|
Category:pharmaceuticals / chemical synthisis
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless to pale yellow clear liquid (est) |
| Assay: | 95.00 to 100.00
|
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 1.39800 @ 25.00 °C.
|
| Melting Point: | -11.90 °C. @ 760.00 mm Hg
|
| Boiling Point: | 70.10 °C. @ 760.00 mm Hg
|
| Vapor Pressure: | 153.455002 mmHg @ 25.00 °C. (est) |
| Vapor Density: | 4.17 ( Air = 1 ) |
| Flash Point: | 28.00 °F. TCC ( -2.22 °C. )
|
| logP (o/w): | 1.790 |
| Soluble in: |
| | water, 3830 mg/L @ 25 °C (exp) | | | water, 2947 mg/L @ 25 °C (est) |
Organoleptic Properties:
| Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
intraperitoneal-mouse LD50 48 mg/kg
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 20(12), Pg. 52, 1976.
oral-rat LD50 120 mg/kg
JAT, Journal of Applied Toxicology. Vol. 9, Pg. 235, 1989.
|
| Dermal Toxicity: |
|
Not determined
|
| Inhalation Toxicity: |
inhalation-mammal (species unspecified) LC50 4110 mg/m3
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 18(4), Pg. 55, 1974.
inhalation-rat LC50 10000 mg/m3/30M
Fiziologicheski Aktivnye Veshchestva. Physiologically Active Substances. Vol. 7, Pg. 35, 1975.
|
Safety in Use Information:
| Category: | | pharmaceuticals / chemical synthisis |
| IFRA Purity Specification: | < 0.1% free allyl alcohol |
| Recommendation for allyl bromide usage levels up to: | | | not for fragrance use.
|
| |
| Recommendation for allyl bromide flavor usage levels up to: |
| | not for flavor use.
|
Safety References:
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | allylbromide | | | bromallylene | | 1- | bromo-2-propene | | 3- | bromo-propene | | 3- | bromoprop-1-ene | | 3- | bromopropene | | 3- | bromopropylene | | 1- | propene, 3-bromo- |
Articles:
| PubMed:Nematicidal activity of allyl bromide and dibromo(nitro)methane under laboratory conditions |
| PubMed:Toxicology studies of allyl bromide (CAS No. 106-95-6) in genetically modified (FVB Tg.AC hemizygous) mice and carcinogenicity studies of allyl bromide in genetically modified [B6.129-Trp53tm1Brd (N5) Hapl |
| PubMed:Retraction: Belta‹ef et al. An expeditious synthesis of [1,2]isoxazolidin-5-ones and [1,2]oxazin-6-ones from functional allyl bromide derivatives. Molecules 2010, 15, 4094-4101 |
| PubMed:Indium-Mediated Stereoselective Allylation |
| PubMed:Design, synthesis, and SAR study of isopropoxy allylbenzene derivatives as 15-lipoxygenase inhibitors |
| PubMed:Furan Oxidation Strategy for the Synthesis of the Macrolactone Analogue of Migrastatin |
| PubMed:Rotation-Triggered Transmetalation on a Heterobimetallic Cu/Al N-Phosphine-Oxide-Substituted Imidazolylidene Complex |
| PubMed:Hyperbranched Poly(ether-siloxane)s Containing Ammonium Groups: Synthesis, Characterization and Catalytic Activity |
| PubMed:Direct and Delayed Dynamics in Electron-Induced Surface Reaction |
| PubMed:Synthesis of Quaternary-Substituted Thiazolines via Halocyclization of S-Allyl Thioimidate Salts |
| PubMed:Bioconversion of ethyl 4-chloro-3-oxobutanoate by permeabilized fresh brewer's yeast cells in the presence of allyl bromide |
| PubMed:Palladium-catalyzed allyl cross-coupling reactions with in situ generated organoindium reagents |
| PubMed:Synthesis of novel tri- and tetrasubstituted C18 furan fatty esters |
| PubMed:The Role Ionic Liquid [BMIM][PF(6)] in One-Pot Synthesis of Tetrahydropyran Rings through Tandem Barbier-Prins Reaction |
| PubMed:Chromium(III)-Catalyzed C(sp(2))-H Alkynylation, Allylation, and Naphthalenation of Secondary Amides with Trimethylaluminum as Base |
| PubMed:An expeditious synthesis of [1,2]isoxazolidin-5-ones and [1,2]oxazin-6-ones from functional allyl bromide derivatives |
