EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

lauryl methacrylate
acrylic acid, 2-methyl-, dodecyl ester

Supplier Sponsors

CAS Number: 142-90-5Picture of molecule3D/inchi
Other(deleted CASRN):170292-57-6
ECHA EINECS - REACH Pre-Reg:205-570-6
FDA UNII: B6L83074BZ
Nikkaji Web:J78.373K
Beilstein Number:1708160
MDL:MFCD00008972
XlogP3:7.20 (est)
Molecular Weight:254.41350000
Formula:C16 H30 O2
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:viscosity controlling agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.86800 @ 25.00 °C.
Melting Point: -7.00 °C. @ 760.00 mm Hg
Boiling Point: 322.72 °C. @ 760.00 mm Hg (est)
Vapor Pressure:0.001200 mmHg (est)
Flash Point:> 230.00 °F. TCC ( > 110.00 °C. )
logP (o/w): 6.811 (est)
Soluble in:
 water, 0.05478 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: viscosity controlling agents
 
Suppliers:
BASF
LMA 1214
BOC Sciences
For experimental / research use only.
Dodecyl 2-methylacrylate 95%
Jarchem Industries
Jarchem® LMA
Odor: characteristic
Use: Monomer offering excellent flexibility and low shrinkage. Excellent for use in automotive refinish resins, low temperature caulks, sealants, and adhesives.
Kao Corporation
EXCEPARL L-MA
Odor: characteristic
Use: Paint additives, Adhesives, Lubricant additives, Petroleum additives
Moellhausen
Lauryl Methacrylate
Penta International
LAURYL METHACRYLATE
Santa Cruz Biotechnology
For experimental / research use only.
Lauryl Methacrylate
Sigma-Aldrich: Aldrich
For experimental / research use only.
Lauryl methacrylate, contains 500 ppm MEHQ as inhibitor, 96%
sds
TCI AMERICA
For experimental / research use only.
Dodecyl Methacrylate (stabilized with MEHQ) >97.0%(GC)
sds
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
intravenous-dog LDLo 1240 uL/kg
Journal of Pharmaceutical Sciences. Vol. 63, Pg. 376, 1974.

intraperitoneal-mouse LD50 25000 mg/kg
Journal of Pharmaceutical Sciences. Vol. 62, Pg. 778, 1973.

intraperitoneal-rat LD50 12000 mg/kg
Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 36, Pg. 58, 1975.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
viscosity controlling agents
Recommendation for lauryl methacrylate usage levels up to:
 not for fragrance use.
 
Recommendation for lauryl methacrylate flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):142-90-5
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :8906
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:1
dodecyl 2-methylprop-2-enoate
Chemidplus:0000142905
EPA/NOAA CAMEO:hazardous materials
RTECS:OZ4300000 for cas# 142-90-5
 
References:
 dodecyl 2-methylprop-2-enoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:142-90-5
Pubchem (cid):8906
Pubchem (sid):134973414
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEMBL:View
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2916.14.2050
ChemSpider:View
Formulations/Preparations:
the commercial material is a mixture, containing also lower and higher fatty derivatives.
 
Potential Blenders and core components note
None Found
 
Potential Uses:
 odor neutralizer
 viscosity controlling agents
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 acrylic acid, 2-methyl-, dodecyl ester
 ageflex FM 246
1-dodecanol methacrylate
 dodecyl 2-methyl-2-propenoate
 dodecyl 2-methylacrylate
 dodecyl 2-methylprop-2-enoate
 dodecyl methacrylate
 metazene
 methacrylic acid dodecyl ester
 methacrylic acid, dodecyl ester
 methacrylic acid, lauryl ester
2-methyl-2-propenoic acid dodecyl ester
2-methyl-2-propenoic acid, dodecyl ester
2-propenoic acid, 2-methyl-, dodecyl ester
 sipomer LMA
 

Articles:

