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carbamic acid, N-1H-benzimidazol-2-yl-, methyl ester

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Name:methyl N-(1H-benzimidazol-2-yl)carbamate
CAS Number: 10605-21-7Picture of molecule3D/inchi
Other(deleted CASRN):102040-01-7
ECHA EINECS - REACH Pre-Reg:234-232-0
Nikkaji Web:J3.120H
Beilstein Number:649044
XlogP3:1.50 (est)
Molecular Weight:191.19013000
Formula:C9 H9 N3 O2
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
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Pubchem Patents:Search
Physical Properties:
Appearance:light gray or beige powder (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 300.00 °C. @ 760.00 mm Hg
Vapor Pressure:7.500000 mmHg @ 20.00 °C. (est)
Flash Point: 32.00 °F. TCC ( 0.00 °C. ) (est)
logP (o/w): 1.520
Soluble in:
 water, 29 mg/L @ 24C (exp)
 water, 2441 mg/L @ 25 °C (est)
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
Cosmetic Information:
None found
BOC Sciences
For experimental / research use only.
Odor: characteristic
Use: Carbendazim is a widely used broad-spectrum benzimidazole fungicide.
Connect Chemicals
Santa Cruz Biotechnology
For experimental / research use only.
Shiva Chemicals and Pharmaceuticals
For experimental / research use only.
Carbendazim PESTANAL®, analytical standard
Safety Information:
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-chicken LD50 1800 mg/kg
Indian Journal of Pharmacology. Vol. 18, Pg. 102, 1986.

oral-dog LD50 > 2500 mg/kg
Pesticide Manual. Vol. 9, Pg. 123, 1991.

oral-guinea pig LD50 4150 mg/kg
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 52(3), Pg. 58, 1987.

intraperitoneal-mouse LD50 1225 mg/kg
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 52(3), Pg. 58, 1987.

oral-mouse LD50 7700 mg/kg
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(5), Pg. 49, 1981.

oral-quail LD50 > 10000 mg/kg
Pesticide Manual. Vol. 9, Pg. 123, 1991.

oral-rabbit LD50 8160 mg/kg
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 52(3), Pg. 58, 1987.

intraperitoneal-rat LD50 1720 mg/kg
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 52(3), Pg. 58, 1987.

oral-rat LD50 6400 mg/kg
"Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 4, Pg. 131, 1976/1977.

Dermal Toxicity:
skin-rabbit LD50 8500 mg/kg
Indian Journal of Pharmacology. Vol. 18, Pg. 102, 1986.

skin-rat LD50 2000 mg/kg
"Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976Vol. -, Pg. -, 1971/1976.

Inhalation Toxicity:
Not determined
Safety in Use Information:
herbicides / pesticides
Recommendation for carbendazim usage levels up to:
 not for fragrance use.
Recommendation for carbendazim flavor usage levels up to:
 not for flavor use.
Safety References:
European Food Safety Authority (EFSA) reference(s):

Reasoned opinion on the review of the existing maximum residue levels (MRLs) for thiophanate-methyl and carbendazim according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf

Retrospective analysis of the immunotoxic effects of plant protection products as reported in the Draft Assessment Reports for their peer review at EU level
View page or View pdf

Reasoned opinion on the toxicological properties and maximum residue levels (MRLs) for the benzimidazole substances carbendazim and thiophanate-methyl
View page or View pdf