| PubMed:Mannan-based conjugates as a multimodal imaging platform for lymph nodes |
| PubMed:In-situ synthesis of acylated sodium alginate-g-(tetrahydrofuran(5)-b-polyisobutylene) terpolymer/Ag-NPs nanocomposites |
| PubMed:Total synthesis of alotaketal A |
| PubMed:?-Cyclodextrin functionalized polystyrene porous monoliths for separating phenol from wastewater |
| PubMed:Novel Quaternary Ammonium-Functionalized Covalent Organic Frameworks/Poly(2,6-dimethyl-1,4-phenylene oxide) Hybrid Anion Exchange Membranes with Enhanced Ion Conductivity and Stability |
| PubMed:B-B Bond Nucleophilicity in a Tetraaryl ?-Hydridodiborane(4) Anion |
| PubMed:Redox-Active Ligand-Assisted Two-Electron Oxidative Addition to Gallium(II) |
| PubMed:A mild synthesis of new aryl vinyl ethers and diethyl 1-[(alkyl)(cyano)methyl]vinylphosphonates via the substitution of a 2,3-difunctional allyl bromide |
| PubMed:Allylic compounds bind directly to DNA: investigation of the binding mechanisms in vitro |
| PubMed:Synthesis of a spirocyclic indoline lactone |
| PubMed:Organic impurity profiling of 3,4-methylenedioxymethamphetamine (MDMA) synthesised from catechol |
| PubMed:N,N,N-trimethylchitosan modified with well defined multifunctional polymer modules used as pDNA delivery vector |
| PubMed:Structures and Reactivities of Sodiated Evans Enolates: Role of Solvation and Mixed Aggregation on the Stereochemistry and Mechanism of Alkylations |
| PubMed:An efficient asymmetric synthesis of diacylglycerols |
| PubMed:Synthesis and antimicrobial evaluation of novel pyrazolones and pyrazolone nucleosides |
| PubMed:Preparation of (+)-trans-isoalliin and its isomers by chemical synthesis and RP-HPLC resolution |
| PubMed:Gas-phase synthesis of [Ag4H]+ and its mediation of the C--C coupling of allyl bromide |
| PubMed:Expeditious synthesis of the fused hexacycle of puberuline C via a radical-based cyclization/translocation/cyclization process |
| PubMed:Synthesis and anticancer activity of some new s-glycosyl and s-alkyl 1,2,4-triazinone derivatives |
| PubMed:Direct synthesis of B-allyl and B-allenyldiisopinocampheylborane reagents using allyl or propargyl halides and indium metal under Barbier-type conditions |
| PubMed:Design and synthesis of modular oxazoline ligands for the enantioselective chromium-catalyzed addition of allyl bromide to ketones |
| PubMed:Oxidation state, aggregation, and heterolytic dissociation of allyl indium reagents |
| PubMed:Kinetic and spectroscopic characterization of the isomers of the allyl bromide molecular ion |
| PubMed:Preparation of cis-?-hydroxycarvone derivatives for synthesis of sesterterpenoid natural products: total synthesis of phorbin A |
| PubMed:Pharmacological actions of levallorphan allyl bromide (CM 32191), a new peripheral narcotic antagonist |
| PubMed:Per-O-(3-hydroxy)propyl-beta-cyclodextrin: a cyclodextrin derivative bearing only primary hydroxyl groups |
| PubMed:Rapid detection of avian influenza A virus by immunochromatographic test using a novel fluorescent dye |
| PubMed:Reactions of atoms and free radicals in solution; the reaction of allyl bromide with bromotrichloromethane |
| PubMed:Structure and reactivity of the cysteine methyl ester radical cation |
| PubMed:Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts |
| PubMed:Asymmetric syntheses of epohelmins A and B by In-mediated allylation |
| PubMed:Mutagenicity of vinyl compounds in Salmonella typhimurium |
| PubMed:Metal-free activation in the anionic ring-opening polymerization of cyclopropane derivatives |
