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dicyclopentadiene
3a,4,7,7a-tetrahydro-4,7-methanoindene

Supplier Sponsors

CAS Number: 77-73-6Picture of molecule3D/inchi
Other(deleted CASRN):107760-16-7
ECHA EINECS - REACH Pre-Reg:201-052-9
FDA UNII: Search
Nikkaji Web:J9.241J
Beilstein Number:1904092
MDL:MFCD00078246
XlogP3-AA:2.50 (est)
Molecular Weight:132.20564000
Formula:C10 H12
BioActivity Summary:listing
NMR Predictor:Predict (works with chrome, Edge or firefox)
Category:indirect food additives: adhesives and components of coatings
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
DG SANTE Food Contact Materials:dicyclopentadiene
FDA Mainterm (IAUFC):77-73-6 ; DICYCLOPENTADIENE
 
Physical Properties:
Appearance:colorless to pale yellow clear liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Melting Point: -1.00 °C. @ 760.00 mm Hg
Boiling Point: 170.00 °C. @ 760.00 mm Hg
Vapor Pressure:2.000000 mmHg @ 25.00 °C. (est)
Vapor Density:4.55 ( Air = 1 )
Flash Point: 116.00 °F. TCC ( 46.80 °C. ) (est)
logP (o/w): 3.300 (est)
Soluble in:
 water, 51.88 mg/L @ 25 °C (est)
 
Organoleptic Properties:
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
Aston Chemical
For experimental / research use only.
Dicyclopentadiene
LyondellBasell Industries
Dicyclopentadiene
Penta International
DICYCLOPENTADIENE
Sigma-Aldrich: Aldrich
For experimental / research use only.
Dicyclopentadiene contains BHT as stabilizer
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-cattle LD50 1200 mg/kg
BEHAVIORAL: ATAXIA GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
National Technical Information Service. Vol. AD-A093-673

intraperitoneal-mammal (species unspecified) LD50 960 mg/kg
National Technical Information Service. Vol. AD-A087-257

intraperitoneal-mouse LD50 200 mg/kg
Progress Report for Contract No. PH-43-64-886, Submitted to the National Cancer Institute by The Institute of Chemical Biology, University of San Francisco. Vol. PH43-64-886

oral-mouse LD50 190 mg/kg
"Proceedings of the International Congress on Toxicology, Toxicology as a Predictive Science, 1st, Toronto, 1977," Plaa, G.L., and W.A. Duncan, eds., New York, Academic Press, Inc., 1978Vol. -, Pg. 448, 1978.

intraperitoneal-rat LD50 200 mg/kg
Progress Report for Contract No. PH-43-64-886, Submitted to the National Cancer Institute by The Institute of Chemical Biology, University of San Francisco. Vol. PH43-64-886

oral-rat LD50 353 mg/kg
BEHAVIORAL: MUSCLE WEAKNESS BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Toxicology and Applied Pharmacology. Vol. 20, Pg. 552, 1971.

Dermal Toxicity:
skin-rabbit LD50 5080 mg/kg
BEHAVIORAL: MUSCLE WEAKNESS BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Toxicology and Applied Pharmacology. Vol. 20, Pg. 552, 1971.

Inhalation Toxicity:
inhalation-dog LCLo 773 ppm/1H
Toxicology and Applied Pharmacology. Vol. 20, Pg. 552, 1971.

inhalation-guinea pig LC50 770 ppm/4H
Toxicology and Applied Pharmacology. Vol. 20, Pg. 552, 1971.

inhalation-mouse LC50 145 ppm/4H
Toxicology and Applied Pharmacology. Vol. 20, Pg. 552, 1971.

inhalation-rabbit LC50 771 ppm/4H
Toxicology and Applied Pharmacology. Vol. 20, Pg. 552, 1971.

inhalation-rat LC50 660 ppm/4H
BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
National Technical Information Service. Vol. OTS0557739

 
Safety in Use Information:
Category:
indirect food additives: adhesives and components of coatings
Recommendation for dicyclopentadiene usage levels up to:
 not for fragrance use.
 
Recommendation for dicyclopentadiene flavor usage levels up to:
 not for flavor use.
 
Safety References:
EPI System: View
NIOSH International Chemical Safety Cards:search
NIOSH Pocket Guide:search
Chemical Carcinogenesis Research Information System:Search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA GENetic TOXicology:Search
EPA Substance Registry Services (TSCA):77-73-6
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :6492
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
Chemidplus:0000077736
EPA/NOAA CAMEO:hazardous materials
RTECS:77-73-6
 
References:
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:77-73-6
Pubchem (cid):6492
Pubchem (sid):134972645
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Indirect Additives used in Food Contact Substances:View
CHEBI:View
CHEMBL:View
KEGG (GenomeNet):C14411
HMDB (The Human Metabolome Database):Search
ChemSpider:View
Wikipedia:View
Formulations/Preparations:
•65%, 85%, 95% grades •suspension concentrate •grades or purity: 97%
 
