EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes

1,4-butane diol dimethacrylate
2-propenoic acid, 2-methyl-, 1,4-butanediyl ester

Supplier Sponsors

Name:4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate
CAS Number: 2082-81-7Picture of molecule3D/inchi
Other(deleted CASRN):148390-75-4
ECHA EINECS - REACH Pre-Reg:218-218-1
Nikkaji Web:J112.782I
XlogP3:3.20 (est)
Molecular Weight:226.27226000
Formula:C12 H18 O4
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:film forming agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
 FDA/DG SANTE Petitions, Reviews, Notices:
FCN 834 1,4-Butanediol dimethacrylate View - notice
FCN 1378 1,4-Butanediol dimethacrylate View - notice
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:1.02300 @ 25.00 °C.
Melting Point: 226.28 °C. @ 760.00 mm Hg
Boiling Point: 292.27 °C. @ 760.00 mm Hg (est)
Vapor Pressure:0.002000 mmHg @ 25.00 °C. (est)
Flash Point:> 230.00 °F. TCC ( > 110.00 °C. )
logP (o/w): 2.809 (est)
Soluble in:
 water, 60.01 mg/L @ 25 °C (est)
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: film formers
BOC Sciences
For experimental / research use only.
1,4-Butanediol dimethacrylate 95%
Santa Cruz Biotechnology
For experimental / research use only.
1,4-Butanediol Dimethacrylate 95%
Sigma-Aldrich: Aldrich
For experimental / research use only.
1,4-Butane Diol Dimethacrylate 95%
contains 200-300 ppm MEHQ as inhibitor
Safety Information:
Preferred SDS: View
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
Safety in Use Information:
film forming agents
Recommendation for 1,4-butane diol dimethacrylate usage levels up to:
 not for fragrance use.
Recommendation for 1,4-butane diol dimethacrylate flavor usage levels up to:
 not for flavor use.
Safety References:
European Food Safety Authority (EFSA) reference(s):

Scientific Opinion on the safety assessment of the substances (butadiene, ethyl acrylate, methyl methacrylate, styrene) copolymer either not crosslinked or crosslinked with divinylbenzene or 1,3-butanediol dimethacrylate, in nanoform, for use in food contact materials
View page or View pdf

EPI System: View
Chemical Carcinogenesis Research Information System:Search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):2082-81-7
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :16387
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:1
4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate
 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:2082-81-7
Pubchem (cid):16387
Pubchem (sid):134981721
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Indirect Additives used in Food Contact Substances:View
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2916.14.0050
Potential Blenders and core components note
None Found
Potential Uses:
None Found
Occurrence (nature, food, other):note
 not found in nature
 butane-1,4-diyl bis(2-methylacrylate)
1,4-butanediol dimethacrylate
1,4-butanediyl bis(2-methyl-2-propenoate)
1,4-butanediyl bis(2-methylacrylate)
1,4-butylene dimethacrylate
1,4-butylene glycol dimethacrylate
 di(methacrylic) acid, diester with butanediol
 methacrylic acid, tetramethylene ester
4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate
2-propenoic acid, 2-methyl-, 1,4-butanediyl ester


PubMed:Effects of dental methacrylates on oxygen consumption and redox status of human pulp cells.
PubMed:Effect of repeated preheating cycles on flexural strength of resin composites.
PubMed:Highly crosslinked polymeric monoliths for reversed-phase capillary liquid chromatography of small molecules.
PubMed:Two-body wear resistance of some indirect composite resins.
PubMed:Biological and physicochemical properties of carbon-graphite fibre-reinforced polymers intended for implant suprastructures.
PubMed:Effects of 1,4-butanediol dimethacrylate and urethane dimethacrylate on HL-60 cell metabolism.
PubMed:Effect of thermal cycling on flexural properties of carbon-graphite fiber-reinforced polymers.
PubMed:Cytotoxicity of silica-glass fiber reinforced composites.
PubMed:Influence of thermal cycling on flexural properties of composites reinforced with unidirectional silica-glass fibers.
PubMed:Effect of methacrylic monomers on phagocytes reactive oxygen species: a possible BDDMA modulating action.
PubMed:Electron-beam irradiation of experimental denture base polymers.
PubMed:Dendritic copolymers and particulate filler composites for dental applications: degree of conversion and thermal properties.
PubMed:Mechanical and physical properties of carbon-graphite fiber-reinforced polymers intended for implant suprastructures.
PubMed:Polymer-based monolithic microcolumns for hydrophobic interaction chromatography of proteins.
PubMed:Analysis of residual monomers in dendritic methacrylate copolymers and composites by HPLC and headspace-GC/MS.
PubMed:Evaluation of two matrix materials intended for fiber-reinforced polymers.
PubMed:Physicochemical evaluation of silica-glass fiber reinforced polymers for prosthodontic applications.
PubMed:Resistance of medical gloves to permeation by methyl methacrylate (MMA), ethylene glycol dimethacrylate (EGDMA), and 1,4-butanediol dimethacrylate (1,4-BDMA).
PubMed:Permeability of different types of medical protective gloves to acrylic monomers.
PubMed:Chemical synthesis of NS-1 region of hepatitis C-viral polyprotein fragments: a comparison of PS-BDODMA resin and merrifield resin.
PubMed:An efficient gel-phase synthesis of peptides on a high capacity flexible crosslinked polystyrene support: comparison with Merrifield resin.
PubMed:Solid phase synthesis of hydrophobic difficult sequence peptides on BDDMA-PS support.
PubMed:Gel-Phase synthesis of hydrophobic (thr14) (thr19) galanin (1 -19) fragment on a high capacity flexible crosslinked polystyrene support.
PubMed:Synthesis of esculentin-1 antibacterial peptide fragments on 1,4-butanediol dimethacrylate cross-linked polystyrene support.
PubMed:Syntheses of immunodominant peptide regions of hepatitis C viral pathogens using PS-BDODMA resin: a single peptide derived from the conserved domain (E2/NS1) was highly effective in detecting anti-HCV antibodies.
PubMed:Experimental studies on the application of a porcelain-light-cured resin matrix system to the porcelain margin of metal-ceramic crowns.
PubMed:Properties of poly(2-hydroxyethyl acrylate) networks.
contains 100 ppm p-methoxyphenol as stabilizer; referred to as 1,3-butanodiol dimethacrylate in text; do not confuse with benzyldimethylamine.
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