| PubMed:One-pot preparation of trifluoromethylated homoallylic N-acylhydrazines or à-methylene-?-lactams from acylhydrazines, trifluoroacetaldehyde methyl hemiacetal, allyl bromide and tin |
| PubMed:Secondary deuterium kinetic isotope effects in irreversible additions of allyl reagents to benzaldehyde |
| PubMed:Copper-catalyzed regioselective fluorination of allylic halides |
| PubMed:[Investigation on isotopic exchange of bromine between sodium bromide and allyl bromide in alcohol solution] |
| PubMed:Role of Hydrogen Bonding on the Reactivity of Thiyl Radicals: A Mass Spectrometric and Computational Study Using the Distonic Radical Ion Approach |
| PubMed:Fractionation of whey proteins with high-capacity superparamagnetic ion-exchangers |
| PubMed:Pressure dependent product formation in the photochemically initiated allyl + allyl reaction |
| PubMed:New (99m)Tc(CO)(3) mannosylated dextran bearing S-derivatized cysteine chelator for sentinel lymph node detection |
| PubMed:Synthetic and mechanistic studies of indium-mediated allylation of imines in ionic liquids |
| PubMed:[Molecular toxicological mechanism of the lethal interactions of the new antiviral drug, sorivudine, with 5-fluorouracil prodrugs and genetic deficiency of dihydropyrimidine dehydrogenase] |
| PubMed:7-Bromo-4b-methyl-7,8-dihydro-4bH-9-thia-8a-aza-fluorene 9,9-dioxide |
| PubMed:Kinetics and mechanisms of the unimolecular elimination of 2,2-diethoxypropane and 1,1-diethoxycyclohexane in the gas phase: experimental and theoretical study |
| PubMed:Aromatic allylation via diazotization: variation of the allylic moiety and a short route to a benzazepine derivative |
| PubMed:Highly efficient formal synthesis of cephalotaxine, using the Stevens rearrangement--acid lactonization sequence as a key transformation |
| PubMed:Gastragogue effect of laxatives and allyl-bromide-mixture |
| PubMed:Indium-catalyzed reduction of allyl bromide with gallium or aluminum. Formation of allylgallium and allylaluminum sesquibromides |
| PubMed:A synthetic macromolecule for sentinel node detection: (99m)Tc-DTPA-mannosyl-dextran |
| PubMed:Photodissociation dynamics of allyl bromide at 234, 265, and 267 nm |
| PubMed:Synthesis and antibacterial activity of 2, 3-dehydro-3-O-(3-aryl-E-prop-2-enyl)-10, 11-anhydroclarithromycin derivatives |
| PubMed:The design and synthesis of 9-phenylcyclohepta[d]pyrimidine-2,4-dione derivatives as potent non-nucleoside inhibitors of HIV reverse transcriptase |
| PubMed:Synthesis of halogenated 4-quinolones and evaluation of their antiplasmodial activity |
| PubMed:Directed hydrozirconation of propargylic alcohols |
| PubMed:Kinetics and mechanisms of the thermal decomposition of 2-methyl-1,3-dioxolane, 2,2-dimethyl-1,3-dioxolane, and cyclopentanone ethylene ketal in the gas phase. Combined experimental and DFT study |
| PubMed:Selective palladium(ii)-mediated oxidation of homoallylic N-tert-butanesulfinyl amine derivatives |
| PubMed:Synthesis of Chiral 1,3-Dienes through Ring-Closing Metathesis of Enantioenriched Enynes: Potential Precursors of Morphane Analogs |
| PubMed:Stereochemical Study of the Allylation of Aldehydes with Allyl Halides in Cosolvent/Water(Salt)/Zn and in Cosolvent/Water(Salt)/Zn/Haloorganotin Media |
| PubMed:Indium and zinc-mediated Barbier-type addition reaction of 2,3-allenals with allyl bromide: an efficient synthesis of 1,5,6-alkatrien-4-ols |
| PubMed:Stereoselective synthesis of pyroglutamate natural product analogs from à- aminoacids and their anti-cancer evaluation |
| PubMed:Titanocene(III) chloride mediated radical induced allylation of aldimines: formal synthesis of C-linked 4'-deoxy aza-disaccharide |
| PubMed:DFT computational study of the mechanism of allyl halides carbonylation catalyzed by nickel tetracarbonyl |