EPI System: View
NIOSH International Chemical Safety Cards:search
Chemical Carcinogenesis Research Information System:Search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA GENetic TOXicology:Search
EPA Substance Registry Services (TSCA):10605-21-7
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :25429
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
methyl N-(1H-benzimidazol-2-yl)carbamate
EPA/NOAA CAMEO:hazardous materials
 methyl N-(1H-benzimidazol-2-yl)carbamate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:10605-21-7
Pubchem (cid):25429
Pubchem (sid):134991270
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
KEGG (GenomeNet):C10897
HMDB (The Human Metabolome Database):HMDB31769
Export Tariff Code:2933.90.8000
•acidazim; amibendazim; bendazim; mobeedazim; carbendate; cekudazim; chemzim; chemcarb; tartan; devistin; dhanustin; ranger; carbenex; agni; eurozim-50; fertidazim; takistin; benfil; hilzim; curacarb; arrest; micfun; attention; laicar; carzim; luxazim-f; majestin; mitrosal; sharp; pacarzim; volzim; carbenzim; sicostin, fungy; protek; unisol; vicarben; zen. •aqueous suspension, water dispersible granules and a wettable powder. •discontinued names: mastiff; ponnax; corbel triple; corbel duo; bavistin; bavical; bavical f; cosmic; prodazim; occidor plus; raydor; delsene; delsene m; bolda; kombat; masolon; bravocarb; azidro; akozim; silcarbon; silear. •derosal (agrevo) •carbate (pan brittanica) •cekudazim (cequisa) •available in wettable powder formulations or dispersions that contain from 6-70% active ingredient, the balance is either inert ingredients or other fungicides. •usepaopp pesticide code 128872; trade names: e-965; bas 3460; derosal; kemdazin; u-32.104; equitdazin; and pillarstin. •fb642(methyl-2-benzimidazolecarbamate, carbendazim)[hammond la et al; j cancer res clin oncol 127(5): 301-13 (2001)] pubmed abstract
Potential Blenders and core components note
None Found
Potential Uses:
None Found
Occurrence (nature, food, other):note
 not found in nature
 antibac MF
 bavistin 3460
 BCM (fungicide)
1H-benzimidazol-2-ylcarbamic acid methyl ester
1H-benzimidazol-2-ylcarbamic acid, methyl ester
 benzimidazole carbamate de methyle
 benzimidazole-2-carbamic acid, methyl ester
1H-benzimidazole-2-carbamic acid, methyl ester
2-benzimidazolecarbamic acid, methyl ester
 BMK (fungicide)
 carbamic acid, 1H-benzimidazol-2-yl-, methyl ester
 carbamic acid, N-1H-benzimidazol-2-yl-, methyl ester
 carben VL
 funaben 3
 funaben 50
 kolfugo 25 FW
 methyl 1H-benzimidazol-2-ylcarbamate (9CI)
 methyl 1H-benzimidazole-2-carbamate
 methyl 2-benzimidazolecarbamate
 methyl benzimidazol-2-ylcarbamate
 methyl benzimidazolylcarbamate
 methyl N-(1H-benzimidazol-2-yl)carbamate
 methyl N-2-benzimidazolecarbamate
 preparation G 665
 preventol BCM


