EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

ceric ammonium nitrate
cerate(2-), hexakis(nitrato-O)-, diammonium, (OC-6-11)-

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Name:diazanium;cerium(4+);hexanitrate
CAS Number: 16774-21-3Picture of molecule3D/inchi
Other(deleted CASRN):1807482-78-5
ECHA EINECS - REACH Pre-Reg:240-827-6
FDA UNII: U99S55ED6B
MDL:MFCD00151121
Molecular Weight:548.22136000
Formula:Ce H8 N8 O18
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:pharmaceuticals / chemical synthisis
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
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Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Appearance:yellow to reddish brown powder (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Flash Point: 32.00 °F. TCC ( 0.00 °C. ) (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
Carbosynth
For experimental / research use only.
Ceric Ammonium Nitrate
ECSA Chemicals
DIAMMONIUM HEXANITRATOCERATE
ECSA TRADE THE MOST UPDATED FINANCIAL PUBLICATION ON THE WORLD OF CHEMISTRY
Santa Cruz Biotechnology
For experimental / research use only.
Ammonium cerium(IV) nitrate ≥98%
Sigma-Aldrich: Aldrich
For experimental / research use only.
Ammonium cerium(IV) nitrate ≥99.99% trace metals basis
sds
TCI AMERICA
For experimental / research use only.
Ammonium Cerium(IV) Nitrate >98.0%(T)
sds
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
pharmaceuticals / chemical synthisis
Recommendation for ceric ammonium nitrate usage levels up to:
 not for fragrance use.
 
Recommendation for ceric ammonium nitrate flavor usage levels up to:
 not for flavor use.
 
Safety References:
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):16774-21-3
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :56841022
National Institute of Allergy and Infectious Diseases:Data
diazanium;cerium(4+);hexanitrate
Chemidplus:0016774213
 
References:
 diazanium;cerium(4+);hexanitrate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:16774-21-3
Pubchem (cid):56841022
Pubchem (sid):135116155
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2846.10.0050
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 ammonium ceric nitrate
 ammonium cerium nitrate
 ammonium cerium(IV) nitrate
 cerate(2-), hexakis(nitrato-kappaO)-, ammonium (1:2), (OC-6-11)-
 cerate(2-), hexakis(nitrato-kappaO)-, diammonium, (OC-6-11)-
 cerate(2-), hexakis(nitrato-O)-, diammonium, (OC-6-11)-
 cerate(2-), hexanitrato-, diammonium (8CI)
 cericammoniumnitrate
 cerium ammonium nitrate
 diammonium cerium hexanitrate
 diammonium hexanitratocerate
 diammonium hexanitratocerate(2-)
 

Articles:

PubMed:Electrocatalytic Oxygen Evolution with an Immobilized TAML Activator.
PubMed:Comparative studies on the removal of heavy metals ions onto cross linked chitosan-g-acrylonitrile copolymer.
PubMed:Efficient carbon-Ferrier rearrangement on glycals mediated by ceric ammonium nitrate: Application to the synthesis of 2-deoxy-2-amino-C-glycoside.
PubMed:Sorption studies on Cr (VI) removal from aqueous solution using cellulose grafted with acrylonitrile monomer.
PubMed:High Surface Area Ceria for CO Oxidation Prepared from Cerium t-Butoxide by Combined Sol-Gel and Solvothermal Processing.
PubMed:A facile synthesis of N-H- and N-substituted acridine-1,8-diones under sonic condition.
PubMed:[Surface modification of polyvinylidene fluoride (PVDF) membrane by using the zwitterionic substance].
PubMed:Semi-interpenetrating network of acrylamide-grafted-sodium alginate microspheres for controlled release of diclofenac sodium, preparation and characterization.
PubMed:A novel polymeric flocculant based on polyacrylamide grafted inulin: aqueous microwave assisted synthesis.
PubMed:One-pot tandem synthesis of 2-arylquinazolines by a multicomponent cyclization reaction.
PubMed:Development of poly(N-isopropylacrylamide)/alginate copolymer hydrogel-grafted fabrics embedding of berberine nanosuspension for the infected wound treatment.