| PubMed:Low energy electron-induced decomposition of (?(3)-C(3)H(5))Ru(CO)(3)Br, a potential focused electron beam induced deposition precursor with a heteroleptic ligand set |
| PubMed:Stereoselective à-aminoallylation of aldehydes with chiral tert-butanesulfinamides and allyl bromides |
| PubMed:Synthesis and evaluation of 3-salicyloylpyridine derivatives as cytotoxic mitochondrial apoptosis inducers |
| PubMed:Mechanism-based inactivation of human dihydropyrimidine dehydrogenase by (E)-5-(2-bromovinyl)uracil in the presence of NADPH |
| PubMed:Stereospecific 7à-alkylation of 20-hydroxyecdysone in a lithium-ammonia solution |
| PubMed:2-(chromon-3-yl)imidazole derivatives as potential antimicrobial agents: synthesis, biological evaluation and molecular docking studies |
| PubMed:Enantioselective synthesis and preliminary metabolic studies of the optical isomers of 2-n-propyl-4-pentenoic acid, a hepatotoxic metabolite of valproic acid |
| PubMed:Palladium complexes with a tridentate PNO ligand. Synthesis of eta1-allyl complexes and cross-coupling reactions promoted by boron compounds |
| PubMed:Synthesis of a deoxy analogue of ADP L-glycero-D-manno-heptose |
| PubMed:[Alkylation of gem-dibromocyclopropanes with higher-order organocuprates] |
| PubMed:Synthesis of the oxepinochromone natural products ptaeroxylin (desoxykarenin), ptaeroxylinol, and eranthin |
| PubMed:N,N'-(Hexane-1,6-diyl)bis(4-methyl-N-(oxiran-2-ylmethyl)benzenesulfonamide): Synthesis via cyclodextrin mediated N-alkylation in aqueous solution and further Prilezhaev epoxidation |
| PubMed:Total synthesis of antillatoxin |
| PubMed:Aromatic allylation via diazotization: metal-free C-C bond formation |
| PubMed:Addition of organochromium reagents to heteroaryl aldehydes. Synthesis of heteroaryl substituted bis-allyl ethers and homoallyl ethers |
| PubMed:[Biotransformation of 4-methyl-7-allyloxy coumarin by transgenic hairy roots of Polygonum multiflorum] |
| PubMed:Preparation of 4'-substituted thymidines by substitution of the thymidine 5'-esters |
| PubMed:Indium-mediated asymmetric barbier-type allylations: additions to aldehydes and ketones and mechanistic investigation of the organoindium reagents |
| PubMed:Polar reactions of acyclic conjugated bisallenes |
| PubMed:Chiral Diarylmethanes via Copper-Catalyzed Asymmetric Allylic Arylation with Organolithium Compounds |
| PubMed:A novel palladium-catalyzed coupling of epoxides with allyl bromide mediated by indium(I) chloride: a cascade epoxide rearrangement-carbonyl allylation |
| PubMed:Experimental and theoretical studies of the homogeneous, unimolecular gas-phase elimination kinetics of trimethyl orthovalerate and trimethyl orthochloroacetate |
| PubMed:An advance on exploring N-tert-butanesulfinyl imines in asymmetric synthesis of chiral amines |
| PubMed:Copper-free asymmetric allylic alkylation with a Grignard reagent: design of the ligand and mechanistic studies |
| PubMed:Synthesis of acyclovir and HBG analogues having nicotinonitrile and its 2-methyloxy 1,2,3-triazole |
| PubMed:Preparation of 1,3-bis(allyloxy)benzene under a new multi-site phase-transfer catalyst combined with ultrasonication--a kinetic study |
| PubMed:Sensory irritating effects of allyl halides and a role for hydrogen bonding as a likely feature at the receptor site |
| PubMed:Joint experimental and DFT study of the gas-phase unimolecular elimination kinetic of methyl trifluoropyruvate |
| PubMed:Investigation into the regiochemistry of some isoxazoles derived from 1,3-dipolar cycloaddition of 4-nitrobenzonitrile oxide with some dipolarophiles: a combined theoretical and experimental studies |