PubMed:Development and verification for analysis of pesticides in eggs and egg products using QuEChERS and LC-MS/MS.
PubMed:[Laser Raman spectrum analysis of carbendazim pesticide].
PubMed:Sensitive determination of carbendazim in orange juice by electrode modified with hybrid material.
PubMed:Fungicide Sensitivity and Characterization of Cobweb Disease on a Pleurotus eryngii Mushroom Crop Caused by Cladobotryum mycophilum.
PubMed:Design, synthesis, antifungal, and antioxidant activities of (E)-6-((2-phenylhydrazono)methyl)quinoxaline derivatives.
PubMed:Kinetics of degradation of carbendazim by B. subtilis strains: possibility of in situ detoxification.
PubMed:Small changes result in large differences: discovery of (-)-incrustoporin derivatives as novel antiviral and antifungal agents.
PubMed:Genetic relationships, carbendazim sensitivity and mycotoxin production of the Fusarium graminearum populations from maize, wheat and rice in eastern China.
PubMed:Pesticide monitoring in the basin of Llobregat River (Catalonia, Spain) and comparison with historical data.
PubMed:Potential involvement of chemicals in liver cancer progression: an alternative toxicological approach combining biomarkers and innovative technologies.
PubMed:Wightianines A-E, dihydro-β-agarofuran sesquiterpenes from Parnassia wightiana, and their antifungal and insecticidal activities.
PubMed:Antifungal activity of compounds extracted from Cortex Pseudolaricis against Colletotrichum gloeosporioides.
PubMed:Pesticide residues in fruits and vegetables from the Aegean region, Turkey.
PubMed:Synthesis and Antifungal Activity of Nicotinamide Derivatives as Succinate Dehydrogenase Inhibitors.
PubMed:Secondary metabolites from the endophytic Botryosphaeria dothidea of Melia azedarach and their antifungal, antibacterial, antioxidant, and cytotoxic activities.
PubMed:Pesticide residue analysis in parsley, lettuce and spinach by LC-MS/MS.
PubMed:An integrated approach for the reduction of aflatoxin contamination in chilli (Capsicum annuum L.).
PubMed:Determination of pesticide residue transfer rates (percent) from dried tea leaves to brewed tea.
PubMed:Ultra-high performance liquid chromatography/ electrospray ionization-tandem mass spectrometry determination of 151 pesticides in soybeans and pulses.
PubMed:Occurrence and removal efficiency of pesticides in sewage treatment plants of four Mediterranean River Basins.
PubMed:Influence of different planting seasons of six leaf vegetables on residues of five pesticides.
PubMed:Synthesis and biological evaluation of benzofuroxan derivatives as fungicides against phytopathogenic fungi.
PubMed:Comparisons of metabolic and physiological changes in rats following short term oral dosing with pesticides commonly found in food.
PubMed:Molecular characterization, fitness and mycotoxin production of benzimidazole-resistant isolates of Penicillium expansum.
PubMed:Accumulation and half-lives of 13 pesticides in muscle tissue of freshwater fishes through food exposure.
PubMed:Antifungal activities of metabolites produced by a termite-associated Streptomyces canus BYB02.
PubMed:The inhibin B (InhB) response to the testicular toxicants mono-2-ethylhexyl phthalate (MEHP), 1,3 dinitrobenzene (DNB), or carbendazim (CBZ) following short-term repeat dosing in the male rat.
PubMed:Capillary electrophoresis coupled to mass spectrometry for the determination of anthelmintic benzimidazoles in eggs using a QuEChERS with preconcentration as sample treatment.
PubMed:Simple multiresidue extraction method for the determination of fungicides and plant growth regulator in bean sprouts using low temperature partitioning and tandem mass spectrometry.
PubMed:Investigation of pesticide residues in vegetables and fruits grown in various regions of Hatay, Turkey.
PubMed:[Benzimidazole and its derivatives--from fungicides to designer drugs. A new occupational and environmental hazards].
PubMed:Monitoring and risk assessment of pesticide residues in yuza fruits (Citrus junos Sieb. ex Tanaka) and yuza tea samples produced in Korea.
PubMed:Pesticide pressure and fish farming in barrage pond in Northeastern France. Part II: residues of 13 pesticides in water, sediments, edible fish and their relationships.
PubMed:Determination of fungicide residues in baby food by liquid chromatography-ion trap tandem mass spectrometry.
PubMed:Organic micropollutants in rivers downstream of the megacity Beijing: sources and mass fluxes in a large-scale wastewater irrigation system.
PubMed:Effect of home processing on the distribution and reduction of pesticide residues in apples.