PubMed:Use of a readily removable auxiliary group for the synthesis of pyrrolidones by the palladium-catalyzed intramolecular amination of unactivated γ C(sp(3))-H bonds.
PubMed:Synthesis and characterization of noncytotoxic and biodegradable polymethacrylates-grafted chitosan gels.
PubMed:Microwave assisted synthesis of acrylamide grafted locust bean gum and its application in drug delivery.
PubMed:A novel and efficient synthesis of diverse dihydronaphtho[1,2-b]furans using the ceric ammonium nitrate-catalyzed formal [3 + 2] cycloaddition of 1,4-naphthoquinones to olefins and its application to furomollugin.
PubMed:Towards the chemoenzymatic synthesis of heparan sulfate oligosaccharides: Oxidative cleavage of p-nitrophenyl group with ceric ammonium salts.
PubMed:Syntheses, structures and properties of ruthenium complexes of tridentate ligands: isolation and characterization of a rare example of ruthenium nitrosyl complex containing {RuNO}5 moiety.
PubMed:A facile synthesis, anti-inflammatory and analgesic activity of isoxazolyl-2,3-dihydrospiro[benzo[f]isoindole-1,3'-indoline]-2',4,9-triones.
PubMed:Ceric ion initiated synthesis of polyacrylamide grafted oatmeal: Its application as flocculant for wastewater treatment.
PubMed:Synthesis and grafting of CAN-derived tetravalent cerium alkoxide silylamide precursors onto mesoporous silica MCM-41.
PubMed:Redox mediator effect on water oxidation in a ruthenium-based chromophore-catalyst assembly.
PubMed:Synthesis and characterization of multi-amino-functionalized cellulose for arsenic adsorption.
PubMed:Synthesization, characterization and adsorption properties of sulfonic cellulose.
PubMed:The synthesis of the pyranonaphthoquinones dehydroherbarin and anhydrofusarubin using Wacker oxidation methodology as a key step and other unexpected oxidation reactions with ceric ammonium nitrate and salcomine.
PubMed:Polyacrylamide grafted Agar: synthesis and applications of conventional and microwave assisted technique.
PubMed:Nano-sized manganese oxide: a proposed catalyst for water oxidation in the reaction of some manganese complexes and cerium(IV) ammonium nitrate.
PubMed:Concise route to a series of novel 3-(tetrazol-5-yl)quinoxalin-2(1H)-ones.
PubMed:Study of polyacrylamide grafted starch based algal flocculation towards applications in algal biomass harvesting.
PubMed:Cr(VI) adsorption from electroplating plating wastewater by chemically modified coir pith.
PubMed:Ultrasound assisted synthesis of tetrahydrobenzo[c]xanthene-11-ones using CAN as catalyst.
PubMed:Ceric ammonium nitrate-promoted oxidative coupling reaction for the synthesis and evaluation of a series of anti-tumor amide anhydrovinblastine analogs.
PubMed:Evolution of iridium-based molecular catalysts during water oxidation with ceric ammonium nitrate.
PubMed:Copper(II)-mediated oxidative transformation of vic-dioxime to furoxan: evidence for a copper(II)-dinitrosoalkene intermediate.
PubMed:The synthesis of xanthones, xanthenediones, and spirobenzofurans: their antibacterial and antifungal activity.
PubMed:Electrochemical impedance spectroscopy as a highly sensitive tool for a dynamic interaction study between heparin and antithrombin: a novel antithrombin sensor.
PubMed:Microwave assisted synthesis of polyacrylamide grafted agar (Ag-g-PAM) and its application as flocculant for wastewater treatment.
PubMed:Ceric ammonium nitrate-catalyzed azidation of 1,2-anhydro sugars: application in the synthesis of structurally diverse sugar-derived morpholine 1,2,3-triazoles and 1,4-oxazin-2-ones.
PubMed:Highly regioselective [3 + 2] annulation of azomethine imines with 1-alkynyl Fischer carbene complexes to functionalized N,N-bicyclic pyrazolidin-3-ones.
