EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

4-bromomethyl-7-methoxycoumarin
4-bromomethyl-7-methoxy-2-oxo-2H-benzopyran

Supplier Sponsors

Name:4-(bromomethyl)-7-methoxychromen-2-one
CAS Number: 35231-44-8Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:252-448-3
FDA UNII: Search
Nikkaji Web:J207.993C
Beilstein Number:0187211
MDL:MFCD00006869
XlogP3:2.40 (est)
Molecular Weight:269.09433000
Formula:C11 H9 Br O3
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:information only not used for fragrances or flavors
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Boiling Point: 385.30 °C. @ 760.00 mm Hg (est)
Flash Point: 368.00 °F. TCC ( 186.80 °C. ) (est)
logP (o/w): 2.730 (est)
Soluble in:
 water, 139.7 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
4-Bromomethyl-7-Methoxycoumarin >98.0%(T)
Odor: characteristic
Use: Used for derivatization, TLC and HPLC separation, and fluorometric analysis of a wide range of naturally occurring a
Santa Cruz Biotechnology
For experimental / research use only.
4-Bromomethyl-7-methoxycoumarin ≥97%
Sigma-Aldrich: Aldrich
For experimental / research use only.
4-Bromomethyl-7-methoxycoumarin 97%
sds
TCI AMERICA
For experimental / research use only.
Br-Mmc (=4-Bromomethyl-7-methoxycoumarin) [for HPLC Labeling] >98.0%(T)
sds
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
information only not used for fragrances or flavors
Recommendation for 4-bromomethyl-7-methoxycoumarin usage levels up to:
 not for fragrance use.
 
Recommendation for 4-bromomethyl-7-methoxycoumarin flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
Chemical Carcinogenesis Research Information System:Search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :121894
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
4-(bromomethyl)-7-methoxychromen-2-one
Chemidplus:0035231448
 
References:
 4-(bromomethyl)-7-methoxychromen-2-one
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):121894
Pubchem (sid):135077115
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2932.20.4500
ChemSpider:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
4-bromomethyl-7-methoxy-2-oxo-2H-benzopyran
4-(bromomethyl)-7-methoxychromen-2-one
 

Articles:

PubMed:Critical practical aspects in the application of liquid chromatography-mass spectrometric studies for the characterization of impurities and degradation products.
PubMed:Determination of tegafur, 5-fluorouracil, gimeracil and oxonic acid in human plasma using liquid chromatography-tandem mass spectrometry.
PubMed:Simultaneous determination of 6-methylcoumarin and 7-methoxycoumarin in cosmetics using three-dimensional excitation-emission matrix fluorescence coupled with second-order calibration methods.
PubMed:Determination of sodium monofluoroacetate (1080) in biological samples as its 4-bromomethyl-7-methoxycoumarin derivative by RP-HPLC.
PubMed:Identification of lipid binders in old oil paintings by separation of 4-bromomethyl-7-methoxycoumarin derivatives of fatty acids by liquid chromatography with fluorescence detection.
PubMed:Steviol quantification at the picomole level by high-performance liquid chromatography.
PubMed:Uracil in human DNA from subjects with normal and impaired folate status as determined by high-performance liquid chromatography-tandem mass spectrometry.
PubMed:The validity of two HPLC methods and a colorimetric PP2A assay related to the mouse bioassay in quantification of diarrhetic toxins in blue mussels (Mytilus edulis).
PubMed:The repeatability of two HPLC methods and the PP2A assay in the quantification of diarrhetic toxins in blue mussels (Mytilus edulis).
PubMed:Fluorescent-labeled ligands for the benzodiazepine receptor. Part 1: Synthesis and characterization of fluorescent-labeled benzodiazepines.
PubMed:Synthesis, photochemistry and application of (7-methoxycoumarin-4-yl)methyl-caged 8-bromoadenosine cyclic 3',5'-monophosphate and 8-bromoguanosine cyclic 3',5'-monophosphate photolyzed in the nanosecond time region.
PubMed:Derivatization of thymine and thymine photodimers with 4-bromomethyl-7-methoxycoumarin for fluorescence detection in high-performance liquid chromatography.
PubMed:Chemical synthesis and biological properties of novel fluorescent antifolates in Pgp- and MRP-overexpressing tumour cell lines.
PubMed:Derivatization of 5-fluorouracil with 4-bromomethyl-7-methoxycoumarin for determination by liquid chromatography-mass spectrometry.
PubMed:Sensitive high-performance liquid chromatographic assay for pilocarpine in biological fluids using fluorescence derivatisation.
PubMed:Fatty acids in erythrocytes measured by isocratic HPLC.
PubMed:Fluorescent derivatives of thromboxane B(2): Synthesis, spectroscopic and immunologic properties.
PubMed:A procedure for the determination of 5-fluorouracil in tissue using microbore HPLC and fluorescence detection.
PubMed:Investigation of derivatization reagents for the analysis of diarrhetic shellfish poisoning toxins by liquid chromatography with fluorescence detection.
PubMed:Labeling of immunoglobulins with bifunctional, sulfhydryl-selective, and photoreactive coumarins.
PubMed:High performance liquid chromatographic determination of free and conjugated bile acids in serum, liver biopsies, bile, gastric juice and feces by fluorescence labeling.
PubMed:Determination of fatty acids in fish oil dietary supplements by capillary chromatography with laser-induced fluorescence detection.
PubMed:Determination of free valproic acid: evaluation of the Centrifree system and comparison between high-performance liquid chromatography and enzyme immunoassay.
PubMed:Phycotoxins in seafood--toxicological and chromatographic aspects.
PubMed:Determination of valproic acid by high-performance liquid chromatography with photodiode-array and fluorescence detection.
PubMed:4-Bromomethyl-7-methoxycoumarin and analogues as derivatization agents for high-performance liquid chromatography determinations: a review.
PubMed:Measurement of incorporation of bromodeoxyuridine into DNA by high performance liquid chromatography using a novel fluorescent labelling technique.
PubMed:New fluorescent derivatives of cyclosporin for use in immunoassays.
PubMed:Selective high-performance liquid chromatographic method for the determination of glycyrrhizin and glycyrrhetic acid-3-O-glucuronide in biological fluids: application of ion-pair extraction and fluorescence labelling agent.
PubMed:Clean-up and determination of sodium valproate in serum by high-performance liquid chromatography with fluorimetric detection.
PubMed:High-performance liquid chromatography with chemiluminescence detection of serum levels of pre-column derivatized fluoropyrimidine compounds.
PubMed:Determination of individual bile acids in serum by high performance liquid chromatography.
PubMed:Improved automated precolumn derivatization reaction of fatty acids with bromomethylmethoxycoumarin as label.
PubMed:Analysis of 5-fluorouracil in plasma by precolumn derivatization with 4-bromomethyl-7-methoxycoumarin, followed by multi-dimensional high-performance liquid chromatography.
PubMed:Automated analysis procedure for valproic acid in blood, serum and brain dialysate by high-performance liquid chromatography with bromomethylmethoxycoumarin as fluorescent label.
PubMed:Conformational change of the L-shaped tRNA(Phe) molecule.
PubMed:High-performance liquid chromatography of 5-fluorouracil after derivatization with 4-bromomethyl-7-methoxycoumarin. Characterization of the derivative and the use of column switching for the improvement of resolution and the enhancement of sensitivity.
PubMed:High-performance liquid chromatographic determination of valproic acid in plasma using a micelle-mediated pre-column derivatization.
PubMed:High-performance liquid chromatographic analysis of glucuronic acid conjugates after derivatization with 4-bromomethyl-7-methoxycoumarin.
PubMed:Simultaneous determination of imidazoleacetic acid and N tau- and N pi-methylimidazoleacetic acids in human urine by high-performance liquid chromatography with fluorescence detection.
PubMed:Use of 4-bromomethyl-7-methoxycoumarin for derivatization of pyrimidine compounds in serum analysed by high-performance liquid chromatography with fluorimetric detection.
PubMed:High-performance liquid chromatography with fluorimetric detection in biological tissues of the 4-bromomethyl-7-methoxycoumarin ester derivative of 5-pyrrolidone-2-carboxylic acid.
PubMed:Fluorescence determination of 5-fluorouracil and 1-(tetrahydro-2-furanyl)-5-fluorouracil in blood serum by high-performance liquid chromatography.
PubMed:Prostaglandin determination with fluorescent reagents.
PubMed:Determination by hplc of trifluoroacetate levels in plasma and urine of patients anaesthetized with halothane.
PubMed:Determination of trace levels of fatty acid metal salts by high-performance liquid chromatography with fluorescence prelabeling.
PubMed:Fluorescence labelling of pyrimidine nucleobases and their related compounds for high-performance liquid chromatography.
PubMed:Conformational study of low molecular weight RNAs in solution by fluorescent probe.
PubMed:[Assay of 2-phenylbutyric acid in plasma with gas and liquid chromatography].
PubMed:[Labeling of 5-fluorouracil and pyrimidine nucleosides with 4-bromomethyl-7-methoxycoumarin for fluorimetric detection in high performance liquid chromatography].
PubMed:Quantitative high-pressure liquid chromatography-fluorescence determination of some important lower Fatty acids in lake sediments.
PubMed:Partial melting of the segment around pseudouridine in yeast 5S RNA.
PubMed:Thermal and Mg2+ dependent behavior of pseudouridines at 39th and 55th of yeast tRNAPhe.
PubMed:Fluorescence labelling in trace analysis of biological samples: simultaneous determination of free fatty acids and related carboxylic compounds.
PubMed:Fluorescent derivatives of prostaglandins and thromboxanes for liquid chromatography.
PubMed:4-Bromomethyl-7-methoxycoumarin as a new fluorescence label for fatty acids.
 
Notes:
None found
Please share your Comments.
Email Address:
Top of Page Home
Copyright © 1980-2021 The Good Scents Company (tgsc) ™ Disclaimer Privacy Policy