Potential Blenders and core components note
None Found
 
Potential Uses:
None Found
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
 bicyclopentadiene
 biscyclopentadiene
1,3-CPD
 cyclopentadiene dimer
1,3-cyclopentadiene, dimer
 DCPD
alpha-dicyclopentadiene (endo form)
 dicyclopentadiene [UN2048] [Flammable liquid]
 dicyklopentadien
4,7-methano-1H-indene, 3a,4,7,7a-tetrahydro-
4,7-methanoindene, 3a,4,7,7a-tetrahydro-
 prometa XP 100
3a,4,7,7a-tetrahydro-4,7-methanoindene
 tricyclo(5.2.1.0)-3,8-decadiene
 

Articles:

US Patents:8,080,691 - Organoleptic compounds
PubMed:Macroporous ZnO foams by high internal phase emulsion technique: synthesis and catalytic activity.
US Patents:Polycyclic lactones as odor- and taste-modifying agents
PubMed:Polylactic acid with improved heat deflection temperatures and self-healing properties for durable goods applications.
PubMed:Chelating ruthenium phenolate complexes: synthesis, general catalytic activity, and applications in olefin metathesis polymerization.
PubMed:Nanocomposite foams from iron oxide stabilized dicyclopentadiene high internal phase emulsions: preparation and bromination.
PubMed:The infinite possible growth ambients that support single-wall carbon nanotube forest growth.
PubMed:Controlling the femtosecond laser-driven transformation of dicyclopentadiene into cyclopentadiene.
PubMed:Deterministic control over high-Z doping of polydicyclopentadiene-based aerogel coatings.
PubMed:Phase separation polymerization of dicyclopentadiene characterized by in operando fluorescence microscopy.
PubMed:Ring Opening Metathesis Polymerisation (ROMP) as a tool for polyHIPes with extraordinary mechanical properties.
PubMed:Inverse electron demand Diels-Alder (iEDDA) functionalisation of macroporous poly(dicyclopentadiene) foams.
PubMed:The use of an emulsion templated microcellular poly(dicyclopentadiene-co-norbornene) membrane as a separator in lithium-ion batteries.
PubMed:Separation of cis-fatty acids from saturated and trans-fatty acids by nanoporous polydicyclopentadiene membranes.
PubMed:Theoretical study on cyclopropanation of endo-dicyclopentadiene with zinc carbenoids: effects of solvent and (ICH2)2Zn.
PubMed:Results of a 90-day inhalation study of dicyclopentadiene in B6C3F1 mice.
PubMed:Metal-cation-based anion exchange membranes.
PubMed:Homogeneous vs heterogeneous polymerization catalysis revealed by single-particle fluorescence microscopy.
PubMed:Reusable biocatalytic crosslinked microparticles self-assembled from enzyme-nanoparticle complexes.
PubMed:Retention of palladium and phosphine ligands using nanoporous polydicyclopentadiene thimbles.
PubMed:Control of femtosecond laser driven retro-Diels-Alder-like reaction of dicyclopentadiene.
PubMed:Adhesion promotion via noncovalent interactions in self-healing polymers.
PubMed:Synthesis of molecularly imprinted polymers via ring-opening metathesis polymerization for solid-phase extraction of bisphenol A.
PubMed:Silica-protected micron and sub-micron capsules and particles for self-healing at the microscale.
PubMed:Ruthenium-indenylidene olefin metathesis catalyst with enhanced thermal stability.
PubMed:Inherently reactive polyHIPE material from dicyclopentadiene.
PubMed:Polymerization of monomer-based ferrofluids.
PubMed:Kinetics of liquid phase catalytic hydrogenation of dicyclopentadiene over Pd/C catalyst.
PubMed:A ring-opening metathesis polymerization route to alkaline anion exchange membranes: development of hydroxide-conducting thin films from an ammonium-functionalized monomer.
PubMed:A room-temperature autonomically-healing PMMA bone cement: influence of composition on fatigue crack propagation rate.
PubMed:Diffusion and flow across nanoporous polydicyclopentadiene-based membranes.
PubMed:Assembly of organic monolayers on polydicyclopentadiene.
PubMed:Study of the adsorption of organic molecules on transition metal exchanged zeolites via solid state NMR. Part 2: adsorption of organic molecules on zeolite NaX, CaX, and CaCoX.
PubMed:Metal-mediated retro Diels-Alder of dicyclopentadiene derivatives: a convenient synthesis of [(Cp-R)M(CO)3] (M = 99mTc, Re) complexes.
PubMed:High-load, oligomeric monoamine hydrochloride: Facile generation via ROM polymerization and application as an electrophile scavenger.
PubMed:Cascade reactions using LiAlH4 and grignard reagents in the presence of water.
PubMed:Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene.
PubMed:A new self-healing epoxy with tungsten (VI) chloride catalyst.
PubMed:Self-healing kinetics and the stereoisomers of dicyclopentadiene.
PubMed:Life extension of self-healing polymers with rapidly growing fatigue cracks.
PubMed:Binuclear half-sandwich cobalt(III) and rhodium(III) ortho-carboranedichalocogenolato complexes with ether chain-bridged bis(cyclopentadienyl) ligand.