PubMed:Oxidation of 4-methoxyanilines to 1,4-benzoquinones using ceric ammonium nitrate (CAN).
PubMed:Hydroxyethylcellulose-graft-poly(2-(dimethylamino)ethyl methacrylate) as physically adsorbed coating for protein separation by CE.
PubMed:Flow injection colorimetric method using acidic ceric nitrate as reagent for determination of ethanol.
PubMed:Adsorption of chromium (VI) from aqueous solutions by cellulose modified with β-CD and quaternary ammonium groups.
PubMed:Adsorption-desorption properties and characterization of crosslinked Konjac glucomannan-graft-polyacrylamide-co-sodium xanthate.
PubMed:CAN-mediated oxidations for the synthesis of xanthones and related products.
PubMed:Synthesis of atromentin and its O-alkylated natural products.
PubMed:Microwave assisted synthesis of polyacrylamide grafted starch (St-g-PAM) and its applicability as flocculant for water treatment.
PubMed:Synthesis of 2-oxo/thioxooctahydroquinazolin-5-one derivatives and their evaluation as anticancer agents.
PubMed:A comparative study on the graft copolymerization of acrylic acid onto rayon fibre by a ceric ion redox system and a γ-radiation method.
PubMed:Aggregation control of hydrophilic maghemite (gamma-Fe2O3) nanoparticles by surface doping using cerium atoms.
PubMed:Cp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry.
PubMed:Fast water oxidation using iron.
PubMed:Mechanism of N(5)-ethyl-flavinium cation formation upon electrochemical oxidation of N(5)-ethyl-4a-hydroxyflavin pseudobase.
PubMed:Films of dextran-graft-polybutylmethacrylate to enhance endothelialization of materials.
PubMed:Synthesis and characterization of poly(vinyl alcohol) membranes with quaternary ammonium groups for wound dressing.
PubMed:Diversity-oriented synthesis of quinolines via Friedländer annulation reaction under mild catalytic conditions.
PubMed:Diversity oriented synthesis of benzoxanthene and benzochromene libraries via one-pot, three-component reactions and their anti-proliferative activity.
PubMed:Hydroxyethylcellulose-graft-poly (4-vinylpyridine) as a novel, adsorbed coating for protein separation by CE.
PubMed:Synthesis and antiviral activity of 4,4'-(arylmethylene)bis(1H-pyrazol-5-ols) against peste des petits ruminant virus (PPRV).
PubMed:FerriBRIGHT: a rationally designed fluorescent probe for redox active metals.
PubMed:Controlled release of theophylline through semi-interpenetrating network microspheres of chitosan-(dextran-g-acrylamide).
PubMed:Graft copolymerization onto cellulose-based filter paper and its further development as silver nanoparticles loaded antibacterial food-packaging material.
PubMed:Facile Route to Tetrasubstituted Pyrazoles Utilizing Ceric Ammonium Nitrate.
PubMed:Synthesis and characterization of a new polysaccharide-graft-polymethacrylate copolymer for three-dimensional hybrid hydrogels.
PubMed:[Synthesis, characterization and antimicrobial activity of konjac glucomannan derivative with quaternary ammonium salts].
PubMed:Formation of gamma-lactones through CAN-mediated oxidative cleavage of hemiketals.
PubMed:Microelectrode arrays and ceric ammonium nitrate: a simple strategy for developing new site-selective synthetic methods.
PubMed:Synthesis of crosslinked starch-graft-polyacrylamide-co-sodium xanthate and its performances in wastewater treatment.
PubMed:Spectrophotometric determination of plutonium in highly radioactive liquid waste using an internal standardization technique with neodymium(III).
PubMed:A ceric ammonium nitrate N-dearylation of N-p-anisylazoles applied to pyrazole, triazole, tetrazole, and pentazole rings: release of parent azoles. generation of unstable pentazole, HN5/N5-, in solution.
PubMed:Green and efficient synthesis of quinoxaline derivatives via ceric ammonium nitrate promoted and in situ aerobic oxidation of alpha-hydroxy ketones and alpha-keto oximes in aqueous media.