| PubMed:Modified glycogen as construction material for functional biomimetic microfibers |
| PubMed:Zinc-mediated allylation and alkylation of aminals in the presence of TMSCl and diisopropylamine |
| PubMed:Reactions of atoms and free radicals in solution; decomposition of diacetyl peroxide in allyl bromide |
| PubMed:Manganese-Mediated Carbon-Carbon Bond Formation in Aqueous Media: Chemoselective Allylation and Pinacol Coupling of Aryl Aldehydes |
| PubMed:Synthesis and anti-HIV-1 activity of novel 2,3-dihydro-7H-thiazolo[3,2-a]pyrimidin-7-ones |
| PubMed:Glucopyranosylidene-spiro-iminothiazolidinone, a new bicyclic ring system: synthesis, derivatization, and evaluation for inhibition of glycogen phosphorylase by enzyme kinetic and crystallographic methods |
| PubMed:Structure-activity relationships of alpha, beta-unsaturated carbonylic compounds |
| PubMed:Reactivity and enantioselectivity in the reactions of scalemic stereogenic alpha-(N-carbamoyl)alkylcuprates |
| PubMed:Frequency of C-allylations on oligoglycinates via N-ylides |
| PubMed:Reactivity of alkynylzirconates towards allyl bromides: selective formation of ?-allyl-zirconacyclopentadienes |
| PubMed:Metal-mediated allylation of enzymatically oxidized methyl à-D-galactopyranoside |
| PubMed:Cotton functionalized with peptides: characterization and synthetic methods |
| PubMed:Silica: An efficient catalyst for one-pot regioselective synthesis of dithioethers |
| PubMed:Synthesis and anticholinesterase activity of (-)-N1-norphysostigmine, (-)-eseramine, and other N(1)-substituted analogues of (-)-physostigmine |
| PubMed:P(NMe2)3-Mediated Umpolung Alkylation and Nonylidic Olefination of à-Keto Esters |
| PubMed:Vinylic C--H borylation of cyclic vinyl ethers with bis(pinacolato)diboron catalyzed by an Iridium(I)-dtbpy complex |
| PubMed:Aliphatic analogues of nucleotides: synthesis and affinity towards nucleases |
| PubMed:Enantioselective allylic alkylation of stereodefined polysubstituted copper enolates as an entry to acyclic quaternary carbon stereocentres |
| PubMed:Mono(cycloheptatrienyl) tantalum chemistry: synthesis and characterization of new tantalum halide, hydride, and alkyl species |
| PubMed:Indium-mediated asymmetric Barbier-type allylation of aldimines in alcoholic solvents: synthesis of optically active homoallylic amines |
| PubMed:Synthesis of Six-Membered Spiro Azacyclic Oxindole Derivatives via a One-Pot Process of Umpolung Allylation/Aza-Prins Cyclization |
| PubMed:Structural and oxo-transfer reactivity differences of hexacoordinate and pentacoordinate (nitro)(tetraphenylporphinato)cobalt(III) derivatives |
| PubMed:A convenient procedure for bismuth-mediated Barbier-type allylation of aldehydes in water containing fluoride ions |
| PubMed:Synthesis of 2,5-Diaryl-1,5-dienes from Allylic Bromides Using Visible-Light Photoredox Catalysis |
| PubMed:[Effects of ATP-regulated potassium channels modulators, N-(2-pyridyl)-N'-(4-toluol) sulfonylcarbamides, on electromechanical activity in guinea pig myocardium] |
| PubMed:An enantiospecific approach to tricyclic sesquiterpenes mayurone and thujopsenes |
| PubMed:Stereoselective allylation of 4-oxoazetidine-2-carbaldehydes. Application To the stereocontrolled synthesis of fused tricyclic beta-lactams via intramolecular diels-alder reaction of 2-azetidinone-tethered |
| PubMed:Analytical application of poly{methyl[3-(2-hydroxy-3,4-difluoro)phenyl]propyl siloxane} as a QCM coating for DMMP detection |
| PubMed:An approach to the total synthesis of the marine ascidian metabolite perophoramidine via a halogen-selective tandem Heck/carbonylation strategy |
