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tralkoxydim
2-cyclohexen-1-one, 2-(1-(ethoxyimino)propyl)-3-hydroxy-5-(2,4,6-trimethylphenyl)-

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Name:2-[1-(ethoxyamino)propylidene]-5-(2,4,6-trimethylphenyl)cyclohexane-1,3-dione
CAS Number: 87820-88-0Picture of molecule3D/inchi
FDA UNII: 39J71H3DDD
Nikkaji Web:J482.675B
Beilstein Number:8577523
MDL:MFCD00145415
XlogP3-AA:4.50 (est)
Molecular Weight:329.43979000
Formula:C20 H27 N O3
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
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Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
 
Physical Properties:
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: 106.00 °C. @ 760.00 mm Hg
logP (o/w): 4.460
Soluble in:
 water, 5 mg/L @ 20 °C (exp)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
Sigma-Aldrich
For experimental / research use only.
Tralkoxydim PESTANAL®, analytical standard
TCI AMERICA
For experimental / research use only.
Tralkoxydim >95.0%(HPLC)(N)
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
unreported-bird - wild LD50 4430 mg/kg
Proceedings of the British Crop Protection Conference - Weeds. Vol. -, Pg. 19, 1987.

oral-duck LD50 > 3020 mg/kg
Pesticide Manual. Vol. 9, Pg. 828, 1991.

oral-mouse LD50 1100 mg/kg
Proceedings of the British Crop Protection Conference - Weeds. Vol. -, Pg. 19, 1987.

oral-quail LD50 6237 mg/kg
Proceedings of the British Crop Protection Conference - Weeds. Vol. -, Pg. 19, 1987.

oral-rat LD50 934 mg/kg
Farm Chemicals Handbook. Vol. -, Pg. C158, 1991.

Dermal Toxicity:
skin-rat LD50 > 2000 mg/kg
Proceedings of the British Crop Protection Conference - Weeds. Vol. -, Pg. 19, 1987.

Inhalation Toxicity:
inhalation-rat LC50 > 3467 mg/m3
Proceedings of the British Crop Protection Conference - Weeds. Vol. -, Pg. 19, 1987.

 
Safety in Use Information:
Category:
herbicides / pesticides
Recommendation for tralkoxydim usage levels up to:
 not for fragrance use.
 
Recommendation for tralkoxydim flavor usage levels up to:
 not for flavor use.
 
Safety References:
European Food Safety Authority (EFSA) reference(s):

Review of the existing maximum residue levels for tralkoxydim according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :91746
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
2-[1-(ethoxyamino)propylidene]-5-(2,4,6-trimethylphenyl)cyclohexane-1,3-dione
Chemidplus:0087820880
RTECS:GW7191600 for cas# 87820-88-0
 
References:
 2-[1-(ethoxyamino)propylidene]-5-(2,4,6-trimethylphenyl)cyclohexane-1,3-dione
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):91746
Pubchem (sid):135049177
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C18769
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2928.00.5000
ChemSpider:View
Wikipedia:View
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
2-cyclohexen-1-one, 2-(1-(ethoxyimino)propyl)-3-hydroxy-5-(2,4,6-trimethylphenyl)-
2-[1-(ethoxyamino)propylidene]-5-(2,4,6-trimethylphenyl)cyclohexane-1,3-dione
2-(1-(ethoxyimino)propyl)-3-hydroxy-5-(2,4,6-trimethylphenyl)-2-cyclohexen-1-one
2-(1-(ethoxyimino)propyl)-3-hydroxy-5-(2,4,6-trimethylphenyl)cyclohex-2-enone
2-(1-(ethoxyimino)propyl)-3-hydroxy-5-mesitylcyclohex-2-enone
 tralkoxydime
 

Articles:

PubMed:Chemical control of herbicide-resistant Lolium rigidum Gaud. in north-eastern Spain.
PubMed:Resistance to ACCase-inhibiting herbicides in the weed Lolium multiflorum.
PubMed:[Effect of herbicide tralkoxydim and 2-acylcyclohexane-1,3-diones on peroxidase activity].
PubMed:Pheromone biosynthetic pathways: PBAN-regulated rate-limiting steps and differential expression of desaturase genes in moth species.
PubMed:[Determination of six pesticides in milk using cloud point extraction-high performance liquid chromatography].
PubMed:Diversity of acetyl-coenzyme A carboxylase mutations in resistant Lolium populations: evaluation using clethodim.
PubMed:Hepatic porphyria induced by the herbicide tralkoxydim in small mammals is species-specific.
PubMed:EK-2612, a new cyclohexane-1,3-dione possessing selectivity between rice (Oryza sativa) and barnyardgrass (Echinochloa crus-galli).
PubMed:Cross-resistance to ACCase inhibitors of Lolium multiflorum, Lolium perenne and Lolium rigidum found in Chile.
PubMed:Resistance to ACCase-inhibiting herbicides and isoproturon in UK populations of Lolium multiflorum: mechanisms of resistance and implications for control.
PubMed:Inhibition of ACCase220 and ACCase240 isozymes from sethoxydim-resistant and -susceptible maize hybrids.
PubMed:Cross-Resistance to Herbicides in Annual Ryegrass (Lolium rigidum): I. Properties of the Herbicide Target Enzymes Acetyl-Coenzyme A Carboxylase and Acetolactate Synthase.
PubMed:Inhibition of Acetyl-CoA Carboxylase Activity by Haloxyfop and Tralkoxydim.
 
Notes:
an alkyl ketone herbicide.
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