PubMed:Synthesis of novel N-(4-ethoxyphenyl) azetidin-2-ones and their oxidative N-deprotection by ceric ammonium nitrate.
PubMed:Synthesis of novel N-sulfonyl monocyclic beta-lactams as potential antibacterial agents.
PubMed:Chromium(III) removal from water and wastewater using a carboxylate-functionalized cation exchanger prepared from a lignocellulosic residue.
PubMed:An efficient and general approach to beta-functionalized ketones.
PubMed:Imidazolium ionic liquids as solvents for cerium(IV)-mediated oxidation reactions.
PubMed:Synthesis of new phytogrowth-inhibitory substituted aryl-p-benzoquinones.
PubMed:Isomerization of triphenylmethoxyl and 1,1-diphenylethoxyl radicals. Revised assignment of the electron-spin resonance spectra of purported intermediates formed during the ceric ammonium nitrate mediated photooxidation of aryl carbinols.
PubMed:Whole genome expression profiling using DNA microarray for determining biocompatibility of polymeric surfaces.
PubMed:Ceric ammonium nitrate promoted oxidation of oxazoles.
PubMed:Novel interpenetrating network chitosan-poly(ethylene oxide-g-acrylamide) hydrogel microspheres for the controlled release of capecitabine.
PubMed:2-(Quinazolin-4-ylamino)-[1,4]benzoquinones as covalent-binding, irreversible inhibitors of the kinase domain of vascular endothelial growth factor receptor-2.
PubMed:A stepwise degradation of sterically hindered CpCo-cyclobutadiene complexes.
PubMed:Structure-reactivity relationships in oxidative carbon-carbon bond forming reactions: a mild and efficient approach to stereoselective syntheses of 2,6-disubstituted tetrahydropyrones.
PubMed:CYP 17 and CYP 19 inhibitors. Evaluation of fluorine effects on the inhibiting activity of regioselectively fluorinated 1-(Naphthalen-2-ylmethyl)imidazoles.
PubMed:Catalytic ceric ammonium nitrate mediated synthesis of 2-deoxy-1-thioglycosides.
PubMed:Correlation of the oxidation state of cerium in sol-gel glasses as a function of thermal treatment via optical spectroscopy and XANES studies.
PubMed:Aminoxyl radicals as crosslinks for macromolecules of polyvinylpyrrolidone.
PubMed:Recent advances in synthetic transformations mediated by cerium(IV) ammonium nitrate.
PubMed:Building functionalized peptidomimetics: new electroauxiliaries and the use of a chemical oxidant for introducing N-acyliminium ions into peptides.
PubMed:Synthesis of 3-azido-2,3,6-trideoxy-beta-D-arabino-hexopyranosyl pyranonaphthoquinone analogues of medermycin.
PubMed:Platelet adhesive resistance of segmented polyurethane film surface-grafted with vinyl benzyl sulfo monomer of ammonium zwitterions.
PubMed:Oxidative 5-endo cyclization of enamides mediated by ceric ammonium nitrate.
PubMed:First generation of pentazole (HN5, pentazolic acid), the final azole, and a zinc pentazolate salt in solution: A new N-dearylation of 1-(p-methoxyphenyl) pyrazoles, a 2-(p-methoxyphenyl) tetrazole and application of the methodology to 1-(p-methoxyphenyl) pentazole.
PubMed:Temperature-responsive cellulose by ceric(IV) ion-initiated graft copolymerization of N-isopropylacrylamide.
PubMed:Novel synthesis of 2-arylbenzothiazoles mediated by ceric ammonium nitrate (CAN): a rebuttal.
PubMed:Graft copolymerization of ethyl acrylate onto cellulose using ceric ammonium nitrate as initiator in aqueous medium.
PubMed:Addition of malonyl radicals to glycals with C-1 acceptor groups: remarkable influence of the substituents on the product distribution.
PubMed:Novel synthesis of 2-arylbenzothiazoles mediated by ceric ammonium nitrate (CAN).
PubMed:A new precursor for the radiosynthesis of [18F]FLT.