PubMed:Protocol for an electrospray ionization tandem mass spectral product ion library: development and application for identification of 240 pesticides in foods.
PubMed:[Determination of thiophanate-methyl and carbendazim in cucumber and soil by QuEChERS-high performance liquid chromatography-triple quadrupole tandem mass spectrometry].
PubMed:Total diet study on pesticide residues in France: levels in food as consumed and chronic dietary risk to consumers.
PubMed:Determination of pesticide residues in wine by membrane-assisted solvent extraction and high-performance liquid chromatography-tandem mass spectrometry.
PubMed:Occurrence and distribution study of residues from pesticides applied under controlled conditions in the field during rice processing.
PubMed:Effect of household and industrial processing on the levels of pesticide residues and degradation products in melons.
PubMed:Pesticide pressure and fish farming in barrage pond in northeastern France. Part III: how management can affect pesticide profiles in edible fish?
PubMed:Metabolites from Aspergillus fumigatus, an endophytic fungus associated with Melia azedarach, and their antifungal, antifeedant, and toxic activities.
PubMed:[Rapid determination of 6 pesticide residues in tomato paste by ultra performance liquid chromatography-tandem mass spectrometry].
PubMed:Role of fungicides, application of nozzle types, and the resistance level of wheat varieties in the control of Fusarium head blight and deoxynivalenol.
PubMed:Carbendazim combined with imazalil or cypermethrin potentiate DNA damage in hepatocytes of mice.
PubMed:Determination of sixteen pesticides in peppers using high-performance liquid chromatography/mass spectrometry.
PubMed:Determination of carbendazim, thiophanate, thiophanate-methyl and benomyl residues in agricultural products by liquid chromatography-tandem mass spectrometry.
PubMed:Dissipation and distribution behavior of azoxystrobin, carbendazim, and difenoconazole in pomegranate fruits.
PubMed:Cumulative risk assessment of chemical exposures in urban environments.
PubMed:Physico-chemical, respiratory and fungicide residue changes in wax coated mandarin fruit stored at chilling temperature with intermittent warming.
PubMed:Effect of anilinopyrimidine resistance on aflatoxin production and fitness parameters in Aspergillus parasiticus Speare.
PubMed:Reducing the impact of pesticides on biological control in Australian vineyards: pesticide mortality and fecundity effects on an indicator species, the predatory mite Euseius victoriensis (Acari: Phytoseiidae).
PubMed:Realistic approach of pesticide residues and French consumer exposure within fruit & vegetable intake.
PubMed:A selective spectrofluorimetric method for carbendazim determination in oranges involving inclusion-complex formation with cucurbit[7]uril.
PubMed:Dissipation study of thiophanate methyl residue in/on grapes (Vitis vinifera L.) in India.
PubMed:Quantification, confirmation and screening capability of UHPLC coupled to triple quadrupole and hybrid quadrupole time-of-flight mass spectrometry in pesticide residue analysis.
PubMed:Simultaneous analysis of thiabendazole, carbendazim and 2-aminobenzimidazole in concentrated fruit juices by liquid chromatography after a single mix-mode solid-phase extraction cleanup.
PubMed:Hollow fiber-liquid-phase microextraction of fungicides from orange juices.
PubMed:Determination of pesticide residues in integrated pest management and nonintegrated pest management samples of apple (Malus pumila Mill.).
PubMed:Mutations in a beta-tubulin confer resistance of Gibberella zeae to benzimidazole fungicides.
PubMed:[Determination of carbendazim residue in orange and soil using high performance liquid chromatography].
PubMed:Efficacy of Lippia alba (Mill.) N.E. Brown essential oil and its monoterpene aldehyde constituents against fungi isolated from some edible legume seeds and aflatoxin B1 production.
PubMed:Brassinosteroids promote metabolism of pesticides in cucumber.
PubMed:Bayesian modeling of measurement errors and pesticide concentration in dietary risk assessments.
PubMed:Determination of pesticide residues in fruit-based soft drinks.
PubMed:Predictive assessment of ochratoxin A accumulation in grape juice based-medium by Aspergillus carbonarius using neural networks.
PubMed:Detection of carbendazim by surface-enhanced Raman scattering using cyclodextrin inclusion complexes on gold nanorods.
