EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

methyl magnesium chloride
chloro(methyl)magnesium

Supplier Sponsors

Name:magnesium;carbanide;chloride
CAS Number: 676-58-4Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:211-629-7
FDA UNII: M5E1132G4W
MDL:MFCD00000468
Molecular Weight:74.79191000
Formula:C H3 Cl Mg
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:information only not used for fragrances or flavors
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:1.01300 @ 25.00 °C.
Flash Point: 1.00 °F. TCC ( -17.22 °C. )
Soluble in:
 water, 7.598e+004 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
Methylmagnesium chloride 95%
EMD Millipore
For experimental / research use only.
Methylmagnesium chloride
sds
Sigma-Aldrich: Aldrich
For experimental / research use only.
Methylmagnesium chloride solution 3.0 M in THF
sds
Strem Chemicals
For experimental / research use only.
Methylmagnesium chloride, 3M in THF
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
information only not used for fragrances or flavors
Recommendation for methyl magnesium chloride usage levels up to:
 not for fragrance use.
 
Recommendation for methyl magnesium chloride flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):676-58-4
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :12670
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
magnesium;carbanide;chloride
Chemidplus:0000676584
 
References:
 magnesium;carbanide;chloride
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:676-58-4
Pubchem (cid):12670
Pubchem (sid):134978324
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2931.00.5050
ChemSpider:View
Wikipedia:View
Formulations/Preparations:
available as a soln in tetrahydrofuran.
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 chloro(methyl)magnesium
 chloromethylmagnesium
 magnesium, chloromethyl-
 magnesium;carbanide;chloride
 methylmagnesium chloride
 

Articles:

US Patents:7,927,643 - Compositions of oxo-terpene derivatives and process for preparing the same
PubMed:Validation of methane measurement using headspace-GC-MS and quantification by a stable isotope-labeled internal standard generated in situ.
PubMed:Chemoselective quantum control of carbonyl bonds in Grignard reactions using shaped laser pulses.
PubMed:Development of an automated modular system for the synthesis of [11C]acetate.
PubMed:C-F bond-cleavage reactions of fluoroalkanes with magnesium reagents and without metal catalysts.
PubMed:A simple Tracerlab module modification for automated on-column [11C]methylation and [11C]carboxylation.
PubMed:Synthesis of a naphthyridone p38 MAP kinase inhibitor.
PubMed:Air-assisted addition of grignard reagents to olefins. A simple protocol for a three-component coupling process yielding alcohols.
PubMed:Synthesis of 1-tert-butyl-4-chloropiperidine: generation of an N-tert-butyl group by the reaction of a dimethyliminium salt with methylmagnesium chloride.
PubMed:Accurate determinations of the extent to which the SE2' reactions of allyl-, allenyl- and propargylsilanes are stereospecifically anti.
PubMed:An efficient synthesis of 2-substituted 6-methylpurine bases and nucleosides by Fe- or Pd-catalyzed cross-coupling reactions of 2,6-dichloropurines.
PubMed:A computational study on addition of Grignard reagents to carbonyl compounds.
PubMed:An improvement of 11C acetate synthesis--non-radioactive contaminants by irradiation-induced species emanating from the 11C carbon dioxide production target.
PubMed:Synthesis, structural characterization, and transmetalation reactions of a tetranuclear magnesium silsesquioxane complex.
PubMed:A one-step C-linked disaccharide synthesis from carbohydrate allylsilanes and tri-O-acetyl-D-glucal.
 
Notes:
None found
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