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napropamide
propanamide, N,N-diethyl-2-(1-naphthalenyloxy)-

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Name:N,N-diethyl-2-naphthalen-1-yloxypropanamide
CAS Number: 15299-99-7Picture of molecule3D/inchi
Other(deleted CASRN):154799-64-1
ECHA EINECS - REACH Pre-Reg:239-333-3
FDA UNII: B56M9401K6
Nikkaji Web:J1.863E
Beilstein Number:2217870
MDL:MFCD00055354
XlogP3-AA:3.40 (est)
Molecular Weight:271.35977000
Formula:C17 H21 N O2
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
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Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 75.00 °C. @ 760.00 mm Hg
logP (o/w): 3.360
Soluble in:
 water, 73 mg/L @ 20 °C (exp)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
Napropamid
Odor: characteristic
Use: Napropamid is a selective systemic amide herbicide which is used against a number of annual grasses and broad-leaved weeds for inhibiting root development and growth.
Sigma-Aldrich
For experimental / research use only.
Napropamid PESTANAL®, analytical standard
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
intraperitoneal-mouse LD50 > 1000 mg/kg
Niigata Igakkai Zasshi. Niigata Medical Journal. Vol. 87, Pg. 289, 1973.

oral-mouse LD50 > 5000 mg/kg
Niigata Igakkai Zasshi. Niigata Medical Journal. Vol. 87, Pg. 289, 1973.

oral-rat LD50 5000 mg/kg
"Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 2, Pg. 59, 1977.

parenteral-rat LD50 > 5000 mg/kg
Defense des Vegetaux. Vol. 26, Pg. 5, 1972.

Dermal Toxicity:
skin-guinea pig LD50 > 2000 mg/kg
"Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A292, Pg. 1983

subcutaneous-mouse LD50 > 1000 mg/kg
Niigata Igakkai Zasshi. Niigata Medical Journal. Vol. 87, Pg. 289, 1973.

skin-rabbit LD50 4640 mg/kg
Pesticide & Toxic Chemical News. Vol. 8, Pg. 22, 1980.

Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
herbicides / pesticides
Recommendation for napropamide usage levels up to:
 not for fragrance use.
 
Recommendation for napropamide flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Outcome of the consultation with Member States, the applicant and EFSA on the pesticide risk assessment for napropamide in light of confirmatory data
View page or View pdf

Review of the existing maximum residue levels for napropamide according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf

Peer review of the pesticide risk assessment of the active substance napropamide-M
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :27189
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
N,N-diethyl-2-naphthalen-1-yloxypropanamide
Chemidplus:0015299997
RTECS:UE3600000 for cas# 15299-99-7
 
References:
 N,N-diethyl-2-naphthalen-1-yloxypropanamide
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):27189
Pubchem (sid):134992693
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C18868
HMDB (The Human Metabolome Database):Search
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 devrinol
N,N-diethyl-2-(1-naphthyloxy)propanamide
N,N-diethyl-2-naphthalen-1-yloxypropanamide
 propanamide, N,N-diethyl-2-(1-naphthalenyloxy)-
 

Articles:

PubMed:Enantioselective phytotoxicity and bioacitivity of the enantiomers of the herbicide napropamide.
PubMed:Simultaneous determination of herbicide residues in tobacco using ultraperformance convergence chromatography coupled with solid-phase extraction.
PubMed:The chiral separation and enantioselective degradation of the chiral herbicide napropamide.
PubMed:Napropamide.
PubMed:Sorption of selected pesticides on soils, sediment and straw from a constructed agricultural drainage ditch or pond.
PubMed:Fate of napropamide herbicide in selected Malaysian soils.
PubMed:Biodegradation of soil-applied pesticides by selected strains of plant growth-promoting rhizobacteria (PGPR) and their effects on bacterial growth.
PubMed:The maintenance of the second-order advantage: second-order calibration of excitation-emission matrix fluorescence for quantitative analysis of herbicide napropamide in various environmental samples.
PubMed:Accumulation and residue of napropamide in alfalfa (Medicago sativa) and soil involved in toxic response.
PubMed:The action of herbicides on fatty acid biosynthesis and elongation in barley and cucumber.
PubMed:Effect of dissolved organic matters on napropamide availability and ecotoxicity in rapeseed ( Brassica napus ).
PubMed:Salicylic acid reduces napropamide toxicity by preventing its accumulation in rapeseed (Brassica napus L.).
PubMed:Alteration of microbial properties and community structure in soils exposed to napropamide.
PubMed:Assessment of heavy metal and pesticide levels in soil and plant products from agricultural area of Belgrade, Serbia.
PubMed:Automatic chemiluminescence-based determination of carbaryl in various types of matrices.
PubMed:[Degradation and adsorption behavior of napropamide in soils].
PubMed:Surface photochemistry of the herbicide napropamide. The role of the media and environmental factors in directing the fates of intermediates.
PubMed:Persistence of napropamide in/on tea under North-East Indian climatic condition.
PubMed:[Characterization of napropamide enantiomers by CD and determination of the enantiomeric ratios in water].
PubMed:Application of automated mass spectrometry deconvolution and identification software for pesticide analysis in surface waters.
PubMed:[Effects of dissolved organic matter on napropamide adsorption and transport in soil system].
PubMed:Determination of diphenamide, napropamide and metolachlor in tobacco by gel permeation chromatographic clean-up and high performance liquid chromatography.
PubMed:Impact of soil amendments on broccoli quality and napropamide movement under field conditions.
PubMed:Napropamide residues in runoff and infiltration water from pepper production.
PubMed:Simple determination of the herbicide napropamide in water and soil samples by room temperature phosphorescence.
PubMed:Picloram and napropamide sorption as affected by polymer addition and salt concentration.
PubMed:Molecular weight of dissolved organic matter-napropamide complex transported through soil columns.
PubMed:Determination of the pesticide napropamide in soil, pepper, and tomato by micelle-stabilized room-temperature phosphorescence.
PubMed:Focused microwave assistance for extracting some pesticide residues from strawberries into water before their determination by SPME/HPLC/DAD.
PubMed:Toxico-kinetics, recovery, and metabolism of napropamide in goats following a single high-dose oral administration.
PubMed:Solid-phase microextraction coupled with high performance liquid chromatography: a complementary technique to solid-phase microextraction-gas chromatography for the analysis of pesticide residues in strawberries.
PubMed:Sorption and photolysis studies in soil and sediment of the herbicide napropamide.
PubMed:[An analysis of maicaodi by high performance liquid chromatography].
PubMed:Stereoselective analysis of herbicides by capillary electrophoresis using sulfobutyl ether beta-cyclodextrin as chiral selector.
PubMed:Fluorescence lifetime measurements of fluoranthene, 1-naphthol, and napropamide in the presence of dissolved humic Acid.
PubMed:Relevance of enantiomeric separations in environmental science.
PubMed:Applicability of a carbamate insecticide multiresidue method for determining additional types of pesticides in fruits and vegetables.
PubMed:Herbicidal treatments for control of Papaver somniferum L.
PubMed:Herbicidal treatments for control of Cannabis sativa L.
 
Notes:
None found
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