and density functional theory studies of the C-H bond activation. |
| PubMed:Pyrazole analogues of porphyrins and oxophlorins. |
| PubMed:Ethyl 4-acetyl-5-oxo-3-phenyl-hexa-noate. |
| PubMed:Synthesis and antibacterial activity of 2, 3-dehydro-3-O-(3-aryl-E-prop-2-enyl)-10, 11-anhydroclarithromycin derivatives. |
| PubMed:Isostructural Pd(II) and Pt(II) pyrophosphato complexes: polymorphism and unusual bond character in d8-d8 systems. |
| PubMed:Tetrasubstituted furans by Pd(II)/Cu(I)-cocatalyzed three-component domino reactions of 2-(1-alkynyl)-2-alken-1-ones, nucleophiles and diaryliodonium salts. |
| PubMed:Efficient assembly of 1-methylene-1H-indenes via palladium-catalyzed tandem reaction of 1-(2,2-dibromovinyl)-2-alkenylbenzene with arylboronic acid. |
| PubMed:Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)(2)/HPMoV/O(2) system. |
| PubMed:Alkyne hydroarylation in ionic liquids catalyzed by palladium(II) complexes. |
| PubMed:Controlling the coordination modes of a new and highly flexible ligand bearing two N-heterocyclic carbene moieties at a bipyridine backbone. |
| PubMed:Selective Heck arylation of cyclohexene with homogeneous and heterogeneous palladium catalysts. |
| PubMed:Efficient synthesis of alkyl aryl ketones & ketals via palladium-catalyzed regioselective arylation of vinyl ethers. |
| PubMed:Pd(OAc)(2) catalyzed olefination of highly electron-deficient perfluoroarenes. |
| PubMed:Spontaneous product segregation from reactions in ionic liquids: application in Pd-catalyzed aliphatic alcohol oxidation. |
| PubMed:Synthesis of alpha-cyanocinnamaldehydes from acrylonitrile and benzaldehydes catalyzed by Pd(OAc)(2)/HPMoV/FeCl(3)/O(2) system. |
| PubMed:Palladium(II) acetate catalyzed tandem cycloisomerization and oxidation of arylvinylcyclopropenes using p-benzoquinone as oxidant and pro-nucleophile. |
| PubMed:Cyclometallation of amino-imines on palladium complexes. The effect of the solvent on the experimental and calculated mechanism. |
| PubMed:Synthesis of novel 3,5-dichloro-2-arylpyridines by palladium acetate-catalyzed ligand-free Suzuki reactions in aqueous media. |
| PubMed:31P NMR study of the stoichiometry, stability and thermodynamics of complex formation between palladium(II) acetate and bis(diphenylphosphino)ferrocene. |
| PubMed:Fluorogenic derivatization of aryl halides based on the formation of biphenyl by Suzuki coupling reaction with phenylboronic acid. |
| PubMed:Efficient syntheses of phosphonylated isochromenes by regioselective 6-endo-dig addition to carbon-carbon triple bond catalyzed by Pd(OAc)2. |
| PubMed:Total synthesis of dehydroaltenuene A. Revision of the structure and total synthesis of dihydroaltenuene B. |
| PubMed:Palladium catalysts supported on mesoporous molecular sieves bearing nitrogen donor groups: preparation and use in Heck and Suzuki C-C bond-forming reactions. |
| PubMed:Dendrimer-encapsulated Pd nanoparticles versus palladium acetate as catalytic precursors in the stille reaction in water. |
| PubMed:Synthesis and reactivity of N-methyl and N-phenyl meso-unsubstituted N-confused porphyrins. |
| PubMed:Palladium(II) complexes of unsymmetrical CNN pincer ligands. |
| PubMed:Palladium(II)-catalyzed direct arylation of enaminones using organotrifluoroborates. |
| PubMed:A general synthesis of diarylketones by means of a three-component cross-coupling of aryl and heteroaryl bromides, carbon monoxide, and boronic acids. |
| PubMed:Stabilized spherical aggregate of palladium nanoparticles prepared by reduction of palladium acetate in octa(3-aminopropyl)octasilsesquioxane as a rigid template. |
| PubMed:Enantiospecific syntheses of copper cubanes, double-stranded copper/palladium helicates, and a (dilithium)-dinickel coronate from enantiomerically pure bis-1,3-diketones--solid-state self-organization towards wirelike copper/palladium strands. |
| PubMed:Synthesis, stability, and complexation behavior of isolable salen-type N2S2 and N2SO ligands based on thiol and oxime functionalities. |
| PubMed:"Click" dendrimers: synthesis, redox sensing of Pd(OAc)2, and remarkable catalytic hydrogenation activity of precise Pd nanoparticles stabilized by 1,2,3-triazole-containing dendrimers. |
| PubMed:Synthesis of substituted furoates from acrylates and aldehydes by Pd(OAc)(2)/HPMoV/CeCl(3)/O(2) system. |
| PubMed:Syntheses and reactivity of meso-unsubstituted azuliporphyrins derived from 6-tert-butyl- and 6-phenylazulene. |
| PubMed:[The synthesis of 2alpha,3alpha-isopropylidenedioxy-6,6-ethylenedioxy-5alpha-androst-15-en-17-one and its 2beta,3beta-isomer]. |
| PubMed:Alkoxy- and amidocarbonylation of functionalised aryl and heteroaryl halides catalysed by a Bedford palladacycle and dppf: a comparison with the primary Pd(II) precursors (PhCN)2PdCl2 and Pd(OAc)2. |