PubMed:Synthesis, characterization and platelet adhesion of segmented polyurethanes grafted phospholipid analogous vinyl monomer on surface.
PubMed:Graft copolymerization of acrylonitrile and ethyl methacrylate comonomers on cellulose using ceric ions.
PubMed:Ceric ammonium nitrate-catalyzed tetrahydropyranylation of alcohols and synthesis of 2-deoxy-o-glycosides.
PubMed:A Facile Access to Polycyclic Homo- and Heteroaromatic Hydrocarbons Based on the Ceric Ammonium Nitrate-Promoted Oxidative Addition of 3-Aryl-1-[(trimethylsilyl)oxy]cyclohexenes to Ethyl Vinyl Ether.
PubMed:Efficient Total Synthesis of (-)-Ilimaquinone.
PubMed:Synthesis and antiviral activity of novel 5-(1-cyanamido-2-haloethyl) and 5-(1-hydroxy(or methoxy)-2-azidoethyl) analogues of uracil nucleosides.
PubMed:A very efficient method to cleave Lipid A and saccharide components in bacterial lipopolysaccharides.
PubMed:Exploring a benzyloxyaniline linker utilizing ceric ammonium nitrate (CAN) as a cleavage reagent: solid-phase synthesis of N-unsubstituted beta-lactams and secondary amides.
PubMed:Ceric ammonium nitrate on silica gel for efficient and selective removal of trityl and silyl groups
PubMed:[Oxidative determination of hydroxyamphetamine in drops using flow injection analysis].
PubMed:Iodoacetoxylation of glycals using cerium(IV) ammonium nitrate, sodium iodide, and acetic acid: stereoselective synthesis of 2-deoxy-2-iodo-alpha-mannopyranosyl acetates.
PubMed:Characterization, via ESR spectroscopy, of radical intermediates in the photooxidation of arylcarbinols by ceric ammonium nitrate
PubMed:Spectrophotometric determination of methoxamine using cerium(IV) in presence of sodium lauryl sulphate and rhodamine-B.
PubMed:Stereoselective Synthesis of Dihydropyran-4-ones via a Formal Hetero Diels-Alder Reaction and Ceric Ammonium Nitrate Dehydrogenation.
PubMed:Synthesis of 2,3-Substituted Cycloalkanones by Ceric Ammonium Nitrate-Promoted Oxidative Tandem Additions of 1-Ethoxy-1-[(Trimethylsilyl)oxy]cyclopropane to alpha,beta-Unsaturated Cycloalkenones.
PubMed:Oxidation of dimethoxylated aromatic compounds by lignin peroxidase from Phanerochaete chrysosporium.
PubMed:Preparative chemical methods for aromatization of 19-nor-delta 4-3-oxosteroids.
PubMed:An efficient asymmetric synthesis of diacylglycerols.
PubMed:Synthesis, antitumor evaluation and SAR of new 1H-pyrrolo [3,2-c] quinoline-6,9-diones and 11H-indolo [3,2-c] quinoline-1,4-diones.
PubMed:Synthesis and antiviral activity of 5-thien-2-yl-2'-deoxyuridine analogues.
PubMed:Lignified materials as medicinal resources. V. Anti-HIV (human immunodeficiency virus) activity of some synthetic lignins.
PubMed:5-Quinone derivatives of 2'-deoxyuridine 5'-phosphate: inhibition and inactivation of thymidylate synthase, antitumor cell, and antiviral studies.
PubMed:Synthesis and antimicrobial evaluation of bicyclomycin analogues.
PubMed:On reaction of sterol hydroperoxides with superoxide.
PubMed:A colorimetric method of determining the presence of ethanol in the blood by the use of ceric ammonium nitrate as a color reagent.
PubMed:Identification and quantitation of alpha-hydroxy and alpha-keto acids with a ceric ammonium nitrate reagent.
PubMed:[Analysis of opium alkaloids and the allied compounds. XV. Colorimetric determination of dihydrocodeine by ceric ammonium nitrate 2,4-dinitrophenylhydrazine].
 
Notes:
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