PubMed:Self-Assembly Behavior of Hairy Colloidal Particles with Different Architectures: Mixed versus Janus.
PubMed:Synthesis and characterization of transferrin-targeted chemotherapeutic delivery systems prepared via RAFT copolymerization of high molecular weight PEG macromonomers.
PubMed:Polymer monoliths with chelating functionalities for solid phase extraction of metal ions from water.
PubMed:Thermo-responsive diblock copolymer worm gels in non-polar solvents.
PubMed:Amine functional hydrogels as selective substrates for corneal epithelialization.
PubMed:A minimal hydrophobicity is needed to employ amphiphilic p(HPMA)-co-p(LMA) random copolymers in membrane research.
PubMed:Self-healing of the superhydrophobicity by ironing for the abrasion durable superhydrophobic cotton fabrics.
PubMed:HPLC analysis of synthetic polymers on short monolithic columns.
PubMed:Interaction of pHPMA-pLMA copolymers with human blood serum and its components.
PubMed:HPMA-LMA copolymer drug carriers in oncology: an in vivo PET study to assess the tumor line-specific polymer uptake and body distribution.
PubMed:PEGylation of HPMA-based block copolymers enhances tumor accumulation in vivo: a quantitative study using radiolabeling and positron emission tomography.
PubMed:Preparation and characterization of alkyl methacrylate-based monolithic columns for capillary gas chromatography applications.
PubMed:Improving Si solar cell performance using Mn:ZnSe quantum dot-doped PLMA thin film.
PubMed:Synthesis of low-cost, rubbery amphiphilic comb-like copolymers and their use in the templated synthesis of mesoporous TiO2 films for solid-state dye-sensitized solar cells.
PubMed:Cation exchange/hydrophobic interaction monolithic chromatography of small molecules and proteins by nano liquid chromatography.
PubMed:Preparation and evaluation of lauryl methacrylate monoliths with embedded silver nanoparticles for capillary electrochromatography.
PubMed:Fine encapsulation of dual-particle electronic ink by incorporating block copolymer for electrophoretic display application.
PubMed:Iminodiacetic acid functionalised organopolymer monoliths: application to the separation of metal cations by capillary high-performance chelation ion chromatography.
PubMed:Hydrophobic modification of polyurethane foam for oil spill cleanup.
PubMed:Preparation and application of hydrophobic hybrid monolithic columns containing polyhedral oligomeric silsesquioxanes for capillary electrochromatography.
PubMed:Capillary electrochromatography of three β2-agonists in human urine using a lauryl methacrylate-based monolithic column.
PubMed:Chemical anchoring of lauryl methacrylate-based reversed phase monolith to 1/16″ o.d. polyetheretherketone tubing.
PubMed:Polymer compatibility in two dimensions. Modeling of phase behavior of mixed polymethacrylate Langmuir films.
PubMed:A novel ionic liquid monolithic column and its separation properties in capillary electrochromatography.
PubMed:[Microchip-based reversed-phase liquid chromatography-tandem mass spectrometry platform for protein analysis].
PubMed:A general synthetic approach for obtaining cationic and anionic inorganic nanoparticles via encapsulation in amphiphilic copolymers.
PubMed:Methacrylate monolithic stationary phases for gradient elution separations in microfluidic devices.
PubMed:Analyses of sulfonamide antibiotics in meat samples by on-line concentration capillary electrochromatography-mass spectrometry.
PubMed:Preparation and characterization of lauryl methacrylate-based monolithic microbore column for reversed-phase liquid chromatography.
PubMed:Monolithic polymer layer with gradient of hydrophobicity for separation of peptides using two-dimensional thin layer chromatography and MALDI-TOF-MS detection.
PubMed:Modifying the body distribution of HPMA-based copolymers by molecular weight and aggregate formation.
PubMed:The effect of various cosmetic pretreatments on protecting hair from thermal damage by hot flat ironing.
PubMed:Effects of functional monomers on retention behavior of small and large molecules in monolithic capillary columns at isocratic and gradient conditions.
PubMed:Synthesis of amphiphilic star block copolymers and their evaluation as transdermal carriers.
PubMed:Multifunctional poly(alkyl methacrylate) films for dental care.
PubMed:Nanoscale graft copolymer templates decorated by silver bromide nanoparticles arrays.
PubMed:The effect of surface properties on the strength of attachment of fungal spores using AFM perpendicular force measurements.
PubMed:Analyses of synthetic antioxidants by capillary electrochromatography using poly(styrene-divinylbenzene-lauryl methacrylate) monolith.
PubMed:Electrochromatography in cyclic olefin copolymer microchips: a step towards field portable analysis.
PubMed:Electrochromatographic characterization of methacrylate ester-based monolith and capillary electrochromatography separation of flavonoids.
PubMed:Poly(divinylbenzene-alkyl methacrylate) monolithic stationary phases in capillary electrochromatography.
PubMed:Methacrylate ester-based monolithic columns for nano-LC separation of tocopherols in vegetable oils.
PubMed:[Preparation of monolithic polylaurylmethacrylate column and its application in capillary electrochromatographic separation of myoglobin digests].
