EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

glufosinate
DL-phosphinothricin

Supplier Sponsors

CAS Number: 51276-47-2Picture of molecule3D/inchi
Other(deleted CASRN):126633-48-5
ECHA EINECS - REACH Pre-Reg:257-102-5
FDA UNII: C8W4FP6BTY
Nikkaji Web:J8.581B
XlogP3:-5.00 (est)
Molecular Weight:181.12820200
Formula:C5 H12 N O4 P
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 230.00 °C. @ 760.00 mm Hg
Boiling Point: 519.10 °C. @ 760.00 mm Hg (est)
Flash Point: 514.00 °F. TCC ( 267.70 °C. ) (est)
logP (o/w): -0.750 (est)
Soluble in:
 water, 1e+006 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
BOC Sciences
For experimental / research use only.
Glufosinate
 
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
herbicides / pesticides
Recommendation for glufosinate usage levels up to:
 not for fragrance use.
 
Recommendation for glufosinate flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Reasoned opinion on the review of the existing maximum residue levels (MRLs) for for glufosinate according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf

Retrospective analysis of the immunotoxic effects of plant protection products as reported in the Draft Assessment Reports for their peer review at EU level
View page or View pdf

Protocol for the evaluation of data concerning the necessity of the application of herbicide active substances to control a serious danger to plant health which cannot be contained by other available means, including non-chemical methods
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :4794
National Institute of Allergy and Infectious Diseases:Data
2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid
Chemidplus:0051276472
 
References:
 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):4794
Pubchem (sid):135049171
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C05042
HMDB (The Human Metabolome Database):Search
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
3-amino-3-carboxypropylmethylphosphinic acid
DL-2-amino-4-(methylphosphino)butanoic acid
2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid
 butanoic acid, 2-amino-4-(hydroxymethylphosphinyl)-
 phosphinothricin
(+-)-phosphinothricin
DL-phosphinothricin
 

Articles:

PubMed:Insect-Protected Event DAS-81419-2 Soybean (<i>Glycine max<i> L.) Grown in the United States and Brazil is Compositionally Equivalent to Non-Transgenic Soybean.
PubMed:Chromatic Biosensor for Detection of Phosphinothricin Acetyltransferase by Use of Polydiacetylene Vesicles Encapsulated within Automatically Generated Immunohydrogel Beads.
PubMed:Transgene flow: Facts, speculations and possible countermeasures.
PubMed:A review of methods for the analysis of orphan and difficult pesticides: glyphosate, glufosinate, quaternary ammonium and phenoxy acid herbicides, and dithiocarbamate and phthalimide fungicides.
PubMed:Rapid detection of pesticides not amenable to multi-residue methods by flow injection-tandem mass spectrometry.
PubMed:Effect of metabolic inhibitors on growth and carotenoid production in Dunaliella bardawil.
PubMed:Simultaneous LC-MS/MS analysis of glyphosate, glufosinate, and their metabolic products in beer, barley tea, and their ingredients.
PubMed:Compositional equivalence of DAS-444Ø6-6 (AAD-12 + 2mEPSPS + PAT) herbicide-tolerant soybean and nontransgenic soybean.
PubMed:Accumulation of PrLeg, a Perilla legumin protein in potato tuber results in enhanced level of sulphur-containing amino acids.
PubMed:Compositional safety of herbicide-tolerant DAS-81910-7 cotton.
PubMed:[Determination of glufosinate residue in tea by liquid chromatography-tandem mass spectrometry coupled with precolumn derivatization].
PubMed:Fast and interference-free determination of glyphosate and glufosinate residues through electrophoresis in disposable microfluidic chips.
PubMed:Composition of grain and forage from insect-protected and herbicide-tolerant corn, MON 89034 × TC1507 × MON 88017 × DAS-59122-7 (SmartStax), is equivalent to that of conventional corn (Zea mays L.).
PubMed:Thirteen week rodent feeding study with grain from molecular stacked trait lepidopteran and coleopteran protected (DP-ØØ4114-3) maize.
PubMed:Spontaneous renal tumors in two rats from a thirteen week rodent feeding study with grain from molecular stacked trait lepidopteran and coleopteran resistant (DP-ØØ4114-3) maize.
PubMed:Surveying of pollen-mediated crop-to-crop gene flow from a wheat field trial as a biosafety measure.
PubMed:Bayer CropScience's position on the findings of glufosinate and its metabolite.
PubMed:The impact of altered herbicide residues in transgenic herbicide-resistant crops on standard setting for herbicide residues.
PubMed:A rapid liquid chromatography method for determination of glufosinate residue in maize after derivatisation.
PubMed:Microbead-assisted PDA sensor for the detection of genetically modified organisms.
PubMed:Maternal and fetal exposure to pesticides associated to genetically modified foods in Eastern Townships of Quebec, Canada.
PubMed:Expression of PAT and NPT II proteins during the developmental stages of a genetically modified pepper developed in Korea.
PubMed:Relevance of traditional integrated pest management (IPM) strategies for commercial corn producers in a transgenic agroecosystem: a bygone era?
PubMed:Monitoring of Bt11 and Bt176 genetically modified maize in food sold commercially in Brazil from 2005 to 2007.
PubMed:Cell viability and PSA secretion assays in LNCaP cells: a tiered in vitro approach to screen chemicals with a prostate-mediated effect on male reproduction within the ReProTect project.
PubMed:Enrichment and low-level determination of glyphosate, aminomethylphosphonic acid and glufosinate in drinking water after cleanup by cation exchange resin.
PubMed:Glyphosate effect on shikimate, nitrate reductase activity, yield, and seed composition in corn.
PubMed:Reproductive phenology of transgenic Brassica napus cultivars: Effect on intraspecific gene flow.
PubMed:[Culture of transgenic Glycyrrhiza uralensis hairy root with licorice squalene synthase (SQS) gene].
PubMed:Collaborative trial validation studies of real-time PCR-based GMO screening methods for detection of the bar gene and the ctp2-cp4epsps construct.
PubMed:Multiplex PCR-based simultaneous amplification of selectable marker and reporter genes for the screening of genetically modified crops.
PubMed:Decontamination of aqueous glyphosate, (aminomethyl)phosphonic acid, and glufosinate solutions by electro-fenton-like process with Mn2+ as the catalyst.
PubMed:Pollen-mediated gene flow from transgenic safflower (Carthamus tinctorius L.) intended for plant molecular farming to conventional safflower.
PubMed:Subchronic feeding study with genetically modified stacked trait lepidopteran and coleopteran resistant (DAS-Ø15Ø7-1xDAS-59122-7) maize grain in Sprague-Dawley rats.
PubMed:The pleiotropic effects of the bar gene and glufosinate on the Arabidopsis transcriptome.
PubMed:Evaluation of corn grain with the genetically modified input trait DAS-59122-7 fed to growing-finishing pigs.
PubMed:Enhancement of carotenoids by mutation and stress induced carotenogenic genes in Haematococcus pluvialis mutants.
PubMed:Environmental impact of herbicide regimes used with genetically modified herbicide-resistant maize.
PubMed:Comparison of grain from corn rootworm resistant transgenic DAS-59122-7 maize with non-transgenic maize grain in a 90-day feeding study in Sprague-Dawley rats.
PubMed:Quantitative analysis of phosphinothricin-N-acetyltransferase in genetically modified herbicide tolerant pepper by an enzyme-linked immunosorbent assay.
PubMed:Hereditary behavior of bar gene cassette is complex in rice mediated by particle bombardment.
PubMed:Metabolic engineering of novel ketocarotenoid production in carrot plants.
PubMed:Evaluating homogeneity of LL601 rice in commercial lots using quantitative real-time PCR.
PubMed:Sampling plan and test protocol for the semiquantitative detection of genetically modified canola (Brassica napus) seed in bulk canola seed.
PubMed:Subchronic feeding study of DAS-59122-7 maize grain in Sprague-Dawley rats.
PubMed:Cardiovascular effects of herbicides and formulated adjuvants on isolated rat aorta and heart.
PubMed:Event-specific qualitative and quantitative polymerase chain reaction analysis for genetically modified canola T45.
PubMed:Thirteen week feeding study with transgenic maize grain containing event DAS-Ø15Ø7-1 in Sprague-Dawley rats.
PubMed:Compositional assessment of event DAS-59122-7 maize using substantial equivalence.
PubMed:Peas (Pisum sativum L.).
PubMed:Atomic structure of plant glutamine synthetase: a key enzyme for plant productivity.
PubMed:Phosphinothricin analogues as inhibitors of plant glutamine synthetases.
PubMed:Biosafety considerations for selectable and scorable markers used in cassava (Manihot esculenta Crantz) biotechnology.
PubMed:Improved ELISA method for screening human antigen-specific IgE and its application for monitoring specific IgE for novel proteins in genetically modified foods.
PubMed:Evaluation of detection methods for genetically modified traits in genotypes resistant to European corn borer and herbicides.
PubMed:Effects of dispersal, predators (Acari: Phytoseiidae), weather, and ground cover treatments on populations of Tetranychus urticae (Acari: Tetranychidae) in apple orchards.
PubMed:Application of immunoaffinity column as cleanup tool for an enzyme linked immunosorbent assay of phosphinothricin-N-acetyltransferase detection in genetically modified maize and rape.
PubMed:Glufosinate herbicide-tolerant (LibertyLink) rice vs. conventional rice in diets for growing-finishing swine.
PubMed:Rice (Oryza sativa L.) containing the bar gene is compositionally equivalent to the nontransgenic counterpart.
PubMed:Physiological and biochemical characterization of quinclorac resistance in a false cleavers (Galium spurium L.) biotype.
PubMed:Safety evaluation of the phosphinothricin acetyltransferase proteins encoded by the pat and bar sequences that confer tolerance to glufosinate-ammonium herbicide in transgenic plants.
PubMed:Simultaneous quantification of glyphosate, glufosinate, and their major metabolites in rice and soybean sprouts by gas chromatography with pulsed flame photometric detector.
PubMed:Herbicidal pyridyl derivatives of aminomethylene-bisphosphonic acid inhibit plant glutamine synthetase.
PubMed:Development of antibodies for the detection of N-acetyl-glufosinate.
PubMed:Comparative study of in vitro digestibility of food proteins and effect of preheating on the digestion.
PubMed:Circadian response of annual weeds in a natural setting to high and low application rates of four herbicides with different modes of actions.
PubMed:[Rapid analysis of glufosinate by improving the bulletin method and its application to soybean and corn].
PubMed:Glufosinate-ammonium reduces growth and aflatoxin B1 production by Aspergillus flavus.
PubMed:Circadian response of annual weeds to glyphosate and glufosinate.
PubMed:Determination of glufosinate ammonium and its metabolite (AE F064619 and AE F061517) residues in water by gas chromatography with tandem mass spectrometry after ion exchange cleanup and derivatization.
PubMed:Transformation of peas (Pisum sativum L.) using immature cotyledons.
PubMed:Hairy roots of Brassica napus: II. Glutamine synthetase overexpression alters ammonia assimilation and the response to phosphinothricin.
PubMed:Hairy roots of Brassica napus: I. Applied glutamine overcomes the effect of phosphinothricin treatment.
PubMed:Glufosinate ammonium--some aspects of its mode of action in mammals.
PubMed:Summary of safety evaluation toxicity studies of glufosinate ammonium.
 
Notes:
None found
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