PubMed:Simultaneous determination of methyl tert-butyl ether, its degradation products and other gasoline additives in soil samples by closed-system purge-and-trap gas chromatography-mass spectrometry.
PubMed:Photoinduced electron transfer in ionic liquids: use of 2,4,6-triphenylthiapyrylium as a photosensitizer probe.
PubMed:Semi-quantitative immunohistochemical analysis of male rat-specific alpha2u-globulin accumulation for chemical toxicity evaluation.
PubMed:Novel rubbers from cationic copolymerization of soybean oils and dicyclopentadiene. 1. Synthesis and characterization.
PubMed:Fate of gasoline oxygenates in conventional and multilevel wells of a contaminated groundwater table in Düsseldorf, Germany.
PubMed:Identification of hydrocarbon-degrading bacteria in soil by reverse sample genome probing.
PubMed:Raman spectroscopic studies of the cure of dicyclopentadiene (DCPD).
PubMed:Biodegradation of C5+ hydrocarbons by a mixed bacterial consortium from a C(5+)-contaminated site.
PubMed:[Hygienic standards of the occupational air quality established by the Experts on Chemical Agents, 2002].
PubMed:Synthesis, structure, and dynamics of nickelacarboranes incorporating the [nido-7,9-C(2)B(9)H(11)](2)(-) ligand.
PubMed:Glycosylthiomethyl chloride: a new species for S-neoglycoconjugate synthesis. Synthesis of 1-N-glycosylthiomethyl-1,2,3-triazoles.
PubMed:[Gas chromatographic detection of dicyclopentadiene in workplace air].
PubMed:In situ poly(urea-formaldehyde) microencapsulation of dicyclopentadiene.
PubMed:Fate of MTBE and DCPD compounds relative to BTEX in gasoline-contaminated aquifers.
PubMed:[Analysis of C5 fractions and carbonyl compounds by capillary gas chromatography].
PubMed:Preparation and cell growth inhibitory activity of [PtR(2)L(2)] (R=polyfluorophenyl, L(2)=diene, cyclohexane-1,2-diamine (chxn) or cis-(dimethyl sulfoxide)(2)) and the X-ray crystal structure of [Pt(C(6)F(5))(2)(cis-chxn)].
PubMed:Microbial community composition at an ethane pyrolysis plant site at different hydrocarbon inputs.
PubMed:Allergic contact dermatitis from unsaturated polyester resin consisting of maleic anhydride, phthalic anhydride, ethylene glycol and dicyclopentadiene.
PubMed:Copper(I)-catalyzed [2 + 2] photocycloadditions with tethered linkers: synthesis of syn-photodimers of dicyclopentadienes.
PubMed:Composition of soil microbial communities enriched on a mixture of aromatic hydrocarbons.
PubMed:Catalytic asymmetrization of racemic dicyclopentadiene derivatives by using chiral copper(II) catalyst
PubMed:Biodegradation of dicyclopentadiene in the field.
PubMed:[Gas chromatographic determination of dicyclopentadiene in the work area air].
PubMed:In vitro degradation of dicyclopentadiene by microbial consortia isolated from hydrocarbon-contaminated soil.
PubMed:Subchronic toxicity study of dicyclopentadiene vapor in rats.
PubMed:[Hygienic analysis of the experience in dicyclopentadiene production from petrochemical raw materials].
PubMed:[Twenty-eight day repeated dose toxicity test of dicyclopentadiene in F344 rat].
PubMed:[The role of construction materials as secondary sources of the air pollution of manufacturing premises with dicyclopentadiene].
PubMed:[Protection of the respiratory organs in production of dicyclopentadiene].
PubMed:[Index of functional discoordination as a criterion of hazardousness for exposure to toxic chemicals].
PubMed:Derivatives of dicyclopentadiene in ground water.
PubMed:[Establishment of the maximum permissible concentrations of norbornene, norbornadiene and dicyclopentadiene in reservoir water].
PubMed:In vivo skeletal localization properties of 99mTc complexes of large phosphonate ligands.
PubMed:[Gas chromatographic determination of dicyclopentadiene in the air].
PubMed:Mutagenic activity associated with by-products of drinking water disinfection by chlorine, chlorine dioxide, ozone and UV-irradiation.
PubMed:Toxicologic evaluation of diisopropyl methylphosphonate and dicyclopentadiene in cattle.
PubMed:Fate of dicyclopentadiene in a lactating cow.
PubMed:Testing of twenty-one environmental aromatic amines or derivatives for long-term toxicity or carcinogenicity.
PubMed:Biological active polycycloalkanes. 4. Phosphoric esters of trimethylenenorbornyl alcohols.
PubMed:[Separate determination of indene, coumarone, styrol, cyclopentadiene and dicyclopentadiene in the air by thin-layer chromatography].
PubMed:The mammalian toxicity of dicyclopentadiene.
PubMed:[Materials for substantiation of maximum permissible concentration of cyclopentadiene and of its dimer-dicyclopentadiene in the atmosphere of industrial premises].
PubMed:On the addition of formic acid to dicyclopentadiene.
 
Notes:
None found
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