| PubMed:Toward a protecting-group-free halogen-metal exchange reaction: practical, chemoselective metalation of functionalized aromatic halides using dianion-type zincate, tBu4ZnLi2 |
| PubMed:A versatile synthesis of ?-lactam-fused oxacycles through the palladium-catalyzed chemo-, regio-, and diastereoselective cyclization of allenic diols |
| PubMed:Monomeric and dimeric nickel complexes derived from a pincer ligand featuring a secondary amine donor moiety |
| PubMed:Elimination of HX (X = Cl, Br) from haloalkenes on the Ru2Q2 (Q = S, Se) core complex |
| PubMed:Generation of chiral boron enolates by rhodium-catalyzed asymmetric 1,4-addition of 9-aryl-9-borabicyclo[3.3.1]nonanes (B-Ar-9BBN) to alpha,beta-unsaturated ketones |
| PubMed:[bmim][Br] as a solvent and activator for the Ga-mediated Barbier allylation: direct formation of an N-heterocyclic carbene from Ga metal |
| PubMed:Syntheses, derivatives, solubility, and interfacial properties of 2-methyl-2-polyfluoroalkenyloxymethyl-1,3-propanediols: potential building blocks for syntheses of amphiphatic macromolecules |
| PubMed:Diastereoselection during 1,2-Addition of the Allylindium Reagent to alpha-Thia and alpha-Amino Aldehydes in Aqueous and Organic Solvents |
| PubMed:Unique structural properties of 2,4,6-tri-tert-butylanilide: isomerization and switching between separable amide rotamers through the reaction of anilide enolates |
| PubMed:Total synthesis of a cuticular hydrocarbon from the cane beetle Antitrogus parvulus: confirmation of the relative stereochemistry |
| PubMed:Motilides, macrolides with gastrointestinal motor stimulating activity. II. Quaternary N-substituted derivatives of 8,9-anhydroerythromycin A 6,9-hemiacetal and 9,9-dihydroerythromycin A 6,9-epoxide |
| PubMed:Synthesis, structure, and reactions of NH-bridged calix[m]arene[n]pyridines |
| PubMed:Synthesis and biological evaluation of (2,5-dihydro-1H-pyrrol-1-yl)-2H-chromen-2-ones as free radical scavengers |
| PubMed:Cobalt-Catalyzed Cross-Coupling of Grignards with Allylic and Vinylic Bromides: Use of Sarcosine as a Natural Ligand |
| PubMed:Total synthesis and absolute configuration of minalemine A, a guanidine peptide from the marine tunicate Didemnum rodriguesi |
| PubMed:Mechanical properties of IIR/OMMT nanocomposites via melt-compounding and solution process |
| PubMed:Regiospecifically alpha-13C-labeled porphyrins for studies of ground-state hole transfer in multiporphyrin arrays |
| PubMed:Magnesium-Mediated Carbon-Carbon Bond Formation in Aqueous Media: Barbier-Grignard Allylation and Pinacol Coupling of Aldehydes |
| PubMed:Biphilic Organophosphorus Catalysis: Regioselective Reductive Transposition of Allylic Bromides via P(III)/P(V) Redox Cycling |
| PubMed:Evidence for a rapid degenerate hetero-Cope-type rearrangement in [Cp*W(S)2S-CH2-CH=CH2] |
| PubMed:Investigation of the gas phase reactivity of the 1-adamantyl radical using a distonic radical anion approach |
| PubMed:Synthesis and structural characterization of mono- and bisfunctional o-carboranes |
| PubMed:Indium- or Zinc-Mediated One-Pot Synthesis of Homoallylamines, beta-Amino Esters, and beta-Amino Nitriles |
| PubMed:Template synthesis of benzannulated N-heterocyclic carbene ligands |
| PubMed:Iron-catalyzed carbometalation of propargylic and homopropargylic alcohols |
| PubMed:Aqueous Barbier allylation of aldehydes mediated by tin |
| PubMed:Mechanism of alpha-amino acids decomposition in the gas phase. experimental and theoretical study of the elimination kinetics of N-benzyl glycine ethyl ester |
| PubMed:Novel and efficient method for the allylation of carbonyl compounds and imines using triallylaluminum |
