EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes

allyl methacrylate
methacrylic acid, allyl ester

Supplier Sponsors

Name:prop-2-enyl 2-methylprop-2-enoate
CAS Number: 96-05-9Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:202-473-0
Nikkaji Web:J38.884J
Beilstein Number:1747406
XlogP3-AA:1.70 (est)
Molecular Weight:126.15510000
Formula:C7 H10 O2
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:indirect food additives: adhesives and components of coatings
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
DG SANTE Food Contact Materials:methacrylic acid, allyl ester
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.93800 @ 25.00 °C.
Boiling Point: 138.59 °C. @ 760.00 mm Hg (est)
Vapor Pressure:6.682000 mmHg @ 25.00 °C. (est)
Flash Point: 93.00 °F. TCC ( 33.89 °C. )
logP (o/w): 1.567 (est)
Soluble in:
 water, 1470 mg/L @ 25 °C (est)
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
Cosmetic Information:
None found
Kowa Amerian Corporation
Odor: characteristic
Use: AMA is a low viscosity liquid monomer with dual allylic and methacrylic functionalities, offering chemical and heat resistance, adhesion, hardness, excellent second stage cross-linking and low shrinkage.
Santa Cruz Biotechnology
For experimental / research use only.
Allyl Methacrylate 98%
Sigma-Aldrich: Aldrich
For experimental / research use only.
Allyl Methacrylate 98%
contains 50-185 ppm MEHQ as inhibitor
For experimental / research use only.
Allyl Methacrylate (stabilized with MEHQ) >99.0%(GC)
Safety Information:
Preferred SDS: View
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-mouse LD50 57 mg/kg
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(8), Pg. 59, 1990.

parenteral-mouse LD50 57 mg/kg
National Technical Information Service. Vol. OTS0559078

oral-rat LD50 70 mg/kg
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(8), Pg. 59, 1990.

parenteral-rat LD50 70 mg/kg
National Technical Information Service. Vol. OTS0559078

Dermal Toxicity:
skin-rabbit LD50 500 uL/kg
American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.

Inhalation Toxicity:
inhalation-mouse LC50 5500 mg/m3
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(8), Pg. 59, 1990.

inhalation-rat LC50 1800 mg/m3
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 34(8), Pg. 59, 1990.

Safety in Use Information:
indirect food additives: adhesives and components of coatings
IFRA Purity Specification: < 0.1% free allyl alcohol
Recommendation for allyl methacrylate usage levels up to:
 not for fragrance use.
Recommendation for allyl methacrylate flavor usage levels up to:
 not for flavor use.
Safety References:
EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):96-05-9
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :7274
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
prop-2-enyl 2-methylprop-2-enoate
RTECS:UD3483000 for cas# 96-05-9
 prop-2-enyl 2-methylprop-2-enoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:96-05-9
Pubchem (cid):7274
Pubchem (sid):134972207
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Indirect Additives used in Food Contact Substances:View
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2916.14.2050
Typical G.C.
VCF-Online:VCF Volatile Compounds in Food
Potential Blenders and core components note
None Found
Potential Uses:
None Found
Occurrence (nature, food, other):note
 anthemis nobilis flower oil roman @ 0.81%
Data GC Search Trop Picture
 not found in nature
 methacrylic acid allyl ester
 methacrylic acid, allyl ester
 methacrylic acid, allyl ester (8CI)
2-methyl-2-propenoic acid 2-propenyl ester
2-methyl-2-propenyl methacrylate
 prop-2-en-1-yl 2-methylprop-2-enoate
 prop-2-enyl 2-methylprop-2-enoate
2-propenoic acid, 2-methyl-, 2-propen-1-yl ester
2-propenoic acid, 2-methyl-, 2-propenyl ester


PubMed:Poly(allyl methacrylate) functionalized hydroxyapatite nanocrystals via the combination of surface-initiated RAFT polymerization and thiol-ene protocol: a potential anticancer drug nanocarrier
PubMed:Developmental toxicities of methacrylic acid, ethyl methacrylate, n-butyl methacrylate, and allyl methacrylate in rats following inhalation exposure
PubMed:Enrichment and Distribution of Pb(2+) Ions in Zwitterionic Poly(cysteine methacrylate) Brushes at the Solid-Liquid Interface
PubMed:Skin sensitization potential of allyl methacrylate in guinea pigs
PubMed:The effect of heterobifunctional crosslinkers on HEMA hydrogel modulus and toughness
PubMed:Thermoresponsive amperometric glucose biosensor
PubMed:Functionalization of Metal Surface via Thiol-Ene Click Chemistry: Synthesis, Adsorption Behavior, and Postfunctionalization of a Catechol- and Allyl-Containing Copolymer
PubMed:Photochemical Synthesis and Versatile Functionalization Method of a Robust Porous Poly(ethylene glycol methacrylate-co-allyl methacrylate) Monolith Dedicated to Radiochemical Separation in a Centrifugal Microfl
PubMed:Synthesis of an Aqueous Self-Matting Acrylic Resin with Low Gloss and High Transparency via Controlling Surface Morphology
PubMed:Dye-Loaded Mechanochromic and pH-Responsive Elastomeric Opal Films
PubMed:Chemoselective Polymerization of Polar Divinyl Monomers with Rare-Earth/Phosphine Lewis Pairs
PubMed:Novel Anti-Biofouling Soft Contact Lens: l-Cysteine Conjugated Amphiphilic Conetworks via RAFT and Thiol-Ene Click Chemistry
PubMed:Subchronic dermal toxicity study of allyl methacrylate in rabbits
PubMed:Functional-Polymer Library through Post-Polymerization Modification of Copolymers Having Oleate and Pentafluorophenyl Pendants
PubMed:Chemoselective, Stereospecific, and Living Polymerization of Polar Divinyl Monomers by Chiral Zirconocenium Catalysts
PubMed:Preparation and evaluation of a contact lens vehicle for puerarin delivery
PubMed:Functionalised polysiloxanes as injectable, in situ curable accommodating intraocular lenses
PubMed:Towards a functional radiopaque hydrogel for nucleus pulposus replacement
PubMed:Prediction of the reduced glutathione (GSH) reactivity of dental methacrylate monomers using NMR spectra - Relationship between toxicity and GSH reactivity
PubMed:'Clickable' hydrogels for all: facile fabrication and functionalization
PubMed:A decontamination system for chemical weapons agents using a liquid solution on a solid sorbent
PubMed:Facile Preparation of Crosslinked PAN Membranes Based on Thiol-Ene Photopolymerization
PubMed:Study of pH-responsive microgels containing methacrylic acid: effects of particle composition and added calcium
PubMed:[Irritation and allergy to acrylates and methacrylates. - Part I: Common monoacrylates and monomethacrylates (author's transl)]
PubMed:Combination of Surface Initiated Reversible Addition Fragmentation Chain Transfer Polymerization, Thiol-Ene Click Chemistry and Coordination Chemistry for the Fabrication of a Novel Photoluminescent Hydroxyapat
PubMed:Robust Cross-Linked Stereocomplexes and C60 Inclusion Complexes of Vinyl-Functionalized Stereoregular Polymers Derived from Chemo/Stereoselective Coordination Polymerization
PubMed:Some new methods for affixing sections to glass slides. II. Organic-solvent based adhesives
PubMed:Synthesis of a mesoporous functional copolymer bead carrier and its properties for glucoamylase immobilization
PubMed:Inverse microemulsion polymerization of sterically stabilized polyampholyte microgels
PubMed:Glutathione depletion in rat hepatocytes: a mixture toxicity study with alpha, beta-unsaturated esters
None found
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