PubMed:[Determination of benomyl, carbendazim and thiabendazole in apple juice concentrate using solid-phase extraction coupled with ion exchange chromatography].
PubMed:Quantification of Fusarium graminearum in harvested grain by real-time polymerase chain reaction to assess efficacies of fungicides on fusarium head blight, deoxynivalenol contamination, and yield of winter wheat.
PubMed:Carbendazim inhibits cancer cell proliferation by suppressing microtubule dynamics.
PubMed:Impact of postharvest disease control methods and cold storage on volatiles, color development and fruit quality in ripe 'kensington pride' mangoes.
PubMed:Spectrofluorimetric determination of benzoimidazolic pesticides: effect of p-sulfonatocalix[6]arene and cyclodextrins.
PubMed:Atmospheric pressure glow discharge desorption mass spectrometry for rapid screening of pesticides in food.
PubMed:Design, synthesis, and fungicidal activity of macrolactones and macrolactams with a sulfonamide side chain.
PubMed:Multiresidue method for fast determination of pesticides in fruit juices by ultra performance liquid chromatography coupled to tandem mass spectrometry.
PubMed:Assessing the risk to U.K. children from carbendazim residues in apple products.
PubMed:Determination of pesticide residues in IPM and non-IPM samples of mango (Mangifera indica).
PubMed:Multi-residue analysis of traces of pesticides and antibiotics in honey by HPLC-MS-MS.
PubMed:A sensitive determination method for carbendazim and thiabendazole in apples by solid-phase microextraction-high performance liquid chromatography with fluorescence detection.
PubMed:[Study on usage of pesticides in various countries].
PubMed:Determination of postharvest fungicides in fruit juices by solid-phase extraction followed by liquid chromatography electrospray time-of-flight mass spectrometry.
PubMed:Multiple pesticide analysis in wine by MEKC combined with solid-phase microextraction and sample stacking.
PubMed:Effect of carbendazim and physicochemical factors on the growth and ochratoxin A production of Aspergillus carbonarius isolated from grapes.
PubMed:Analysis of pesticide multi-residues in leafy vegetables by ultrasonic solvent extraction and liquid chromatography-tandem mass spectrometry.
PubMed:Analyses of pesticide residues in fruit-based baby food by liquid chromatography/electrospray ionization time-of-flight mass spectrometry.
PubMed:MEKC combined with SPE and sample stacking for multiple analysis of pesticides in water samples at the ng/L level.
PubMed:Comprehensive multi-residue method for the target analysis of pesticides in crops using liquid chromatography-tandem mass spectrometry.
PubMed:On-line preconcentration strategies for analyzing pesticides in fruits and vegetables by micellar electrokinetic chromatography.
PubMed:Determination of carbendazim residues in the eggs, liver and pectoral muscle of Japanese quail (Coturnix coturnix japonica).
PubMed:Determination of pesticides in soy-based infant formula using liquid chromatography with electrospray ionization tandem mass spectrometry.
PubMed:[Determination of carbendazim and thiabendazole in tomatoes by solid-phase microextraction coupled with high performance liquid chromatography and fluorescence detection].
PubMed:Effects of the benzoxazolinone BOA, selected degradation products and structure related pesticides on soil organisms.
PubMed:Determination of carbendazim residues in fruit juices by liquid chromatography-tandem mass spectrometry.
PubMed:Screening and evaluation of fruit samples for four pesticide residues.
PubMed:Investigation into the validity of extrapolation in setting maximum residue levels for pesticides in crops of similar morphology.
PubMed:Fate of pesticides during the winemaking process in relation to malolactic fermentation.
PubMed:Determination of pesticides in apple-based infant foods using liquid chromatography electrospray ionization tandem mass spectrometry.
PubMed:Modeling the dietary pesticide exposures of young children.
PubMed:Application of micellar electrokinetic capillary chromatography to the analysis of uncharged pesticides of environmental impact.
PubMed:Repeated dose 28-day oral toxicity study in Wistar rats with a mixture of five pesticides often found as residues in food: alphacypermethrin, bromopropylate, carbendazim, chlorpyrifos and mancozeb.
PubMed:Ring-testing and field-validation of a terrestrial model ecosystem (TME)--an instrument for testing potentially harmful substances: effects of carbendazim on nematodes.
PubMed:Assessing N,N'-Dibutylurea (DBU) formation in soils after application of n-butylisocyanate and benlate fungicides.