| PubMed:Palladium-catalyzed coupling of allenylphosphonates, phenylallenes, and allenyl esters: remarkable salt effect and routes to novel benzofurans and isocoumarins. |
| PubMed:Remarkably efficient hydrolysis of methylparathion catalyzed by [2-(2-pyridyl)phenyl-C,N]palladium(II) complexes. |
| PubMed:Unexpected roles of molecular sieves in palladium-catalyzed aerobic alcohol oxidation. |
| PubMed:Stereochemical investigations of a novel class of chiral phosphapalladacycle complexes derived from 1-[(2,5-dimethyl)phenyl]ethyldiphenylphosphine. |
| PubMed:Pd-catalyzed silicon hydride reductions of aromatic and aliphatic nitro groups. |
| PubMed:Suzuki-Miyaura cross-coupling of benzylic phosphates with arylboronic acids. |
| PubMed:Non-trivial behavior of palladium(II) acetate. |
| PubMed:Mono- and beta,beta-double-Heck reactions of alpha,beta-unsaturated carbonyl compounds in aqueous media. |
| PubMed:Efficient batch and continuous flow Suzuki cross-coupling reactions under mild conditions, catalysed by polyurea-encapsulated palladium (II) acetate and tetra-n-butylammonium salts. |
| PubMed:Palladium(II) acetate in pyridine as an effective catalyst for highly regioselective hydroselenation of alkynes. |
| PubMed:Diacetato-kappa2O-bis[(S)-1-(4-fluorophenyl)ethylamine-kappaN]palladium(II) and di-mu-acetato-kappa4O:O'-bis[[(S)-2-(1-aminoethyl)-5-fluorophenyl-kappa2C1,N]palladium(II)] benzene hemisolvate. |
| PubMed:Potassium hexacyanoferrate(II)--a new cyanating agent for the palladium-catalyzed cyanation of aryl halides. |
| PubMed:Palladium(II) acetate mediated oxidative cyclization of omega-unsaturated alpha-cyano ketones. A facile methylenecyclopentane annulation process. |
| PubMed:Organometallic chemistry of azuliporphyrins: synthesis, spectroscopy, electrochemistry, and structural characterization of nickel(II), palladium(II), and platinum(II) complexes of azuliporphyrins. |
| PubMed:Transfer hydrogenation using recyclable polyurea-encapsulated palladium: efficient and chemoselective reduction of aryl ketones. |
| PubMed:A modified synthesis of iodoazidoaryl prazosin. |
| PubMed:Organometallic chemistry of carbaporphyrinoids: synthesis and characterization of nickel(II) and palladium(II) azuliporphyrins. |
| PubMed:Polyurea-encapsulated palladium(II) acetate: a robust and recyclable catalyst for use in conventional and supercritical media. |
| PubMed:Encapsulation of palladium in polyurea microcapsules. |
| PubMed:Palladium-imidazolium carbene catalyzed Mizoroki-Heck coupling with aryl diazonium ions. |
| PubMed:Intramolecular palladium(II)-mediated alkoxy carbonylation as a route to functionalized tetrahydropyrans. Synthesis of the C9-C32 segment of phorboxazole A. |
| PubMed:Preparation of vinylogous 2-sulfonylindolines by the palladium-catalyzed heteroannulation of o-iodoanilines with dienyl sulfones and their further transformation to indoles and carbazoles. |
| PubMed:Palladium-imidazolium carbene catalyzed aryl, vinyl, and alkyl Suzuki-Miyaura cross coupling. |
| PubMed:Synthesis of Enantiomerically Pure Cyclopropanes from Cyclopropylboronic Acids. |
| PubMed:Synthesis of Phthalideisoquinoline and Protoberberine Alkaloids and Indolo[2,1-a]isoquinolines in a Divergent Route Involving Palladium(0)-Catalyzed Carbonylation(1). |
| PubMed:Palladium(II) Acetate-Tris(triphenylphosphine)rhodium(I) Chloride: A Novel Catalytic Couple for the Intramolecular Heck Reaction. |
| PubMed:Pd(ii)-hydrotalcite-catalyzed oxidation of alcohols to aldehydes and ketones using atmospheric pressure of air. |
| PubMed:Palladium(II) acetate catalyzed stereoselective C-glycosidation of peracetylated glycals with arylboronic acids. |
| PubMed:Improvements in cross coupling reactions of hypervalent siloxane derivatives. |
| PubMed:Tetrapyrroles as pi Donors: A Pd(2)(2+) Unit Sandwiched between Two Helical Bilindione-Palladium Moieties. |
| PubMed:Novel tetranuclear orthometalated complexes of Pd(II) and Pt(II) derived from p-isopropylbenzaldehyde thiosemicarbazone with cytotoxic activity in cis-DDP resistant tumor cell lines. Interaction of these complexes with DNA. |
| PubMed:Pd.H-C Interactions. Preparation and Structure of Orthometalated Tetranuclear Complexes of Palladium(II) and Platinum(II). |
| PubMed:Synthesis and bioassay of LHRH-antagonists with N-Ac-D-O-phenyltyrosine and N-Ac-D-3-(2-dibenzofuranyl)alanine in position 1. |
| PubMed:Palladium (II)-catalyzed olefin-coupling reactions of kainic acid: effects of substitution on the isopropenyl group on receptor binding. |
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3D/inchi