| PubMed:Convenient synthesis of racemic mixed-chain ether glycerophosphocholines from fatty alkyl allyl ethers: useful analogs for biophysical studies |
| PubMed:Neighboring group migration in enzyme-mediated halohydrin formation |
| PubMed:Joint experimental and theoretical studies of the mechanism for the gas phase elimination kinetics of methyl 2,2-dimethyl-3-hydroxypropionate |
| PubMed:Metal-catalyzed cyclization of beta- and gamma-allenols derived from D-glyceraldehyde--synthesis of enantiopure dihydropyrans and tetrahydrooxepines: an experimental and theoretical study |
| PubMed:Structure and reactivity of the N-acetyl-cysteine radical cation and anion: does radical migration occur? |
| PubMed:Novel vinyl phosphonates and vinyl boronates by halogenation, allylation, and propargylation of alpha-boryl- and alpha-phosphonozirconacyclopentenes |
| PubMed:Synthesis, molecular structure and characterization of allylic derivatives of 6-amino-3-methyl-1,2,4-triazolo[3,4-f][1,2,4]-triazin-8(7H)-one |
| PubMed:Silicones containing pendant biocides for antifouling coatings |
| PubMed:A Facile Generation of a Cyclopropylzinc Compound from an Alkenylzinc Derivative and Its Reaction with Electrophiles |
| PubMed:A novel solid phase for selective separation of flavonoid compounds |
| PubMed:Stereoselective functionalisation of cis- and trans-2-ferrocenyl-3-pivaloyl-4-alkyl-1,3-oxazolidin-5-ones: asymmetric synthesis of (R)- and (S)-2-alkyl-2-aminopent-4-enoic acids and (2R,3S)-2-amino-2-methy |
| PubMed:Synthesis and pharmacological evaluation of enantiomerically pure 4-deoxy-4-fluoromuscarines |
| PubMed:Optochemical sensor for an ornidazole assay using 1-amino-4-allyloxyanthraquinone as a fluorescent indicator |
| PubMed:Synthesis of ferrocenyl alkenes, dienes, and enynes via samarium diiodide promoted tandem addition and dehydration of ferrocenyl carbonyls with halides |
| PubMed:Sequential aza-Baylis-Hillman/ring closing metathesis/aromatization as a novel route for the synthesis of substituted pyrroles |
| PubMed:Monoalkylation of C60 and C70 with Zn and active alkyl bromides |
| PubMed:Copper-catalysed à-selective allylic alkylation of heteroaryllithium reagents |
| PubMed:Synthesis and receptor binding of N-substituted tropane derivatives. High-affinity ligands for the cocaine receptor |
| PubMed:[Synthesis and pharmacologic study of 1,5-benzodiazepine-2,4-diones and their alkyl derivatives] |
| PubMed:A concise synthetic pathway for trans-metanicotine analogues |
| PubMed:New stationary phase for liquid chromatography with chemically bonded pinane ligand: synthesis and characterization by nuclear magnetic resonance and high-performance liquid chromatographic investigations |
| PubMed:[Study on the distribution and structure of polyhalides by gas chromatography-mass spectrometry] |
| PubMed:Copper-free arylation of 3,3-disubstituted allylic halides with triazene-softened aryl Grignard reagents |
| PubMed:Determination of chlorambucil in plasma by GLC with selected-ion monitoring |
| PubMed:An electrochemical coupling of organic halide with aldehydes, catalytic in chromium and nickel salts. the Nozaki-Hiyama-Kishi reaction |
| PubMed:Highly efficient asymmetric construction of quaternary carbon-containing homoallylic and homopropargylic amines |
| PubMed:Stereoselective synthesis of syn and anti 1,2-hydroxyalkyl moieties by Cu-catalyzed asymmetric allylic alkylation |
| PubMed:Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia |
| PubMed:A simple conductimetric method as an alternative to the colorimetric p-nitrobenzylpyridine test for the measurement of the reactivity of potentially mutagenic alkylating compounds |
|
3D/inchi