PubMed:Microwave-assisted extraction for the simultaneous determination of thiamethoxam, imidacloprid, and carbendazim residues in fresh and cooked vegetable samples.
PubMed:Carbendazim and metalaxyl residues in post-harvest treated apples.
PubMed:Occurrence of pesticide residues in mushrooms in Northern Ireland, July 1997-January 1999.
PubMed:Cynodontin: a fungal metabolite with antifungal properties.
PubMed:Modeling of single-step and multistep adsorption isotherms of organic pesticides on soil.
PubMed:Subcritical water extraction to evaluate desorption behavior of organic pesticides in soil.
PubMed:Is the application of carbendazim harmful to healthy plants? Evidence of weak phytotoxicity in tobacco.
PubMed:Complexation of several benzimidazole-type fungicides with alpha- and beta-cyclodextrins.
PubMed:Focused microwave assistance for extracting some pesticide residues from strawberries into water before their determination by SPME/HPLC/DAD.
PubMed:Pesticide residues in oranges from Valencia (Spain).
PubMed:Direct action of the biocide carbendazim on phenolic metabolism in tobacco plants.
PubMed:An LC/MS/MS method for improved quantitation of the bound residues in the tissues of animals orally dosed with [(14)C]Benomyl.
PubMed:Determination of imidacloprid and benzimidazole residues in fruits and vegetables by liquid chromatography-mass spectrometry after ethyl acetate multiresidue extraction.
PubMed:Effect of temperature and humidity on the formation of dibutylurea in benlate fungicide.
PubMed:Kuwait's total diet study: dietary intake of organochlorine, carbamate, benzimidazole and phenylurea pesticide residues.
PubMed:Automated method for cleanup and determination of benomyl and thiabendazole in table-ready foods.
PubMed:Hydrogen peroxide causes RAD9-dependent cell cycle arrest in G2 in Saccharomyces cerevisiae whereas menadione causes G1 arrest independent of RAD9 function.
PubMed:Developmental toxicity of carbendazim: comparison of no-observed-adverse-effect level and benchmark dose approach.
PubMed:High-performance liquid chromatographic determination of benomyl and carbendazim residues in apiarian samples.
PubMed:Chromatographic analysis of imazalil and carbendazim in fruits. Method validation and residue monitoring program 1995.
PubMed:Changes of bromopropylate and carbendazim residues during processing of apples into apple puree.
PubMed:Determination of thiabendazole in fruits and vegetables by competitive-inhibition enzyme immunoassay.
PubMed:Determination of methyl 2-benzimidazolecarbamate in bulk fruit juice concentrates by competitive-inhibition enzyme immunoassay.
PubMed:Genetic toxicity of a mixture of fifteen pesticides commonly found in the Italian diet.
PubMed:Determination of methyl 2-benzimidazolecarbamate in wine by competitive inhibition enzyme immunoassay.
PubMed:Comparison of HPTLC and HPLC procedures for the determination of certain xenobiotic residues in apples and pears.
PubMed:Determination of carbendazim in blueberries by reversed-phase high-performance liquid chromatography.
PubMed:Inhibitory action of benzimidazole fungicides on the in vivo incorporation of [3H]thymidine in various organs of the mouse.
PubMed:Ion-pairing liquid chromatographic determination of benzimidazole fungicides in foods.
PubMed:The feasibility of using Chinese hamsters as an animal model for aneuploidy.
PubMed:[Toxicological evaluation of pesticide and chemical residues in control of biological processes in vegetables under glass and plastics].
PubMed:Pesticides and other chemical residues in Dutch total diet samples (June 1976-July 1978).
PubMed:Simultaneous dermal exposure to captan and benomyl by strawberry harvesters.
PubMed:[Orienting residue test of post-harvest treated white cabbage heads for benomoyl/carbendazim].
PubMed:Determination of thiophanate methyl as carbendazin by high-pressure liquid chromatography: application to onions and cabbage.
PubMed:Determination of methyl 2-benzimidazolylcarbamate in black walnut fruit.
PubMed:Fate of benomyl and its degradation compound methyl 2-benzimidazolecarbamate on apple foliage.
PubMed:a radioimmunoassay for benomyl and methyl 2-benzimidazolecarbamate on food crops.
PubMed:Determination of benomyl, carbendazim and 2-aminobenzimidazole (2-ab) in plant materials. Part I: Apples, red-currants, grapes, kale and sugar beets.
carcinogen when combined with sodium nitrite; principle metabolite of thiophanate methyl & benomyl. Systemic agricultural and horticultural fungicide
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