EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

beta-dextro-pentaacetyl glucose
1,2,3,4,6-penta-O-acetyl-b-D-glucopyranose

Supplier Sponsors

Name:[(2R,3R,5R,6S)-3,4,5,6-tetraacetyloxyoxan-2-yl]methyl acetate
CAS Number: 604-69-3Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:210-074-8
FDA UNII: V833P95COC
Beilstein Number:0098851
MDL:MFCD00006597
XlogP3:0.60 (est)
Molecular Weight:390.34254000
Formula:C16 H22 O11
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:information only not used for fragrances or flavors
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 130.00 to 134.00 °C. @ 760.00 mm Hg
Boiling Point: 434.00 to 435.00 °C. @ 760.00 mm Hg (est)
Flash Point: 370.00 °F. TCC ( 188.10 °C. ) (est)
logP (o/w): 0.634 (est)
Soluble in:
 alcohol
 water, 900 mg/L @ 18C (exp)
 
Organoleptic Properties:
Odor Strength:none
Odor Description:at 100.00 %. odorless
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
1,2,3,4,6-Penta-O-acetyl-b-D-glucopyranose
Carbosynth
For experimental / research use only.
1,2,3,4,6-Penta-O-acetyl-b-D-glucopyranose
Glentham Life Sciences
1,2,3,4,6-Penta-O-acetyl-b-D-glucopyranose
Santa Cruz Biotechnology
For experimental / research use only.
β-D-Glucose Pentaacetate
Sigma-Aldrich: Aldrich
For experimental / research use only.
β-D-Glucose pentaacetate 98%
TCI AMERICA
For experimental / research use only.
Penta-O-acetyl-β-D-glucopyranose >99.0%(GC)
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
information only not used for fragrances or flavors
Recommendation for beta-dextro-pentaacetyl glucose usage levels up to:
 not for fragrance use.
 
Recommendation for beta-dextro-pentaacetyl glucose flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :99332
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
[(2R,3R,5R,6S)-3,4,5,6-tetraacetyloxyoxan-2-yl]methyl acetate
Chemidplus:0000604693
 
References:
 [(2R,3R,5R,6S)-3,4,5,6-tetraacetyloxyoxan-2-yl]methyl acetate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:604-69-3
Pubchem (cid):99332
Pubchem (sid):135056780
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2940.00.6000
ChemSpider:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
beta-d-glucopyranose, pentaacetate
β-D-glucopyranose, pentaacetate
beta-D-glucose pentaacetate
beta-dextro-glucose pentaacetate
1,2,3,4,6-penta-O-acetyl-b-D-glucopyranose
beta-D-pentaacetyl glucose
[(2R,3R,5R,6S)-3,4,5,6-tetraacetyloxyoxan-2-yl]methyl acetate
 

Articles:

PubMed:Insulin release: the receptor hypothesis.
PubMed:Deuterium-induced isotope effects on the 13C chemical shifts of α-D-glucose pentaacetate.
PubMed:Selective formation of glycosidic linkages of N-unsubstituted 4-hydroxyquinolin-2-(1H)-ones.
PubMed:Sugar acetates as CO2-philes: molecular interactions and structure aspects from absorption measurement using quartz crystal microbalance.
PubMed:A simple preparation of 2,3,4,6-tetra-o-acyl-gluco-, galacto- and mannopyranoses and relevant theoretical study.
PubMed:Preparation of nucleoside-carbohydrate phosphodiester prodrug analogues by chemoenzymatic procedure.
PubMed:Directed assembly of sub-nanometer thin organic materials with programmed-size nanopores.
PubMed:Measurement of gluconeogenesis using glucose fragments and mass spectrometry after ingestion of deuterium oxide.
PubMed:Characterization of a new rhamnogalacturonan acetyl esterase from Bacillus halodurans C-125 with a new putative carbohydrate binding domain.
PubMed:YesT: a new rhamnogalacturonan acetyl esterase from Bacillus subtilis.
PubMed:Examination of glass transitions in CO(2)-processed, peracetylated sugars using sum frequency generation spectroscopy.
PubMed:Mirror-image carbohydrates: synthesis of the unnatural enantiomer of a blood group trisaccharide.
PubMed:Monosaccharide esters: new tools in biomedicine.
PubMed:Monosaccharide esters: clinically relevant?
PubMed:Synthesis of 2-thiohydantoins and their S-glucosylated derivatives as potential antiviral and antitumor agents.
PubMed:Synthesis and antiperoxidant activity of new phenolic O-glycosides.
PubMed:Metabolism of alpha-D-[1,2-13C]glucose pentaacetate and alpha-D-glucose penta[2-13C]acetate in rat hepatocytes.
PubMed:Activation of glycogen synthase a in hepatocytes exposed to alpha-D-glucose pentaacetate.
PubMed:Stimulation of insulin synthesis and release by alpha-D-glucose pentaacetate in pancreatic islets from human subjects.
PubMed:Metabolism of D-[1,2-13C]glucose and alpha-D-[1,2-13C]glucose pentaacetate in tumoral pancreatic islet cells.
PubMed:Metabolism of d-glucose and its pentaacetate ester in muscles and pancreatic islets of GLUT4 null mice.
PubMed:Effect of D-mannoheptulose upon the cationic and secretory responses to alpha-D-glucose pentaacetate in perifused rat pancreatic islets.
PubMed:Differences in the time course of the metabolic response of B and non-B pancreatic islet cells to D-glucose and metabolized or non-metabolized hexose esters.
PubMed:Effects of extracellular pH upon the insulinotropic action of alpha-D-glucose pentaacetate.
PubMed:Isomeric and anomeric specificity of the metabolic and secretory response of rat pancreatic islets to glucose pentaacetate.
PubMed:Regioselective hydrolysis of peracetylated alpha-D-glycopyranose catalyzed by immobilized lipases in aqueous medium. A facile preparation of useful intermediates for oligosaccharide synthesis.
PubMed:Insulinotropic action of monosaccharide esters: therapeutic perspectives.
PubMed:Opposite effects of D-glucose pentaacetate and D-galactose pentaacetate anomers on insulin release evoked by succinic acid dimethyl ester in rat pancreatic islets.
PubMed:Effects of alpha-D- and beta-L-glucose pentaacetate on effluent radioactivity from pancreatic islets labelled with [(32)P]phosphate and myo-[2-(3)H]inositol.
PubMed:Effects of artificial sweeteners on insulin release and cationic fluxes in rat pancreatic islets.
PubMed:Effects of hexose pentaacetates on electrical activity and cytosolic Ca2+ in mouse pancreatic islets.
PubMed:Failure of streptozotocin tetraacetate to undergo extensive hydrolysis and to inhibit D-glucose metabolism and insulinotropic action in rat pancreatic islets.
PubMed:The riddle of L-glucose pentaacetate insulinotropic action (review).
PubMed:Insulinotropic action of the polyacetate esters of two non-nutrient monosaccharides in normal and diabetic rats.
PubMed:Insulinotropic action of beta-L-glucose pentaacetate.
PubMed:Monosaccharide esters: new tools in biomedical research.
PubMed:Hydrolysis of hexose pentaacetate esters in rat pancreatic islets.
PubMed:Dual mode of action of glucose pentaacetates on hormonal secretion from the isolated perfused rat pancreas.
PubMed:Comparison of the effects of D-mannoheptulose and its hexaacetate ester on D-glucose metabolism and insulinotropic action in rat pancreatic islets.
PubMed:Insulinotropic action of alpha-D-glucose pentaacetate: metabolic aspects.
PubMed:Stimulation by hexose esters of lactate production by rat erythrocytes: insensitivity to 3-O-methyl-D-glucose and inhibition by 2-deoxy-D-glucose and its tetraacetic ester.
PubMed:Resistance of the insulinotropic action of alpha-D-glucose and beta-L-glucose pentaacetates to cholera and pertussis toxins.
PubMed:Synergistic insulinotropic action of succinate, acetate, and glucose esters in islets from normal and diabetic rats.
PubMed:Insulinotropic action of the polyacetate esters of metabolized and non-metabolized monosaccharides in pancreatic islets from normal and diabetic rats.
PubMed:Bitter taste of monosaccharide pentaacetate esters.
PubMed:Insulinotropic action of alpha-D-glucose pentaacetate: functional aspects.
PubMed:Stimulation of insulin release by alpha-D-glucose pentaacetate.
PubMed:SW.B6-Soa(b) nontaster congenic strains completed and a sucrose octaacetate congenic quartet tested with other bitters.
PubMed:Mass isotopomer pattern and precursor-product relationship.
PubMed:Esterase Activities of Fibrobacter succinogenes subsp. succinogenes S85.
PubMed:Preparation of various glucose esters via lipase-catalyzed hydrolysis of glucose pentaacetate.
PubMed:Rapid and specific isolation of radioactive glucose from biological samples.
PubMed:Utilization of propionic acid by the L4 and adult stages of Cooperia punctata (Nematoda: Trichostrongylidae) grown in vitro.
PubMed:Rapid determination of (carbon-14) glucose specific radioactivity for in vivo glucose kinetics.
PubMed:DETERMINATION OF THE SPECIFIC ACTIVITY OF LABELED BLOOD GLUCOSE BY LIQUID SCINTILLATION USING GLUCOSE PENTAACETATE.
PubMed:The suitability of beta-D-glucose pentaacetate for food use. I. The subscute toxicity of beta-D-glucose pentaacete.
PubMed:The suitability of beta-D-glucose pentaacetate for food use. II. Studies on the absorption and metabolism.
PubMed:Action of the Grignard reagent on beta-d-glucose pentaacetate.
 
Notes:
None found
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