PubMed:Langmuir-Blodgett films of biocompatible poly(HPMA)-block-poly(lauryl methacrylate) and poly(HPMA)-random-poly(lauryl methacrylate): influence of polymer structure on membrane formation and stability.
PubMed:Study of elution behaviour with gradient voltage in CEC using methacrylate monolithic columns.
PubMed:Separation of peptide diastereomers using CEC and a hydrophobic monolithic column.
PubMed:Fabrication and spectroscopic studies on highly luminescent CdSe/CdS nanorod polymer composites.
PubMed:Photo-polymerized lauryl methacrylate monolithic columns for CEC using lauroyl peroxide as initiator.
PubMed:Comparison on photo-initiators for the preparation of methacrylate monolithic columns for capillary electrochromatography.
PubMed:[Preparation of a reversed-phase capillary monolithic column and its application in the separation of polypeptide mixtures].
PubMed:Comparison of thermal- and photo-polymerization of lauryl methacrylate monolithic columns for CEC.
PubMed:Collecting peptide release from the brain using porous polymer monolith-based solid phase extraction capillaries.
PubMed:Short monolithic columns for purification and fractionation of peptide samples for matrix-assisted laser desorption/ionization time-of-flight/time-of-flight mass spectrometry analysis in proteomics.
PubMed:Highly efficient enzyme reactors containing trypsin and endoproteinase LysC immobilized on porous polymer monolith coupled to MS suitable for analysis of antibodies.
PubMed:CEC column behaviour of butyl and lauryl methacrylate monoliths prepared in non-aqueous media.
PubMed:Alteration of skin mechanics by thin polymer films.
PubMed:Rapid determination of sterols in vegetable oils by CEC using methacrylate ester-based monolithic columns.
PubMed:Lauroyl peroxide as thermal initiator of lauryl methacrylate monolithic columns for CEC.
PubMed:From defined reactive diblock copolymers to functional HPMA-based self-assembled nanoaggregates.
PubMed:Electron beam triggered, free radical polymerization-derived monolithic capillary columns for high-performance liquid chromatography.
PubMed:Methacrylate monolithic capillary columns for gradient peptide separations.
PubMed:A decontamination system for chemical weapons agents using a liquid solution on a solid sorbent.
PubMed:A microfluidic platform for integrated synthesis and dynamic light scattering measurement of block copolymer micelles.
PubMed:Automation of nanoflow liquid chromatography-tandem mass spectrometry for proteome and peptide profiling analysis by using a monolithic analytical capillary column.
PubMed:Monolithic porous polymer stationary phases in polyimide chips for the fast high-performance liquid chromatography separation of proteins and peptides.
PubMed:In-line system containing porous polymer monoliths for protein digestion with immobilized pepsin, peptide preconcentration and nano-liquid chromatography separation coupled to electrospray ionization mass spectroscopy.
PubMed:Synthesis and characterization of polymeric implant for kyphoplasty.
PubMed:Fast determination of prominent carotenoids in tomato fruits by CEC using methacrylate ester-based monolithic columns.
PubMed:Optimization of the porous structure and polarity of polymethacrylate-based monolithic capillary columns for the LC-MS separation of enzymatic digests.
PubMed:Polymer chains grafted "to" and "from" layered silicate clay platelets.
PubMed:Continuous full filling capillary electrochromatography: nanoparticle synthesis and evaluation.
PubMed:Final report of the safety assessment of methacrylate ester monomers used in nail enhancement products.
PubMed:Ormosil nanocomposite materials as modifiers for acrylic coating systems.
PubMed:Development of acrylate-based monolithic stationary phases for electrochromatographic separations.
PubMed:Capillary electrochromatography with a neutral monolithic column for classification of analytes and determination of basic drugs in human serum.
PubMed:Capillary high-performance liquid chromatography-electrospray ionization mass spectrometry using monolithic columns and carbon fiber electrospray ionization emitters.
PubMed:Monoliths for microfluidic devices in proteomics.
PubMed:Controlled biological response on blends of a phosphorylcholine-based copolymer with poly(butyl methacrylate).
PubMed:Capillary electrochromatography for separation of peptides driven with electrophoretic mobility on monolithic column.
PubMed:Effect of pendant chain lengths and backbone functionalities on the chemical selectivity of sulfonated amphiphilic copolymers as pseudo-stationary phases in electrokinetic chromatography.
PubMed:Crosslinkable coatings from phosphorylcholine-based polymers.
PubMed:Synthesis and characterisation of phosphorylcholine-based polymers useful for coating blood filtration devices.
PubMed:Structure-activity relationships in allergic contact dermatitis induced by methacrylates. Studies of the influence of side-chain length of methacrylates.
PubMed:Micellization of Graft Copolymers of Alkyl Methacrylates with alpha-Methyl-omega-hydroxypoly(oxyethylene) Methacrylates.
PubMed:Effect of compaction temperature on consolidation of amorphous copolymers with different glass transition temperatures.
PubMed:Surface-modulated skin layers of thermal responsive hydrogels as on-off switches: II. Drug permeation.
PubMed:Surface-modulated skin layers of thermal responsive hydrogels as on-off switches: I. Drug release.
 
Notes:
None found
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